期刊
DALTON TRANSACTIONS
卷 41, 期 35, 页码 10543-10548出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt31068f
关键词
-
资金
- Department of Science and Technology, India [SR/S1/IC-38/2010]
- CSIR, India
Two copper(II) complexes, 1 and 2, of two tridentate N-donor ligands, L-1 and L-2 [L-1 = dansyl derivative of bis-[3-(dimethylamino)-propyl] amine; L-2 = dansyl derivative of dipropylenetriamine] were synthesized and characterized. The quenched fluorescence intensity of complexes 1 and 2, in degassed methanol or aqueous (buffered at pH 7.2) solution, was found to reappear on exposure to nitric oxide. This is attributed to the reduction of paramagnetic Cu(II) center by nitric oxide to diamagnetic Cu(I).
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