Article
Biochemistry & Molecular Biology
Lijie Wei, Haishan Sui, Jingjing Zhang, Zhanyong Guo
Summary: A novel inulin derivative (3) bearing 1,2,3-triazole and diphenyl phosphate was successfully synthesized using CuAAC Click chemistry, showing significantly enhanced antioxidant activity compared with inulin. In vitro evaluation revealed strong radical scavenging abilities of the derivative, particularly against hydroxyl radicals and superoxide radicals. The synthetic strategy may offer an effective approach for preparing new inulin antioxidant biomaterials.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2021)
Article
Chemistry, Physical
Parveen Saini, Gurjaspreet Singh, Gurpreet Kaur, Jandeep Singh, Harminder Singh
Summary: This report describes the absorbance response of a molecular assembly incorporating o-Cresolphthalein appended 1,4-disubstituted 1,2,3-triazole (o-CPT) upon complexation with Pb(II) ions. A Copper (I) catalyzed alkyne-azide cycloaddition reaction was employed to fabricate the designed receptor, which was characterized through various spectroscopic techniques. The results highlight the high sensitivity and selectivity of the receptor towards Pb(II) ions.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Chemistry, Medicinal
Fabiola Suelen dos Santos, Rossimiriam Pereira de Freitas, Camila Simoes de Freitas, Debora Vasconcelos Costa Mendonca, Daniela Pagliara Lage, Grasiele de Sousa Vieira Tavares, Amanda Sanchez Machado, Vivian Tamieti Martins, Adilson Vidal Costa, Vagner Tebaldi de Queiroz, Mariana Belizario de Oliveira, Fabricio Marques de Oliveira, Luciana Maria Ribeiro Antinarelli, Elaine Soares Coimbra, Eduardo Jorge Pilau, Geovane Perez da Silva, Eduardo Antonio Ferraz Coelho, Robson Ricardo Teixeira
Summary: This study synthesized 24 methoxylated cinnamides containing 1,2,3-triazole fragments and evaluated their antileishmanial activity. One of the synthetic compounds, compound 28, demonstrated significant antileishmanial activity with low toxicity in murine cells, making it a potential candidate for the treatment of Leishmaniasis.
Article
Chemistry, Organic
Jeremy R. Tuck, Robert J. Tombari, Noah Yardeny, David E. Olson
Summary: In this study, arylazo-1,2,3-triazoles were successfully synthesized using azide-alkyne click chemistry, showcasing high thermal stabilities and near-quantitative bidirectional photoconversion.
Article
Chemistry, Physical
Nancy George, Gurleen Singh, Riddima Singh, Gurjaspreet Singh, Priyanka, Harminder Singh, Gurpreet Kaur, Jandeep Singh
Summary: A novel 1,2,3-triazole linked schiff base chemosensor was synthesized via Cu(I) catalyzed click reaction. It showed excellent yield, high selectivity and sensitivity. The chemosensor was characterized using FTIR, NMR, MS, CHN analysis, TGA, and DSC. UV-visible and fluorescent spectroscopy were used to investigate the optical properties of the developed chemosensor. The synthesized probe showed a detection limit of 0.25 μM, below the WHO guidelines.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Review
Chemistry, Applied
Farid Ahmed, Hai Xiong
Summary: This review summarizes the latest developments in chemosensors based on click generated triazoles for a range of metal cations, anions, and neutral analytes, highlighting the need for continuous research accumulation in this rapidly growing field to meet demand.
Article
Chemistry, Inorganic & Nuclear
Parveen Saini, Gurleen Singh, Gurjaspreet Singh, Jashan Deep Kaur, Gurpreet Kaur, Jandeep Singh, Harminder Singh
Summary: Current research reports the synthesis and characterization of a ligand, 1-naphtholphthalein linked 1,2,3-triazole (1-NPT), and its absorbance response on binding with Co(II) ions using 'Click Chemistry'. The selectivity of the synthesized receptor towards Co(II) ions was analyzed by performing UV-Visible titrations with various metal ions, showing a minimum detection limit of 1.87 μM and a 1:1 stoichiometry of 1-NPT:Co(II) complex with no interference from other metal ions.
INORGANICA CHIMICA ACTA
(2023)
Review
Chemistry, Organic
Dileep Kumar Singh
Summary: Among the various approaches in organic synthesis, the click chemistry protocol, also known as CuAAC reaction, is commonly used to connect different moieties in a single framework. This review focuses on the synthesis and photophysical studies of porphyrin conjugates with meso-substituted and 1,2,3-triazole-fused structures. The triazole ring serves as a spacer and an electron transfer bridge between the attached chromophores and the porphyrin.
JOURNAL OF ORGANIC CHEMISTRY
(2023)
Article
Chemistry, Medicinal
Poliana A. R. Gazolla, Alex R. de Aguiar, Maria C. A. Costa, Osmair V. Oliveira, Adilson V. Costa, Cleiton M. da Silva, Claudia J. do Nascimento, Jochen Junker, Rafaela S. Ferreira, Fabricio M. de Oliveira, Boniek G. Vaz, Paulo H. F. do Carmo, Daniel A. Santos, Marcia M. C. Ferreira, Robson R. Teixeira
Summary: This study focuses on the synthesis of vanillin derivatives with 1,2,3-triazole fragments and their antifungal activities against various strains. The synthesized compounds showed moderate activity against the microorganisms tested, with some exhibiting fungicidal activity. The compounds also displayed favorable physicochemical and ADMET properties for drug development, and molecular docking calculations revealed their binding affinity to the enzyme active site.
ARCHIV DER PHARMAZIE
(2023)
Article
Chemistry, Inorganic & Nuclear
Nancy George, Gurleen Singh, Riddima Singh, Gurjaspreet Singh, Harminder Sushma, Harminder Singh, Gurpreet Kaur, Jandeep Singh
Summary: This research aims to synthesize a Schiff base tethered 1,2,3-triazole derivative as a highly sensitive and selective optical chemosensor for the recognition of ferric ions using Cu(I) catalyzed click reaction. The synthesized probe was characterized and its optical properties, including the association constant and limit of detection of Fe3+, were investigated. Real sample application for Fe3+ detection in spinach was analyzed, and the probe showed high recovery rate. The probe was also studied computationally using DFT method.
Article
Plant Sciences
Kaveh Rasoolijokari, Peyman Salehi, Atousa Aliahmadi, Bahareh Heidari, Morteza Bararjanian
Summary: A series of 12 novel 1,2,3-triazole penicillin G derivatives were synthesized and evaluated for their antimicrobial activity. Compounds 5a and 5b showed the highest potency in inhibiting the growth of Staphylococcus aureus.
PHYTOCHEMISTRY LETTERS
(2023)
Article
Chemistry, Applied
Melisa Trejo-Maldonado, Luis Ernesto Elizalde, Benjamin Le Droumaguet, Daniel Grande
Summary: A versatile approach was developed for the preparation of porous polystyrene frameworks functionalized with triazolyl moieties. The porous materials were synthesized from PLA-b-P(S-stat-4-AMS) diblock copolymer precursors and characterized by various analytical techniques. Functionalization of the materials with p-tolylacetylene or 2-methyl-3-butyn-2-ol was achieved via copper-catalyzed azide-alkyne cycloaddition, resulting in high yields of the triazole ring.
REACTIVE & FUNCTIONAL POLYMERS
(2021)
Article
Chemistry, Multidisciplinary
Dawid Drelinkiewicz, Richard J. Whitby
Summary: A robust and versatile protocol for the synthesis of 1-monosubstituted and 1,4-disubstituted 1H-1,2,3-triazoles was established under continuous flow conditions using copper-on-charcoal as a heterogeneous catalyst. This method allows for the synthesis of a diverse set of substituted 1,2,3-triazoles with good functional group tolerance and high yields, and it has been successfully used to synthesize an antiepileptic agent.
Article
Chemistry, Inorganic & Nuclear
Jan Holub, Antonio Santoro, Mihail-Adrian Stadler, Jean-Marie Lehn
Summary: The sequential assembly of terminally functionalized bishydrazone ligands followed by coordination with Zn(ii) metal cations yields multi-functionalized grid-type complexes. The introduction of aldehyde functional groups results in octavalent grids, offering potential for diverse dynamic covalent decorations. Further connection with a difunctional covalent linker leads to folded molecular grids with double hairpins geometry, allowing for multifunctional dynamic covalent chemistry.
INORGANIC CHEMISTRY FRONTIERS
(2021)
Article
Chemistry, Multidisciplinary
Kalyana K. Ponnapalli, Sachin K. Kawade, Avijit K. Adak, Hsin-Ru Wu, Chun-Cheng Lin
Summary: The synthesis of a new series of 4-phenyl-C-glycosyl-1,2,3-triazoles was achieved through Cu(I)-catalyzed azide-alkyne cycloaddition, with a key step involving the coupling of unprotected glycosyl azides with substituted C-glycosylated phenyl acetylenes. By using o-phenylenediamine as a ligand, the reaction time was significantly reduced, product yield improved, and purification process simplified. The study also demonstrated a broad substrate scope in terms of sugars.
JOURNAL OF THE CHINESE CHEMICAL SOCIETY
(2021)
Article
Chemistry, Multidisciplinary
Roan A. S. Vasdev, James A. Findlay, David R. Turner, James D. Crowley
Summary: A new ferrocene-containing self-assembled double-walled triangle structure has been synthesized and characterized, showing interactions with anionic guest and redox activity without influence from the guest.
CHEMISTRY-AN ASIAN JOURNAL
(2021)
Article
Chemistry, Inorganic & Nuclear
Tasha R. Steel, Kelvin K. H. Tong, Tilo Sohnel, Stephen M. F. Jamieson, L. James Wright, James D. Crowley, Muhammad Hanif, Christian G. Hartinger
Summary: Multimetallic complexes have been synthesized and characterized, with studies conducted on their binding properties with DNA and protein models. The anticancer activity of the complexes was evaluated against cancer cell lines, showing moderate antiproliferative effects.
INORGANICA CHIMICA ACTA
(2021)
Article
Chemistry, Inorganic & Nuclear
Daniel A. W. Ross, Joseph Mapley, Andrew P. Cording, Roan A. S. Vasdev, C. John McAdam, Keith C. Gordon, James D. Crowley
Summary: A bulky 6,6'-diTPAbpy ligand was synthesized and used to form homoleptic complexes with Cu(I) and Ag(I) ions, as well as interact with 6-coordinate metal ions. The steric bulk of the ligand affected the coordination geometry and photophysical properties of the complexes, showing changes in absorption and emission properties.
INORGANIC CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Joshua J. Sutton, Dan Preston, Philipp Traber, Johannes Steinmetzer, Xue Wu, Surajit Kayal, Xue-Z Sun, James D. Crowley, Michael W. George, Stephan Kupfer, Keith C. Gordon
Summary: The optical properties of two Re(CO)(3)(bpy)Cl complexes with different substituents were studied, revealing distinct charge transfer bands in their absorption spectra and two emissive states in their excited-state spectroscopy which are modulated by solvent. Time-resolved infrared spectroscopy identified the nature of the excited states in different solvents, with DFT calculations suggesting that the switching of properties induced by solvent is controlled by spin-orbit coupling.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2021)
Article
Chemistry, Multidisciplinary
Lynn S. Lisboa, Mie Riisom, Roan A. S. Vasdev, Stephen M. F. Jamieson, L. James Wright, Christian G. Hartinger, James D. Crowley
Summary: Two new di(2,2'-bipyridine) ligands were synthesized to generate metallosupramolecular cylinders, which were characterized through various spectroscopic techniques. The cylinders crystallized as racemic mixtures of helicates and showed anticancer activity against different cell lines, with potential differences in modes of action compared to standard treatments like cisplatin.
FRONTIERS IN CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Lynn S. Lisboa, Dan Preston, C. John McAdam, L. James Wright, Christian G. Hartinger, James D. Crowley
Summary: A strategy for generating heterotrimetallic double cavity cages and their interactions with different guest molecules were reported. The structures of the cages and their selective binding behavior were studied through various spectroscopic techniques. The results provide insights into the design and synthesis of multifunctional host-guest systems.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Inorganic & Nuclear
James A. Findlay, Daniel A. W. Ross, James D. Crowley
Summary: Three ferrocene-based rotary switches were developed using 2-pyridyl-1,2,3-triazole click chelates. The addition of compounds enabled the conformational switch of the rotors, but the weakness of the pytri chelates prevented the development of an electrochemically switchable system.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Lewis P. M. Green, Tasha R. Steel, Mie Riisom, Muhammad Hanif, Tilo Soehnel, Stephen M. F. Jamieson, L. James Wright, James D. Crowley, Christian G. Hartinger
Summary: Multimetallic complexes have been demonstrated to exhibit greater anticancer activity than monometallic counterparts, possibly due to altered modes of action. In this study, a series of heterodimetallic compounds were synthesized and characterized by various techniques. Proliferation assays in human cancer cell lines showed that most complexes were inactive.
FRONTIERS IN CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Daniel A. W. Ross, James A. Findlay, Roan A. S. Vasdev, James D. Crowley
Summary: The study investigates the potential of utilizing new ligands pytri and tripy instead of commonly used polypyridyl ligands in copper(I)/(II) switching systems. The results show that the new ligands exhibit good binding ability in the copper(II) state but lower selectivity in the copper(I) state.
Article
Chemistry, Inorganic & Nuclear
Roan A. S. Vasdev, Dan Preston, Caitlin A. Casey-Stevens, Vicente Marti-Centelles, Paul J. Lusby, Anna L. Garden, James D. Crowley
Summary: This study attempts to generate reduced-symmetry [Pd-2(L)(4)](4+) cage architectures using supramolecular forces and solvophobic effects. The results show that the combination of dispersion forces and solvophobic effects does not provide control over the isomer distribution, while more control is obtained by exploiting hydrogen bonding interactions.
INORGANIC CHEMISTRY
(2022)
Review
Chemistry, Multidisciplinary
Aston C. Pearcy, James D. Crowley
Summary: This article outlines the use of metallosupramolecular structures to mimic the properties of biological enzymes and machines.
CHEMISTRY-A EUROPEAN JOURNAL
(2023)
Article
Chemistry, Inorganic & Nuclear
William D. J. Tremlett, Tilo Soehnel, James D. Crowley, L. James Wright, Christian G. Hartinger
Summary: Using ferrocene-based ligand systems, a series of heterobimetallic architectures were designed to release and bind guest molecules. The complexes were characterized using various techniques and the disassembly and reassembly process of metallosupramolecular structures were investigated using NMR spectroscopy. Guest binding studies revealed interactions with anionic guests and the release of guests was induced by Cl- ions.
INORGANIC CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Aston C. Pearcy, Lynn S. Lisboa, Dan Preston, Nick B. Page, Tristan Lawrence, L. James Wright, Christian G. Hartinger, James D. Crowley
Summary: A new sequential metalation strategy has been developed for the assembly of a more stable heterobimetallic [PdPtL4](4+) cage. By using a low-symmetry ditopic ligand (L) with imidazole and pyridine donor units, a [Pt(L)(4)](2+) open-cage complex was selectively formed and then reacted with Pd(ii) ions to assemble the cage C. Various spectroscopy and crystallography techniques confirmed the formation of the cage and its heterobimetallic structure. The cage C exhibited anionic guest molecule binding capability and demonstrated stimulus-responsive behavior.
Review
Chemistry, Multidisciplinary
Lana K. Moree, Logan A. V. Faulkner, James D. Crowley
Summary: In this tutorial review, the general methods for synthesizing heterometallic metallosupramolecular architectures (MSAs), specifically heterometallic cages, are examined. The intrinsic properties and potential applications of these cages as host-guest systems and reaction catalysts are discussed.
CHEMICAL SOCIETY REVIEWS
(2024)
Article
Chemistry, Inorganic & Nuclear
Lynn S. Lisboa, Mie Riisom, Henry J. Dunne, Dan Preston, Stephen M. F. Jamieson, L. James Wright, Christian G. Hartinger, James D. Crowley
Summary: A new [PdPtL4](4+) heterobimetallic cage containing hydrazone linkages was synthesized using the sub-component self-assembly approach. The cage showed stimulus-responsive behavior and was more stable against hydrolysis compared to a previously synthesized imine-containing cage. It interacted with cisplatin, while the smaller imine cage interacted with 5-fluorouracil and oxaliplatin.
DALTON TRANSACTIONS
(2022)
Article
Chemistry, Inorganic & Nuclear
Vaibhav Bedi, Dipendu Mandal, Zahid Hussain, Shi-Ming Chen, Yile Wu, Zheng-Wang Qu, Stefan Grimme, Douglas W. Stephan
Summary: The reaction of (tBuO(2)CN)(2) with 9-BBN leads to the formation of a bicyclic heterocyclic compound, while its reactions with BF3 or [Et3Si][B(C6F5)(4)] result in the isolation of different compounds. Computational studies reveal that the steric and electronic properties of the Lewis acid are important in the formation of one of the compounds.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Chisa Itoh, Haruka Yoshino, Taku Kitayama, Wataru Kosaka, Hitoshi Miyasaka
Summary: A new synthetic route for constructing functional paddlewheel diruthenium(II,II) complexes was developed, utilizing Schiff base condensation reactions. The attached Schiff base groups significantly affected the electronic states of the resulting complexes, as revealed by cyclic voltammetry and DFT calculations.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Danrui Ni, Haozhe Wang, Xianghan Xu, Weiwei Xie, Robert J. Cava
Summary: A layered rhombohedral polymorph of indium(iii) triiodide is synthesized at high pressure and temperature. It has an orange color, which is different from ambient pressure InI3, which has a monoclinic molecular structure and a light-yellow color.
DALTON TRANSACTIONS
(2024)
Review
Chemistry, Inorganic & Nuclear
Juan Carlos Perez-Sanchez, Raquel P. Herrera, M. Concepcion Gimeno
Summary: Gold(II) complexes have been less utilized in catalysis compared to their gold(I) and gold(III) counterparts. However, gold(II) complexes offer potential in homo-coupling and cross-coupling reactions, as they are more easily accessible through simplified oxidation and reduction processes. Gold(II) exhibits characteristics of both soft acid gold(I) and hard acid gold(III). This review explores the unique reactivity and potential applications of gold(II) species, highlighting their significance in catalytic transformations.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Nighat Yousuf, Yanping Ma, Qaiser Mahmood, Wenjuan Zhang, Yizhou Wang, Hassan Saeed, Wen-Hua Sun
Summary: In this study, a series of structurally rigid cyclooctyl-fused iminopyridine iron complexes were synthesized and used with methylaluminoxane for isoprene polymerization. The extent of steric hindrance of the ligand framework was found to significantly affect catalytic performance, with less hindrance leading to better activity and stability.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Chenghao Song, Huiwei Du, Menglei Xu, Jie Yang, Xinyu Zhang, Jungan Wang, Yuanfang Zhang, Chengjun Gu, Rui Li, Tao Hong, Jingji Zhang, Jiangying Wang, Yongchun Ye
Summary: This study improves the performance of perovskite solar cells by using a dual-hole transport layer strategy. This strategy enhances the charge transfer efficiency of the transport layer, reduces charge recombination, and improves the quality of the perovskite film layer. Ultimately, the stability of the device is enhanced.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Mahender Singh, Aakash Yadav, Ranjit Singh, Chullikkattil P. Pradeep
Summary: A new aryl selenonium polyoxometalate hybrid was developed and compared with an aryl sulfonium polyoxometalate hybrid in terms of their photocatalytic properties. It was found that the aryl selenonium hybrid exhibited better catalytic performance, which could be attributed to the larger atomic radii of selenium stabilizing the photogenerated electron-hole pair more efficiently. Additionally, the generation of elemental selenium through cleavage of C-Se bonds during catalysis was observed.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Yuhan Xie, Boyu Dong, Xuemin Wang, Siyuan Wang, Jinxi Chen, Yongbing Lou
Summary: This study successfully fabricated visible-light-responsive three-dimensional core-shell CoSe2/ZnIn2S4 heterostructures and achieved attractive activity in photocatalytic hydrogen evolution. The presence of CoSe2 improved light absorption and accelerated charge transfer kinetics. The strong interaction between CoSe2 and ZnIn2S4 reduced charge recombination, further enhancing photocatalytic activity for hydrogen evolution.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Andre L. de O. Batista, Joao Marcos T. Palheta, Mauricio J. Piotrowski, Celso R. C. Rego, Diego Guedes-Sobrinho, Alexandre C. Dias
Summary: This study presents a simulation protocol that provides a solid foundation for exploring two-dimensional materials. Using the TiBr2 2H monolayer as an example, the study reveals its promising properties for optoelectronic and valleytronic applications, including its stability, spin-orbit coupling effects, and optical helicity selection rule.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Jiang Jiang, Zi-Wei Li, Zhi-Zhuan Zhang, Bin Tan, Zhao-Feng Wu, Xiao-Ying Huang
Summary: In this work, two metal organic frameworks (MOFs) containing {Cu2I2} clusters, Eu-CuI-INA and Sr-K-CuI-INA, were synthesized and characterized. Both materials have a three-dimensional structure with {Cu2I2} clusters coordinated by INA(-) ligands and Eu3+ or Sr2+ ions. The Sr-K-CuI-INA material exhibited sensitive fluorescence sensing behaviors towards cysteine and nitro-bearing molecules, showing potential applications in bio and explosive molecule sensing. This work provides a good reference for designing fluorescent MOF probes containing CuI molecules.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Zhiya Lin, Jiasheng Wu, Qianwen Ye, Yulong Chen, Hai Jia, Xiaohui Huang, Shaoming Ying
Summary: Na-ion batteries (NIBs) have attracted great interest as a potential technology for grid-scale energy storage due to the wide distribution, low cost, and environmental friendliness of sodium resources. However, their implementation is hindered by low rate capability and cycling stability caused by the large ionic size of Na+. In this study, a three-dimensional nanoarchitectured coral-like CoSe2@N-doped carbon (CL-CoSe2@NC) was synthesized, and it exhibited improved sodium storage properties with better electrode kinetics and a stable SEI film.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Ya-Qiong Zhang, Yu Zhang, Guoping Zeng, Rong-Zhen Liao, Man Li
Summary: The mechanism and selectivity of CO2 reduction under visible light were investigated using density functional calculations. The results showed that a tetradentate PNNP-type Iridium(III) complex exhibited high activity and selectivity in the reaction.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Sanyukta Ghosh, Shubhanth Jain, Soumya Ranjan Mishra, Gerda Rogl, Peter Rogl, Ernst Bauer, B. S. Murty, A. Govindaraj, Ramesh Chandra Mallik
Summary: In this study, reduced graphene oxide (rGO) was uniformly dispersed in the In0.5Co4Sb12 bulk material by ultrasonication, which effectively reduced the lattice thermal conductivity and improved the thermoelectric efficiency.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Mika Takeuchi, Yutaka Amao
Summary: This study developed an effective visible-light driven system for fumaric acid production using renewable resources such as biomass derivatives, providing an alternative to the current petroleum-based synthesis methods.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Juan Jian, Meiting Wang, Zhuo Wang, Jingwen Meng, Yuqin Yang, Limin Chang
Summary: Developing low-cost and self-supported bifunctional catalysts is crucial for highly efficient water splitting devices. In this study, nano-NiFe2O4 was directly grown onto iron foil surface and Sn4+ was introduced into the NiFe2O4. The resulting Sn-NiFe2O4/IF showed low overpotentials and high current densities during oxygen evolution reaction (OER) and hydrogen evolution reaction (HER), making it a promising catalyst for large-scale hydrogen production.
DALTON TRANSACTIONS
(2024)
