Article
Chemistry, Organic
Jeremy R. Tuck, Robert J. Tombari, Noah Yardeny, David E. Olson
Summary: In this study, arylazo-1,2,3-triazoles were successfully synthesized using azide-alkyne click chemistry, showcasing high thermal stabilities and near-quantitative bidirectional photoconversion.
Article
Chemistry, Multidisciplinary
Suguru Yoshida, Yuki Sakata, Yoshihiro Misawa, Takamoto Morita, Tomoko Kuribara, Harumi Ito, Yuka Koike, Isao Kii, Takamitsu Hosoya
Summary: Efficient consecutive formation of 1,2,3-triazoles using multiazide platforms has been achieved in this study. A four-step synthesis of tetrakis(triazoles) was successfully performed from a tetraazide platform molecule, based on the unique clickability of the 1-adamantyl azido group. This method was applied to the convergent synthesis of tetrafunctionalized probes in a modular synthetic manner.
CHEMICAL COMMUNICATIONS
(2021)
Review
Chemistry, Applied
Farid Ahmed, Hai Xiong
Summary: This review summarizes the latest developments in chemosensors based on click generated triazoles for a range of metal cations, anions, and neutral analytes, highlighting the need for continuous research accumulation in this rapidly growing field to meet demand.
Article
Chemistry, Medicinal
Elena O. Shestakova, Sergey G. Il'yasov, Irina A. Shchurova, Vera S. Glukhacheva, Dmitri S. Il'yasov, Egor E. Zhukov, Arkady O. Bryzgalov, Tatiana G. Tolstikova, Yuri V. Gatilov
Summary: In this study, the reaction of 1,3-dipolar cycloaddition between 1,3-diazido-2-nitro-2-azapropane (DANP) and propargyl alcohol was investigated, and the optimal reaction conditions for the synthesis of 2-nitro-1,3-bis(4,4'-dihydroxymethyl)-1,2,3-triazolyl-2-azapropane (1) were identified. Additionally, the reactions between DANP and 1,5-diazido-3-nitrazapentane, as well as phenylacetylene, produced the corresponding 1,2,3-triazole derivatives. The synthesized compounds were characterized using various spectroscopic techniques and elemental analysis. The antiarrhythmic activity of compound 1 was evaluated, demonstrating dose-dependent effects, indicating its potential as a therapeutic agent.
Article
Chemistry, Organic
Cong Guan, Jiabin Yin, Jian Ji, Jinhua Liu, Xiang Wu, Tong Zhu, Shunying Liu
Summary: A regioselective electrochemical C-H amination method using easily accessible ethers has been developed to synthesize N (2)-substituted 1,2,3-triazole. Multiple substituents, including heterocycles, were well-tolerated, and 24 examples were obtained in moderate to good yields. Control experiments and DFT calculations revealed that the electrochemical synthesis occurs through a N-tosyl 1,2,3-triazole radical cation process, promoted by single-electron transfer from the lone pair electrons of the aromatic N-heterocycle, and the desulfonation is responsible for the high N (2)-regioselectivity.
Article
Chemistry, Organic
Jose Laxio Arenas, Pascal Retailleau, Jean-Michel Gillet, Nour-Eddine Ghermani, Sandrine Ongeri, Benoit Crousse
Summary: The 5-fluoro triazole amino acid scaffold prepared by halogen exchange was successfully incorporated into peptides. The X-ray diffraction results revealed an important localization of the 5-fluoro triazole motif on one side of the negative potential surface, with the fluorine atom showing a cylindrical shape in its electron density deformation.
ORGANIC & BIOMOLECULAR CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Aleksandra A. Vidyakina, Andrey A. Shtyrov, Mikhail N. Ryazantsev, Alexander F. Khlebnikov, Ilya E. Kolesnikov, Vladimir V. Sharoyko, Dar'ya Spiridonova, Irina A. Balova, Stefan Braese, Natalia A. Danilkina
Summary: Fluorescent isocoumarin-fused cycloalkynes have been developed, which react in SPAAC and give fluorescent triazoles regardless of the azide nature. The introduction of a pi-acceptor group at the C6 position of the isocoumarin ring converts the non-fluorescent cycloalkyne/triazole pair to its fluorescent counterpart. The design of the fluorescent cycloalkyne/triazole pairs is based on theoretical studies of the deactivation mechanism and electron density redistribution.
CHEMISTRY-A EUROPEAN JOURNAL
(2023)
Article
Chemistry, Multidisciplinary
Menghan Cui, Changhui Su, Rong Wang, Qing Yang, Chunxiang Kuang
Summary: This novel and green route involves the direct synthesis of vinyl triazole derivatives with alkynes and triazoles promoted by an inorganic base under transition metal-free conditions, showing great catalytic activity for the anti-Markovnikov stereoselective hydroamination of alkynes. Good yields with excellent functional group tolerance are successfully achieved for a range of substrates, making it an advanced concept for the synthesis of alkenyl triazole with a versatile and cost-efficient approach.
Article
Chemistry, Organic
Steven J. Peters, Krutil Patel
Summary: This study investigates the anion radicals of N1- and N2-alkylbenzotriazoles and alkyltriazoles through experimental and computational methods, revealing significant differences in the electron spin distribution, particularly in the N-3 portion of the triazole ring. Among the studied radicals, the N2-methyltriazole anion radical exhibits the largest concentration of electron spin in the N-3 moiety, leading to significant anisotropic line broadening in its EPR spectrum.
JOURNAL OF ORGANIC CHEMISTRY
(2021)
Article
Chemistry, Inorganic & Nuclear
Parveen Saini, Gurleen Singh, Gurjaspreet Singh, Jashan Deep Kaur, Gurpreet Kaur, Jandeep Singh, Harminder Singh
Summary: Current research reports the synthesis and characterization of a ligand, 1-naphtholphthalein linked 1,2,3-triazole (1-NPT), and its absorbance response on binding with Co(II) ions using 'Click Chemistry'. The selectivity of the synthesized receptor towards Co(II) ions was analyzed by performing UV-Visible titrations with various metal ions, showing a minimum detection limit of 1.87 μM and a 1:1 stoichiometry of 1-NPT:Co(II) complex with no interference from other metal ions.
INORGANICA CHIMICA ACTA
(2023)
Article
Biochemistry & Molecular Biology
Lijie Wei, Haishan Sui, Jingjing Zhang, Zhanyong Guo
Summary: A novel inulin derivative (3) bearing 1,2,3-triazole and diphenyl phosphate was successfully synthesized using CuAAC Click chemistry, showing significantly enhanced antioxidant activity compared with inulin. In vitro evaluation revealed strong radical scavenging abilities of the derivative, particularly against hydroxyl radicals and superoxide radicals. The synthetic strategy may offer an effective approach for preparing new inulin antioxidant biomaterials.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2021)
Article
Chemistry, Medicinal
Hariom Kumar, Manoj Dhameja, Sirisha Kurella, Adepally Uma, Preeti Gupta
Summary: A series of 1,2,3-triazole-1,3,4-thiadiazole hybrids 7a-j were synthesized and screened for inhibition of α-glucosidase enzyme. Compounds 7h and 7e exhibited the best inhibitory activity, and showed a mixed mode of inhibition.
ARCHIV DER PHARMAZIE
(2023)
Article
Plant Sciences
Kaveh Rasoolijokari, Peyman Salehi, Atousa Aliahmadi, Bahareh Heidari, Morteza Bararjanian
Summary: A series of 12 novel 1,2,3-triazole penicillin G derivatives were synthesized and evaluated for their antimicrobial activity. Compounds 5a and 5b showed the highest potency in inhibiting the growth of Staphylococcus aureus.
PHYTOCHEMISTRY LETTERS
(2023)
Article
Agriculture, Multidisciplinary
Cristiane Aparecida Franco, Toshik Iarley da Silva, Marlon Gomes Dias, Bruno Wesley Ferreira, Bianca Lana de Sousa, Guilherme Mateus Bousada, Robert Weingart Barreto, Boniek Gontijo Vaz, Gesiane da Silva Lima, Marcelo Henrique dos Santos, Jose Antonio Saraiva Grossi, Eduardo Vinicius Vieira Varejao
Summary: A series of tyrosol 1,2,3-triazole derivatives were synthesized and tested for phytotoxic activity on wild poinsettia, fleabane, and tropical spiderwort. While none of the compounds showed activity against two of the weed species, they exhibited strong phytotoxic effects on wild poinsettia, indicating their potential use as tools for managing this competitive weed in agricultural lands.
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Basvaraj S. Kote, Harish S. Kunchur, Latchupatula Radhakrishna, Madhusudan K. Pandey, Maravanji S. Balakrishna
Summary: The synthesis of a triazole appended dinucleating bisphosphine and its coinage metal complexes were described, including dimeric copper complexes, hetero-cubane silver complex, disilver complexes, dinuclear acetate bridged silver complex, and digold complex. The molecular structures of these complexes were confirmed by single crystal X-ray analysis, showing non-covalent interactions between copper and C-arene.
DALTON TRANSACTIONS
(2021)
Article
Chemistry, Multidisciplinary
Roan A. S. Vasdev, James A. Findlay, David R. Turner, James D. Crowley
Summary: A new ferrocene-containing self-assembled double-walled triangle structure has been synthesized and characterized, showing interactions with anionic guest and redox activity without influence from the guest.
CHEMISTRY-AN ASIAN JOURNAL
(2021)
Article
Chemistry, Inorganic & Nuclear
Tasha R. Steel, Kelvin K. H. Tong, Tilo Sohnel, Stephen M. F. Jamieson, L. James Wright, James D. Crowley, Muhammad Hanif, Christian G. Hartinger
Summary: Multimetallic complexes have been synthesized and characterized, with studies conducted on their binding properties with DNA and protein models. The anticancer activity of the complexes was evaluated against cancer cell lines, showing moderate antiproliferative effects.
INORGANICA CHIMICA ACTA
(2021)
Article
Chemistry, Inorganic & Nuclear
Daniel A. W. Ross, Joseph Mapley, Andrew P. Cording, Roan A. S. Vasdev, C. John McAdam, Keith C. Gordon, James D. Crowley
Summary: A bulky 6,6'-diTPAbpy ligand was synthesized and used to form homoleptic complexes with Cu(I) and Ag(I) ions, as well as interact with 6-coordinate metal ions. The steric bulk of the ligand affected the coordination geometry and photophysical properties of the complexes, showing changes in absorption and emission properties.
INORGANIC CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Joshua J. Sutton, Dan Preston, Philipp Traber, Johannes Steinmetzer, Xue Wu, Surajit Kayal, Xue-Z Sun, James D. Crowley, Michael W. George, Stephan Kupfer, Keith C. Gordon
Summary: The optical properties of two Re(CO)(3)(bpy)Cl complexes with different substituents were studied, revealing distinct charge transfer bands in their absorption spectra and two emissive states in their excited-state spectroscopy which are modulated by solvent. Time-resolved infrared spectroscopy identified the nature of the excited states in different solvents, with DFT calculations suggesting that the switching of properties induced by solvent is controlled by spin-orbit coupling.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2021)
Article
Chemistry, Multidisciplinary
Lynn S. Lisboa, Mie Riisom, Roan A. S. Vasdev, Stephen M. F. Jamieson, L. James Wright, Christian G. Hartinger, James D. Crowley
Summary: Two new di(2,2'-bipyridine) ligands were synthesized to generate metallosupramolecular cylinders, which were characterized through various spectroscopic techniques. The cylinders crystallized as racemic mixtures of helicates and showed anticancer activity against different cell lines, with potential differences in modes of action compared to standard treatments like cisplatin.
FRONTIERS IN CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Lynn S. Lisboa, Dan Preston, C. John McAdam, L. James Wright, Christian G. Hartinger, James D. Crowley
Summary: A strategy for generating heterotrimetallic double cavity cages and their interactions with different guest molecules were reported. The structures of the cages and their selective binding behavior were studied through various spectroscopic techniques. The results provide insights into the design and synthesis of multifunctional host-guest systems.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Inorganic & Nuclear
James A. Findlay, Daniel A. W. Ross, James D. Crowley
Summary: Three ferrocene-based rotary switches were developed using 2-pyridyl-1,2,3-triazole click chelates. The addition of compounds enabled the conformational switch of the rotors, but the weakness of the pytri chelates prevented the development of an electrochemically switchable system.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Lewis P. M. Green, Tasha R. Steel, Mie Riisom, Muhammad Hanif, Tilo Soehnel, Stephen M. F. Jamieson, L. James Wright, James D. Crowley, Christian G. Hartinger
Summary: Multimetallic complexes have been demonstrated to exhibit greater anticancer activity than monometallic counterparts, possibly due to altered modes of action. In this study, a series of heterodimetallic compounds were synthesized and characterized by various techniques. Proliferation assays in human cancer cell lines showed that most complexes were inactive.
FRONTIERS IN CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Daniel A. W. Ross, James A. Findlay, Roan A. S. Vasdev, James D. Crowley
Summary: The study investigates the potential of utilizing new ligands pytri and tripy instead of commonly used polypyridyl ligands in copper(I)/(II) switching systems. The results show that the new ligands exhibit good binding ability in the copper(II) state but lower selectivity in the copper(I) state.
Article
Chemistry, Inorganic & Nuclear
Roan A. S. Vasdev, Dan Preston, Caitlin A. Casey-Stevens, Vicente Marti-Centelles, Paul J. Lusby, Anna L. Garden, James D. Crowley
Summary: This study attempts to generate reduced-symmetry [Pd-2(L)(4)](4+) cage architectures using supramolecular forces and solvophobic effects. The results show that the combination of dispersion forces and solvophobic effects does not provide control over the isomer distribution, while more control is obtained by exploiting hydrogen bonding interactions.
INORGANIC CHEMISTRY
(2022)
Review
Chemistry, Multidisciplinary
Aston C. Pearcy, James D. Crowley
Summary: This article outlines the use of metallosupramolecular structures to mimic the properties of biological enzymes and machines.
CHEMISTRY-A EUROPEAN JOURNAL
(2023)
Article
Chemistry, Inorganic & Nuclear
William D. J. Tremlett, Tilo Soehnel, James D. Crowley, L. James Wright, Christian G. Hartinger
Summary: Using ferrocene-based ligand systems, a series of heterobimetallic architectures were designed to release and bind guest molecules. The complexes were characterized using various techniques and the disassembly and reassembly process of metallosupramolecular structures were investigated using NMR spectroscopy. Guest binding studies revealed interactions with anionic guests and the release of guests was induced by Cl- ions.
INORGANIC CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Aston C. Pearcy, Lynn S. Lisboa, Dan Preston, Nick B. Page, Tristan Lawrence, L. James Wright, Christian G. Hartinger, James D. Crowley
Summary: A new sequential metalation strategy has been developed for the assembly of a more stable heterobimetallic [PdPtL4](4+) cage. By using a low-symmetry ditopic ligand (L) with imidazole and pyridine donor units, a [Pt(L)(4)](2+) open-cage complex was selectively formed and then reacted with Pd(ii) ions to assemble the cage C. Various spectroscopy and crystallography techniques confirmed the formation of the cage and its heterobimetallic structure. The cage C exhibited anionic guest molecule binding capability and demonstrated stimulus-responsive behavior.
Review
Chemistry, Multidisciplinary
Lana K. Moree, Logan A. V. Faulkner, James D. Crowley
Summary: In this tutorial review, the general methods for synthesizing heterometallic metallosupramolecular architectures (MSAs), specifically heterometallic cages, are examined. The intrinsic properties and potential applications of these cages as host-guest systems and reaction catalysts are discussed.
CHEMICAL SOCIETY REVIEWS
(2024)
Article
Chemistry, Inorganic & Nuclear
Lynn S. Lisboa, Mie Riisom, Henry J. Dunne, Dan Preston, Stephen M. F. Jamieson, L. James Wright, Christian G. Hartinger, James D. Crowley
Summary: A new [PdPtL4](4+) heterobimetallic cage containing hydrazone linkages was synthesized using the sub-component self-assembly approach. The cage showed stimulus-responsive behavior and was more stable against hydrolysis compared to a previously synthesized imine-containing cage. It interacted with cisplatin, while the smaller imine cage interacted with 5-fluorouracil and oxaliplatin.
DALTON TRANSACTIONS
(2022)
Article
Chemistry, Inorganic & Nuclear
Vaibhav Bedi, Dipendu Mandal, Zahid Hussain, Shi-Ming Chen, Yile Wu, Zheng-Wang Qu, Stefan Grimme, Douglas W. Stephan
Summary: The reaction of (tBuO(2)CN)(2) with 9-BBN leads to the formation of a bicyclic heterocyclic compound, while its reactions with BF3 or [Et3Si][B(C6F5)(4)] result in the isolation of different compounds. Computational studies reveal that the steric and electronic properties of the Lewis acid are important in the formation of one of the compounds.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Chisa Itoh, Haruka Yoshino, Taku Kitayama, Wataru Kosaka, Hitoshi Miyasaka
Summary: A new synthetic route for constructing functional paddlewheel diruthenium(II,II) complexes was developed, utilizing Schiff base condensation reactions. The attached Schiff base groups significantly affected the electronic states of the resulting complexes, as revealed by cyclic voltammetry and DFT calculations.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Danrui Ni, Haozhe Wang, Xianghan Xu, Weiwei Xie, Robert J. Cava
Summary: A layered rhombohedral polymorph of indium(iii) triiodide is synthesized at high pressure and temperature. It has an orange color, which is different from ambient pressure InI3, which has a monoclinic molecular structure and a light-yellow color.
DALTON TRANSACTIONS
(2024)
Review
Chemistry, Inorganic & Nuclear
Juan Carlos Perez-Sanchez, Raquel P. Herrera, M. Concepcion Gimeno
Summary: Gold(II) complexes have been less utilized in catalysis compared to their gold(I) and gold(III) counterparts. However, gold(II) complexes offer potential in homo-coupling and cross-coupling reactions, as they are more easily accessible through simplified oxidation and reduction processes. Gold(II) exhibits characteristics of both soft acid gold(I) and hard acid gold(III). This review explores the unique reactivity and potential applications of gold(II) species, highlighting their significance in catalytic transformations.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Nighat Yousuf, Yanping Ma, Qaiser Mahmood, Wenjuan Zhang, Yizhou Wang, Hassan Saeed, Wen-Hua Sun
Summary: In this study, a series of structurally rigid cyclooctyl-fused iminopyridine iron complexes were synthesized and used with methylaluminoxane for isoprene polymerization. The extent of steric hindrance of the ligand framework was found to significantly affect catalytic performance, with less hindrance leading to better activity and stability.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Chenghao Song, Huiwei Du, Menglei Xu, Jie Yang, Xinyu Zhang, Jungan Wang, Yuanfang Zhang, Chengjun Gu, Rui Li, Tao Hong, Jingji Zhang, Jiangying Wang, Yongchun Ye
Summary: This study improves the performance of perovskite solar cells by using a dual-hole transport layer strategy. This strategy enhances the charge transfer efficiency of the transport layer, reduces charge recombination, and improves the quality of the perovskite film layer. Ultimately, the stability of the device is enhanced.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Mahender Singh, Aakash Yadav, Ranjit Singh, Chullikkattil P. Pradeep
Summary: A new aryl selenonium polyoxometalate hybrid was developed and compared with an aryl sulfonium polyoxometalate hybrid in terms of their photocatalytic properties. It was found that the aryl selenonium hybrid exhibited better catalytic performance, which could be attributed to the larger atomic radii of selenium stabilizing the photogenerated electron-hole pair more efficiently. Additionally, the generation of elemental selenium through cleavage of C-Se bonds during catalysis was observed.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Yuhan Xie, Boyu Dong, Xuemin Wang, Siyuan Wang, Jinxi Chen, Yongbing Lou
Summary: This study successfully fabricated visible-light-responsive three-dimensional core-shell CoSe2/ZnIn2S4 heterostructures and achieved attractive activity in photocatalytic hydrogen evolution. The presence of CoSe2 improved light absorption and accelerated charge transfer kinetics. The strong interaction between CoSe2 and ZnIn2S4 reduced charge recombination, further enhancing photocatalytic activity for hydrogen evolution.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Andre L. de O. Batista, Joao Marcos T. Palheta, Mauricio J. Piotrowski, Celso R. C. Rego, Diego Guedes-Sobrinho, Alexandre C. Dias
Summary: This study presents a simulation protocol that provides a solid foundation for exploring two-dimensional materials. Using the TiBr2 2H monolayer as an example, the study reveals its promising properties for optoelectronic and valleytronic applications, including its stability, spin-orbit coupling effects, and optical helicity selection rule.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Jiang Jiang, Zi-Wei Li, Zhi-Zhuan Zhang, Bin Tan, Zhao-Feng Wu, Xiao-Ying Huang
Summary: In this work, two metal organic frameworks (MOFs) containing {Cu2I2} clusters, Eu-CuI-INA and Sr-K-CuI-INA, were synthesized and characterized. Both materials have a three-dimensional structure with {Cu2I2} clusters coordinated by INA(-) ligands and Eu3+ or Sr2+ ions. The Sr-K-CuI-INA material exhibited sensitive fluorescence sensing behaviors towards cysteine and nitro-bearing molecules, showing potential applications in bio and explosive molecule sensing. This work provides a good reference for designing fluorescent MOF probes containing CuI molecules.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Zhiya Lin, Jiasheng Wu, Qianwen Ye, Yulong Chen, Hai Jia, Xiaohui Huang, Shaoming Ying
Summary: Na-ion batteries (NIBs) have attracted great interest as a potential technology for grid-scale energy storage due to the wide distribution, low cost, and environmental friendliness of sodium resources. However, their implementation is hindered by low rate capability and cycling stability caused by the large ionic size of Na+. In this study, a three-dimensional nanoarchitectured coral-like CoSe2@N-doped carbon (CL-CoSe2@NC) was synthesized, and it exhibited improved sodium storage properties with better electrode kinetics and a stable SEI film.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Ya-Qiong Zhang, Yu Zhang, Guoping Zeng, Rong-Zhen Liao, Man Li
Summary: The mechanism and selectivity of CO2 reduction under visible light were investigated using density functional calculations. The results showed that a tetradentate PNNP-type Iridium(III) complex exhibited high activity and selectivity in the reaction.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Sanyukta Ghosh, Shubhanth Jain, Soumya Ranjan Mishra, Gerda Rogl, Peter Rogl, Ernst Bauer, B. S. Murty, A. Govindaraj, Ramesh Chandra Mallik
Summary: In this study, reduced graphene oxide (rGO) was uniformly dispersed in the In0.5Co4Sb12 bulk material by ultrasonication, which effectively reduced the lattice thermal conductivity and improved the thermoelectric efficiency.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Mika Takeuchi, Yutaka Amao
Summary: This study developed an effective visible-light driven system for fumaric acid production using renewable resources such as biomass derivatives, providing an alternative to the current petroleum-based synthesis methods.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Juan Jian, Meiting Wang, Zhuo Wang, Jingwen Meng, Yuqin Yang, Limin Chang
Summary: Developing low-cost and self-supported bifunctional catalysts is crucial for highly efficient water splitting devices. In this study, nano-NiFe2O4 was directly grown onto iron foil surface and Sn4+ was introduced into the NiFe2O4. The resulting Sn-NiFe2O4/IF showed low overpotentials and high current densities during oxygen evolution reaction (OER) and hydrogen evolution reaction (HER), making it a promising catalyst for large-scale hydrogen production.
DALTON TRANSACTIONS
(2024)