期刊
DALTON TRANSACTIONS
卷 39, 期 12, 页码 2993-2994出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b926061g
关键词
-
资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan [17350027, 17655027, 18033041, 18065017]
- JST, Japan
This communication reports the successful merging of the chemical properties of a natural [NiFe] hydrogenase (Desulfovibrio vulgaris Miyazaki F) and our previously reported [NiRu]hydrogenase-mimic. The catalytic activity of both the natural enzyme and the mimic is almost identical, with the exception of working pH ranges, and this allows us to use them simultaneously in the same reaction flask. In such a manner, isotope exchange between D-2 and H2O could be conducted over an extended pH range (about 2-10) in one pot under mild conditions at ambient temperature and pressure.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据