期刊
DALTON TRANSACTIONS
卷 -, 期 27, 页码 5278-5280出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b906169j
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-
资金
- National Science Foundation [EAR 05015600]
- U.S. Department of Energy [DE-FG03-96ER14629, DE-FG03-02ER15693]
- Australian Academy of Sciences
The rate and activation parameters for oxygen exchange of the mu(3)-oxo bridges in a manganese tetranuclear cluster with (H2O)-O-18 have been measured by ESI-MS; the observed Delta S double dagger of -146 +/- 22 J K-1 mol(-1) is consistent with the expected associative mechanism of substitution.
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