期刊
CURRENT OPINION IN CHEMICAL BIOLOGY
卷 22, 期 -, 页码 40-46出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.cbpa.2014.09.011
关键词
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资金
- Swiss National Science Foundation [2-7786613]
- European Union's 7th Framework Marie-Curie Intra European Fellowship Program
Within this review article we describe recent developments in asymmetric catalysis with peptides. Numerous peptides have been established in the past two decades that catalyze a wide variety of transformations with high stereoselectivities and yields, as well as broad substrate scope. We highlight here catalytically active peptides, which have addressed challenges that had thus far remained elusive in asymmetric catalysis: enantioselective synthesis of atropoisomers and quaternary stereogenic centers, regioselective transformations of polyfunctional substrates, chemoselective transformations, catalysis in-flow and reactions in aqueous environments.
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