期刊
DALTON TRANSACTIONS
卷 -, 期 42, 页码 9101-9109出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b906588a
关键词
-
资金
- National Natural Science Foundation of China [20602003]
- Beijing Municipal Commission of Education
The development of catalysts for intramolecular asymmetric alkene hydroamination has been investigated extensively over the past two decades, since the hydroamination is a highly atom economical process in which an amine N-H bond is added to an unsaturated carbon-carbon bond leading to the formation of nitrogen heterocycles that are building blocks in numerous biologically and pharmacologically active compounds. The organolanthanide catalysts have been shown to be promising in this area. This perspective highlights the recent progress in the development of organolanthanide catalysts with chiral biaryl-backbones for the asymmetric hydroamination/cyclization of non-activated alkenes.
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