4.7 Article

Unprecedented cubane-type silver cluster with a novel phosphinite functionalized N-heterocyclic carbene ligand

期刊

DALTON TRANSACTIONS
卷 -, 期 35, 页码 7288-7293

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/b911439d

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  1. China Scholarship Council
  2. French Embassy in Beijing
  3. CNRS
  4. Ministere de la Recherche (Paris)
  5. IFP

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A novel heterodifunctional phosphinite imidazolium salt was synthesized and reacted with Ag(I) to afford an unusual tetrasilver cubane-type cluster with two P-NHC ligands bridging between the Ag(I) centres of opposite Ag2I2 faces.

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