Article
Biochemical Research Methods
Fady Nahra, Nikolaos Tzouras, Alba Collado, Steven P. Nolan
Summary: N-heterocyclic carbene gold(I) chloride and hydroxide complexes are commonly used as synthetic reagents and efficient catalysts. This study describes a straightforward and practical method for synthesizing mononuclear gold complexes with high yields, as well as the synthesis of a mononuclear gold(I) hydroxide complex and an improved synthesis method for a dinuclear gold(I) hydroxide complex. This methodology offers advantages such as the use of sustainable reaction solvents and commercially available starting materials.
Review
Chemistry, Applied
Xiaoqun Yang, Yi Zhang, Tingting Li, Zhichao Jin
Summary: This review discusses the activations of carbonyl compounds bearing cyclopropyl, epoxyl, azirine, and aziridinyl groups by N-heterocyclic carbene (NHC) organic catalysts. The reactions are introduced and discussed based on the activation modes involved in these transformations. A brief summary of the achievements and challenges in the NHC-catalyzed activation of cyclopropanes and their analogues is provided, along with our perspectives on the future development in this highly active research field.
ADVANCED SYNTHESIS & CATALYSIS
(2023)
Article
Chemistry, Multidisciplinary
Gargi Kundu, V. S. Ajithkumar, K. Vipin Raj, Kumar Vanka, Srinu Tothadi, Sakya S. Sen
Summary: In this study, we synthesized a 6-membered saturated NHC borane adduct and investigated its reactivity. The results showed that the adduct could undergo electrophilic halogenation to form NHC boryl iodides, which further reacted with various nucleophiles to yield novel boranes with different functional groups. Additionally, the adduct reacted with Br-2/H2O to produce a dihydroxyborenium cation.
CHEMICAL COMMUNICATIONS
(2022)
Article
Chemistry, Inorganic & Nuclear
Tereza Duskova, Dharmendra S. Prajapati, Pavel Kaule, Lucie Cervenkova Stastna, Tomas Strasak, Jan Cermak
Summary: A series of imidazolium salts with specific substituents were synthesized and used as precursors for the synthesis of rhodium and iridium complexes. The complexes exhibited high fluorophilicity, making them suitable for organic-organic and organic-fluorous phase separation.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2023)
Article
Chemistry, Applied
Vanessa Vethacke, Vanessa Claus, Martin C. Dietl, Daniel Ehjeij, Arne Meister, Jonas F. Huber, Leon K. Paschai Darian, Matthias Rudolph, Frank Rominger, A. Stephen K. Hashmi
Summary: A variety of unsymmetric diaryl gold N-acyclic carbene (NAC) complexes were successfully synthesized by three different methods, allowing access to new complexes and overcoming previous limitations in the isonitrile route. These new complexes also proved to be successful as pre-catalysts in gold-catalyzed phenol synthesis.
ADVANCED SYNTHESIS & CATALYSIS
(2022)
Article
Chemistry, Inorganic & Nuclear
Gal Segalovich-Gerendash, Mark Baranov, N. Gabriel Lemcoff, Ravindra S. Phatake
Summary: This study describes the synthesis, characterization, and catalytic properties of four new cis-dichlorido ruthenium dithioacetal-chelated complexes. The X-ray structures of the complexes confirm their cis-dichloro configurations, similar to sulfur-chelated benzylidenes. Systematic investigation on the catalytic activity of these complexes for RCM and ROMP reactions provides insights into the impact of dithioacetal chelation on latency and activation behavior.
Article
Chemistry, Inorganic & Nuclear
Dinh Cao Huan Do, Han Vinh Huynh
Summary: This study attempted to synthesize Pd complexes of different types and found that subtle variations in the N-substituents on the NacAc backbone can affect the chelating mode. Computational studies further confirmed these findings and revealed the impact of different substituents on the energy profiles of the complexes.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Paul Zaby, Jan Blasius, Anna K. Mueller, Steven P. Nolan, Oldamur Holloczki
Summary: The formation mechanism of metal-N-heterocyclic carbene (NHC) complexes from imidazolium salts in the presence of weak bases was investigated through theoretical methods. Quantum chemical calculations revealed that both sodium acetate and trimethylamine facilitate complex formation. Molecular dynamics simulations showed that the ionic nature of the [AuCl2](-) and imidazolium ions, as well as the sodium acetate base, keep these species associated in the reaction mixture through ion pairing. The neutral amine, however, remains mostly separated from the other reaction partners, making it a significantly less effective base.
CHEMISTRY-A EUROPEAN JOURNAL
(2023)
Article
Chemistry, Multidisciplinary
Ichraf Slimani, Serap Sahin-Bolukbasi, Mustafa Ulu, Enes Evren, Nevin Gurbuz, Ilknur Ozdemir, Naceur Hamdi, Ismail Ozdemir
Summary: A series of rhodium(i) complexes with N-heterocyclic carbene ligands showed high in vitro cytotoxic activity against human cancer cells, with complex 2b exhibiting the most selective cytotoxic activity. These complexes demonstrated greater cytotoxicity against cancer cells compared to established anticancer agents cisplatin and 5-fluorouracil.
NEW JOURNAL OF CHEMISTRY
(2021)
Review
Chemistry, Inorganic & Nuclear
Sai Zhao, Zhibing Yang, Guizhi Jiang, Sheng Huang, Mianli Bian, Yunlong Lu, Wukun Liu
Summary: NHCs have been introduced as a new platform for the development of anticancer metal complexes, with platinum NHC complexes showing comparable activities to cisplatin and exhibiting different mechanisms of action, including the induction of biochemical hallmarks of immunogenic cell death (ICD) as a type II ICD inducer. These features make them promising candidates in the field of anticancer research.
COORDINATION CHEMISTRY REVIEWS
(2021)
Article
Chemistry, Inorganic & Nuclear
Clemens Kaussler, Darren Wragg, Claudia Schmidt, Guillermo Moreno-Alcantar, Christian Jandl, Johannes Stephan, Roland A. Fischer, Stefano Leoni, Angela Casini, Riccardo Bonsignore
Summary: This study focuses on improving the design of metal complexes as stabilizers of noncanonical DNA secondary structures. A series of cyclic dinuclear Au(I) N-heterocyclic carbene complexes based on xanthine and benzimidazole ligands have been synthesized and characterized. The compounds show stabilization properties towards G-quadruplexes (G4s) and moderate antiproliferative activity in human cancer cells. The binding modes and free energy landscape of the most active compound have been studied using metadynamics.
INORGANIC CHEMISTRY
(2022)
Review
Chemistry, Inorganic & Nuclear
Moushakhi Ghosh, Shabana Khan
Summary: This article highlights the recent developments in silylene-coinage metal chemistry, focusing on synthetic approaches, unusual properties, and catalytic efficiency of these complexes. Further research is needed to explore the potential of silylene-coinage metal complexes in various chemical reactions.
DALTON TRANSACTIONS
(2021)
Review
Chemistry, Applied
Eve M. Poland, Curtis C. Ho
Summary: This Minireview presents recent developments in photoactive/photoluminescent N-heterocyclic carbene (NHC) transition metal complexes and discusses their viability as catalysts in bond-forming photocatalysis. Key structural motifs and photophysical properties of these complexes are summarized. Representative examples of their applications as catalysts in bond-forming photochemical reactions are showcased, highlighting the state-of-the-art and future opportunities for this exciting class of NHC transition metal complexes.
APPLIED ORGANOMETALLIC CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Kajal Balayan, Himanshu Sharma, Kumar Vanka, Sapna Ravindranathan, Rajesh G. Gonnade, Sakya S. Sen
Summary: The combination of 6-SIDipp center dot AlH3 (1) and 5-IDipp leads to the expansion of 6-NHC ring, while the five-membered NHC remains unchanged. This phenomenon is further explained by DFT studies. Moreover, the substitution chemistry of compound 1 with TMSOTf and I-2 results in the replacement of a hydride by triflate or iodide ligands.
CHEMICAL COMMUNICATIONS
(2023)
Review
Chemistry, Multidisciplinary
Zikun Wang, Nikolaos V. Tzouras, Steven P. Nolan, Xihe Bi
Summary: Silver N-heterocyclic carbenes (Ag-NHCs) have good biocompatibility and are widely used in medicine and coordination chemistry, but their coordination with silver can weaken the Lewis acidity of Ag(I), resulting in slow development as catalysts. Future opportunities lie in further research on the catalytic mechanisms of Ag-NHCs to enhance their catalytic activity.
TRENDS IN CHEMISTRY
(2021)
Article
Crystallography
Tesfamariam K. Hagos, Stefan D. Nogai, Liliana Dobrzanska, Stephanie Cronje, Helgard G. Raubenheimer
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
(2010)
Article
Crystallography
Christoph E. Strasser, Stephanie Cronje, Helgard G. Raubenheimer
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
(2010)
Article
Crystallography
Christoph E. Strasser, Stephanie Cronje, Helgard G. Raubenheimer
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
(2011)
Article
Crystallography
Christoph E. Strasser, Leigh-Anne de Jongh, Helgard G. Raubenheimer, Stephanie Cronje
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
(2011)
Article
Crystallography
Christoph E. Strasser, Stephanie Cronje, Helgard G. Raubenheimer
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
(2011)
Article
Crystallography
Tesfamariam K. Hagos, Stefan D. Nogai, Liliana Dobrzanska, Stephanie Cronje, Helgard G. Raubenheimer
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
(2011)
Article
Chemistry, Inorganic & Nuclear
Jacorien Coetzee, Stephanie Cronje, Liliana Dobrzanska, Helgard G. Raubenheimer, Gisela Joone, Margo J. Nell, Heinrich C. Hoppe
DALTON TRANSACTIONS
(2011)
Article
Chemistry, Multidisciplinary
Liliana Dobrzanska, Elzet Stander-Grobler, Christoph E. Strasser, Stephanie Cronje, Helgard G. Raubenheimer
HELVETICA CHIMICA ACTA
(2012)
Article
Chemistry, Inorganic & Nuclear
Elzet Stander-Grobler, Christoph E. Strasser, Oliver Schuster, Stephanie Cronje, Helgard Raubenheimer
INORGANICA CHIMICA ACTA
(2011)
Article
Biochemistry & Molecular Biology
Ulrike E. I. Horvath, Liliana Dobrzanska, Christoph E. Strasser, Wilna Bouwer (nee Potgieter), Gisela Joone, Constance E. Jansen van Rensburg, Stephanie Cronje, Helgard G. Raubenheimer
JOURNAL OF INORGANIC BIOCHEMISTRY
(2012)
Article
Chemistry, Inorganic & Nuclear
Elzet Stander-Grobler, Oliver Schuster, Greta Heydenrych, Stephanie Cronje, Evangeline Tosh, Martin Albrecht, Gernot Frenking, Helgard G. Raubenheimer
Article
Chemistry, Inorganic & Nuclear
Elzet Stander-Grobler, Oliver Schuster, Christoph E. Strasser, Martin Albrecht, Stephanie Cronje, Helgard G. Raubenheimer
Article
Chemistry, Inorganic & Nuclear
William F. Gabrielli, Stefan D. Nogai, Margo Nell, Stephanie Cronje, Helgard G. Raubenheimer
Article
Chemistry, Inorganic & Nuclear
Liliana Dobrzanska, Gerrit R. Julius, Elzet Stander-Grobler, Yolanda Burger (Nee Stander), Stefan D. Nogai, Stephanie Cronje, Helgard G. Raubenheimer
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
(2012)
Article
Chemistry, Inorganic & Nuclear
Leigh-Anne de Jongh, Liliana Dobrzanska, Christoph E. Strasser, Helgard G. Raubenheimer, Stephanie Cronje
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
(2014)
Article
Chemistry, Inorganic & Nuclear
Vaibhav Bedi, Dipendu Mandal, Zahid Hussain, Shi-Ming Chen, Yile Wu, Zheng-Wang Qu, Stefan Grimme, Douglas W. Stephan
Summary: The reaction of (tBuO(2)CN)(2) with 9-BBN leads to the formation of a bicyclic heterocyclic compound, while its reactions with BF3 or [Et3Si][B(C6F5)(4)] result in the isolation of different compounds. Computational studies reveal that the steric and electronic properties of the Lewis acid are important in the formation of one of the compounds.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Chisa Itoh, Haruka Yoshino, Taku Kitayama, Wataru Kosaka, Hitoshi Miyasaka
Summary: A new synthetic route for constructing functional paddlewheel diruthenium(II,II) complexes was developed, utilizing Schiff base condensation reactions. The attached Schiff base groups significantly affected the electronic states of the resulting complexes, as revealed by cyclic voltammetry and DFT calculations.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Danrui Ni, Haozhe Wang, Xianghan Xu, Weiwei Xie, Robert J. Cava
Summary: A layered rhombohedral polymorph of indium(iii) triiodide is synthesized at high pressure and temperature. It has an orange color, which is different from ambient pressure InI3, which has a monoclinic molecular structure and a light-yellow color.
DALTON TRANSACTIONS
(2024)
Review
Chemistry, Inorganic & Nuclear
Juan Carlos Perez-Sanchez, Raquel P. Herrera, M. Concepcion Gimeno
Summary: Gold(II) complexes have been less utilized in catalysis compared to their gold(I) and gold(III) counterparts. However, gold(II) complexes offer potential in homo-coupling and cross-coupling reactions, as they are more easily accessible through simplified oxidation and reduction processes. Gold(II) exhibits characteristics of both soft acid gold(I) and hard acid gold(III). This review explores the unique reactivity and potential applications of gold(II) species, highlighting their significance in catalytic transformations.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Nighat Yousuf, Yanping Ma, Qaiser Mahmood, Wenjuan Zhang, Yizhou Wang, Hassan Saeed, Wen-Hua Sun
Summary: In this study, a series of structurally rigid cyclooctyl-fused iminopyridine iron complexes were synthesized and used with methylaluminoxane for isoprene polymerization. The extent of steric hindrance of the ligand framework was found to significantly affect catalytic performance, with less hindrance leading to better activity and stability.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Chenghao Song, Huiwei Du, Menglei Xu, Jie Yang, Xinyu Zhang, Jungan Wang, Yuanfang Zhang, Chengjun Gu, Rui Li, Tao Hong, Jingji Zhang, Jiangying Wang, Yongchun Ye
Summary: This study improves the performance of perovskite solar cells by using a dual-hole transport layer strategy. This strategy enhances the charge transfer efficiency of the transport layer, reduces charge recombination, and improves the quality of the perovskite film layer. Ultimately, the stability of the device is enhanced.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Mahender Singh, Aakash Yadav, Ranjit Singh, Chullikkattil P. Pradeep
Summary: A new aryl selenonium polyoxometalate hybrid was developed and compared with an aryl sulfonium polyoxometalate hybrid in terms of their photocatalytic properties. It was found that the aryl selenonium hybrid exhibited better catalytic performance, which could be attributed to the larger atomic radii of selenium stabilizing the photogenerated electron-hole pair more efficiently. Additionally, the generation of elemental selenium through cleavage of C-Se bonds during catalysis was observed.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Yuhan Xie, Boyu Dong, Xuemin Wang, Siyuan Wang, Jinxi Chen, Yongbing Lou
Summary: This study successfully fabricated visible-light-responsive three-dimensional core-shell CoSe2/ZnIn2S4 heterostructures and achieved attractive activity in photocatalytic hydrogen evolution. The presence of CoSe2 improved light absorption and accelerated charge transfer kinetics. The strong interaction between CoSe2 and ZnIn2S4 reduced charge recombination, further enhancing photocatalytic activity for hydrogen evolution.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Andre L. de O. Batista, Joao Marcos T. Palheta, Mauricio J. Piotrowski, Celso R. C. Rego, Diego Guedes-Sobrinho, Alexandre C. Dias
Summary: This study presents a simulation protocol that provides a solid foundation for exploring two-dimensional materials. Using the TiBr2 2H monolayer as an example, the study reveals its promising properties for optoelectronic and valleytronic applications, including its stability, spin-orbit coupling effects, and optical helicity selection rule.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Jiang Jiang, Zi-Wei Li, Zhi-Zhuan Zhang, Bin Tan, Zhao-Feng Wu, Xiao-Ying Huang
Summary: In this work, two metal organic frameworks (MOFs) containing {Cu2I2} clusters, Eu-CuI-INA and Sr-K-CuI-INA, were synthesized and characterized. Both materials have a three-dimensional structure with {Cu2I2} clusters coordinated by INA(-) ligands and Eu3+ or Sr2+ ions. The Sr-K-CuI-INA material exhibited sensitive fluorescence sensing behaviors towards cysteine and nitro-bearing molecules, showing potential applications in bio and explosive molecule sensing. This work provides a good reference for designing fluorescent MOF probes containing CuI molecules.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Zhiya Lin, Jiasheng Wu, Qianwen Ye, Yulong Chen, Hai Jia, Xiaohui Huang, Shaoming Ying
Summary: Na-ion batteries (NIBs) have attracted great interest as a potential technology for grid-scale energy storage due to the wide distribution, low cost, and environmental friendliness of sodium resources. However, their implementation is hindered by low rate capability and cycling stability caused by the large ionic size of Na+. In this study, a three-dimensional nanoarchitectured coral-like CoSe2@N-doped carbon (CL-CoSe2@NC) was synthesized, and it exhibited improved sodium storage properties with better electrode kinetics and a stable SEI film.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Ya-Qiong Zhang, Yu Zhang, Guoping Zeng, Rong-Zhen Liao, Man Li
Summary: The mechanism and selectivity of CO2 reduction under visible light were investigated using density functional calculations. The results showed that a tetradentate PNNP-type Iridium(III) complex exhibited high activity and selectivity in the reaction.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Sanyukta Ghosh, Shubhanth Jain, Soumya Ranjan Mishra, Gerda Rogl, Peter Rogl, Ernst Bauer, B. S. Murty, A. Govindaraj, Ramesh Chandra Mallik
Summary: In this study, reduced graphene oxide (rGO) was uniformly dispersed in the In0.5Co4Sb12 bulk material by ultrasonication, which effectively reduced the lattice thermal conductivity and improved the thermoelectric efficiency.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Mika Takeuchi, Yutaka Amao
Summary: This study developed an effective visible-light driven system for fumaric acid production using renewable resources such as biomass derivatives, providing an alternative to the current petroleum-based synthesis methods.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Juan Jian, Meiting Wang, Zhuo Wang, Jingwen Meng, Yuqin Yang, Limin Chang
Summary: Developing low-cost and self-supported bifunctional catalysts is crucial for highly efficient water splitting devices. In this study, nano-NiFe2O4 was directly grown onto iron foil surface and Sn4+ was introduced into the NiFe2O4. The resulting Sn-NiFe2O4/IF showed low overpotentials and high current densities during oxygen evolution reaction (OER) and hydrogen evolution reaction (HER), making it a promising catalyst for large-scale hydrogen production.
DALTON TRANSACTIONS
(2024)