期刊
DALTON TRANSACTIONS
卷 40, 期 14, 页码 3703-3710出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0dt01551b
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资金
- National Science Council and National Center of High-Performance Computing of Taiwan, the Republic of China
Reaction of the ruthenium acetylide complex Cp(dppe)RuC CCH(OMe)CPh2-CH2CH=CMe2 (5a) with oxygen readily gives acetone and the acyl complex 6 in almost quantitative yield. Protonation of 5a is followed by an elimination of MeOH and a hydroxyl addition at C alpha in the presence of water to give the hydroxycarbene complex 7a. The structures of the acyl complex 6 and the hydroxycarbene complex 7c are fully characterized by single crystal X-ray diffraction analysis.
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