期刊
DALTON TRANSACTIONS
卷 40, 期 35, 页码 8906-8911出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1dt10195a
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An improved synthesis of pincer ligand bis[(2-dimethylamino)phenyl]amine ( (N2NH)-N-Me) was reported. Reaction of the Li complex of (N2N)-N-Me with suitable Pd, Pt, and Ru precursors gave the corresponding metal complexes. The structures of the Pd, Pt, and Ru complexes were determined. The Ru complex showed activity in catalytic transfer hydrogenation of aryl and alkyl ketones.
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