期刊
DALTON TRANSACTIONS
卷 41, 期 44, 页码 13741-13746出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt31436c
关键词
-
资金
- NSFC [90922031, 21121061, 50902151]
- 973 Project [2012CB821706]
- Foundation for the Authors of Excellent Doctoral Dissertation of Guangdong Province
The reaction of CoBr2, 1,2-di(4H-1,2,4-triazol-4-yl)diazene (bta) and KSCN yielded a one-dimensional coordination polymer [Co(SCN)(2)(bta)(H2O)(2)] with water molecules coordinated to the metal ions. After dehydration at 100 degrees C, the compound transformed into a layered coordination polymer [Co(SCN)(2)(bta)], whose structure was determined by powder X-ray diffraction based on the single-crystal structure of another layered coordination polymer [Cd(SCN)(2)(bta)]. Interestingly, a magnetic variation from a simple paramagnet to an antiferromagnetic ordered phase of a single-chain-magnet that exhibits both metamagnetic behaviour and slow magnetic relaxation was observed upon the dehydration process.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据