Article
Energy & Fuels
Aycan Atli, Abdullah Yildiz
Summary: An opaque platinum film as a counter electrode in dye-sensitized solar cells demonstrates enhanced reflectivity, smaller resistance, and excellent adhesion properties. As a result, the DSSC with the opaque platinum film achieves a higher electrical power conversion efficiency compared to the transparent platinum film under the same conditions.
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
(2022)
Article
Energy & Fuels
Andi Zhao, Shiqi Huang, Jianting Huang, Ping Hu, Haijuan Mao, Caiyun Chen, Yafeng Li, Mingdeng Wei
Summary: Pt nanoparticles are deposited on nickel foam via a mild displacement reaction at room temperature, producing efficient and flexible Pt counter electrodes for dye-sensitized solar cells (DSSCs). By prolonging the reaction time, the catalytic activities of the Pt counter electrode can be enhanced. The approach is facile and can be scaled up for large production of efficient flexible counter electrodes in DSSCs.
Article
Engineering, Electrical & Electronic
Sowbakkiyavathi Elindjeane Sheela, Ramkumar Sekar, Dheeraj Kumar Maurya, Manidurai Paulraj, Subramania Angaiah
Summary: Dye-sensitized solar cells (DSSCs) are equipped with a counter electrode (CE) that collect electrons and catalyze the iodide/triiodide (I-/I3-) redox reaction. Platinum (Pt) has traditionally been used as the CE material, but its high cost and corrosion issues have prompted researchers to explore alternative materials. This review focuses on the recent advancements in using binary and ternary transition metal chalcogenides (TMC) and their composites as efficient CEs in Pt-free DSSCs.
MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING
(2023)
Article
Green & Sustainable Science & Technology
Nadia Shahzad, Lutfullah, Tahira Perveen, Diego Pugliese, Sirajul Haq, Nusrat Fatima, Syed Muhammad Salman, Alberto Tagliaferro, Muhammad Imran Shahzad
Summary: Efficiency, stability, and cost-effectiveness are the prime challenges in research of materials for solar cells. This study explores carbon nanotubes as alternative counter electrode materials for dye-sensitized solar cells (DSSCs) and discusses various classes of carbon nanotube-based counter electrode materials comprehensively. The properties associated with these materials are analyzed and compared. Additionally, this study includes a brief overview of materials for other components of DSSCs.
RENEWABLE & SUSTAINABLE ENERGY REVIEWS
(2022)
Review
Chemistry, Multidisciplinary
Xiuwen Wang, Bing Zhao, Wei Kan, Ying Xie, Kai Pan
Summary: The photoelectric conversion efficiency of dye-sensitized solar cells can be remarkably improved by optimizing the catalytic activity and charge transfer ability of the counter electrode materials. By designing multifunctional materials and other strategies, the photovoltaic performance of DSSCs based on low-cost counter electrode materials can be further improved.
ADVANCED MATERIALS INTERFACES
(2022)
Article
Materials Science, Multidisciplinary
J. Luo, J. C. Liu, Z. Q. Zhao, S. H. Sun, Y. Zhu, Y. M. Hu
Summary: Orthogonal Cu3SnS4 (CTS) nano-crystals were synthesized, with Cu7S4 seeds forming first at 130 degrees C and orthorhombic CTS nano-crystals forming at 180 degrees C. Selenization at 500 degrees C for 20 minutes resulted in the formation of CTSXSe4-X, which showed good conductivity and electrocatalytic activity for I-3(-) reduction when used as counter electrodes in dye-sensitized solar cells. The optimal 1.7 μm thick CTSXSe4-X counter electrode achieved a power conversion efficiency of 7.57%.
Article
Chemistry, Physical
Abdullah Yildiz, Takwa Chouki, Aycan Atli, Moussab Harb, Sammy W. Verbruggen, Rajeshreddy Ninakanti, Saim Emin
Summary: Transition metal phosphides, particularly the Fe2P phase, show comparable solar-to-current conversion efficiency with platinum (Pt) as a counter electrode in dye-sensitized solar cells (DSSCs) while exhibiting improved stability, making them a promising Pt-free alternative for efficient DSSCs.
ACS APPLIED ENERGY MATERIALS
(2021)
Article
Chemistry, Physical
P. Baskaran, K. D. Nisha, S. Harish, H. Ikeda, J. Archana, M. Navaneethan
Summary: This study focused on enhancing the electrochemical properties of CZTS by compositing it with MoS2 to replace Pt as a counter electrode in dye-sensitized solar cells. The addition of MoS2 in CZTS nanocomposites resulted in improved charge transfer performance and catalytic activity, with the best results observed at 8wt% MoS2 content.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Energy & Fuels
Subashini Gnanasekar, Quyet Van Le, Andrews Nirmala Grace
Summary: The study successfully synthesized template-free vanadium nitride nanopetals and found that they exhibit excellent catalytic performance and power conversion efficiency when used as a counter electrode in dye sensitized solar cells.
Article
Engineering, Electrical & Electronic
Yiqi Zhang, Bao Zhou, Liang Luo, Zaixin Xie, Zhuoqi Duan, Yongmao Hu
Summary: In this study, Sn-alloyed Cu2O was used as a potential alternative material for the counter electrode in dye-sensitized solar cells. It was found that Sn-alloyed Cu2O can increase the specific surface area of electron transport and decrease the band gap of the film through the annealing process. The reaction time of Sn alloying has a significant influence on the photoelectric conversion efficiency of the cells.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2022)
Article
Chemistry, Multidisciplinary
Belqasem Aljafari, Subbiah Vijaya, Arash Takshi, Sambandam Anandan
Summary: This study explores manganese dioxide (MnO2) and copper-doped manganese dioxide (Cu-MnO2) nanoparticles as candidates for the counter electrode (CE) material in dye-sensitized solar cells (DSSCs), aiming to provide low-cost alternatives to platinum (Pt). Experimental results show that DSSC devices fabricated with 10 wt% Cu-MnO(2) as CE exhibit better performance. The low-cost feature of using Cu-MnO(2) as CE is encouraging for further research in improving the efficiency of DSSCs with alternative CEs.
ARABIAN JOURNAL OF CHEMISTRY
(2022)
Article
Chemistry, Physical
U. A. Kamarulzaman, M. Y. A. Rahman, M. S. Su'ait, A. A. Umar
Summary: NiPd alloy-rGO prepared by LPD technique was studied as CE for DSSC, showing potential to replace Pt with comparable efficiency. Ni content and Ni:Pd ratio were found to significantly influence the device performance.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Energy & Fuels
Sajid Ali Ansari, Souraya Goumri-Said, Hemraj M. Yadav, Moussaab Belarbi, Abdullah Aljaafari, Mohammed Benali Kanoun
Summary: The research focused on developing alternative counter electrodes for dye-sensitized solar cells (DSSC) using simple methods. The NiCo2S4 counter electrode showed comparable photovoltaic performance to the platinum-based counter electrode, potentially due to its high electrocatalytic activity and small nanoparticle size providing increased surface area and catalytic sites. A theoretical model based on electrical considerations was used to study the impact of physical parameters on DSSC performance and efficiency, with the model accurately reproducing DSSC characteristics.
SOLAR ENERGY MATERIALS AND SOLAR CELLS
(2021)
Article
Physics, Applied
Mathew K. Francis, P. Balaji Bhargav, N. Santhosh, Nafis Ahmed, C. Balaji, R. Govindaraj
Summary: MoS2-based transition metal dichalcogenide nanoflowers were synthesized using the hydrothermal method in this study to examine their potential as a counter electrode in dye-sensitized solar cells (DSSCs). MoS2-HCP counter electrode showed better electrochemical performance with 5% power conversion efficiency achieved. The bifacial concept of DSSC was demonstrated with 2.2% power conversion efficiency under rear-side illumination.
JOURNAL OF PHYSICS D-APPLIED PHYSICS
(2021)
Article
Materials Science, Multidisciplinary
G. Syrrokostas, K. Bhorkar, L. Sygellou, V. Dracopoulos, G. Leftheriotis, S. N. Yannopoulos
Summary: In this study, it is demonstrated that PtSe2 films, prepared by soft selenization of pre-deposited Pt, are highly efficient counter electrodes (CEs) in dye sensitized solar cells (DSSCs). Devices based on PtSe2 achieve better photoconversion efficiency (9.5±1.2%) compared to those using bare Pt CE (9.18±0.21%), even with lower Pt loading. The improved performance of PtSe2 CEs is attributed to the higher availability of catalytic active sites and more effective mechanism of interfacial electron transfer.
MATERIALS CHEMISTRY AND PHYSICS
(2023)
Article
Chemistry, Physical
Yandong Duan, Nianqing Fu, Sibai Li, Xiaoyang Yang, Jiaxin Zheng, Yuan Lin, Feng Pan
JOURNAL OF MATERIALS CHEMISTRY A
(2017)
Article
Chemistry, Physical
Xiaohe Song, Tongchao Liu, Joseph Amine, Yandong Duan, Jiaxin Zheng, Yuan Lin, Feng Pan
Article
Chemistry, Physical
Jiaxin Zheng, Wenjun Deng, Zongxiang Hu, Zengqing Zhuo, Fusheng Liu, Haibiao Chen, Yuan Lin, Wanli Yang, Khalil Amine, Rui Li, Jun Lu, Feng Pan
ACS ENERGY LETTERS
(2018)
Article
Chemistry, Physical
Pin Ma, Jing Tan, Hongbo Cheng, Yanyan Fang, Yanan Wang, Yuhua Dai, Shibi Fang, Xiaowen Zhou, Yuan Lin
APPLIED SURFACE SCIENCE
(2018)
Article
Physics, Multidisciplinary
Dongmei Xie, Xiaowen Tang, Yuan Lin, Pin Ma, Xiaowen Zhou
Article
Electrochemistry
Pin Ma, Yanyan Fang, Hongbo Cheng, Yanan Wang, Xiaowen Zhou, Shibi Fang, Yuan Lin
ELECTROCHIMICA ACTA
(2018)
Article
Electrochemistry
Jianguang Jia, Lili Mu, Yuan Lin, Xiaowen Zhou
ELECTROCHIMICA ACTA
(2018)
Article
Chemistry, Inorganic & Nuclear
Guangxing Zhang, Han Wang, Jinlong Yang, Qinghe Zhao, Luyi Yang, Hanting Tang, Chaokun Liu, Haibiao Chen, Yuan Lin, Feng Pan
INORGANIC CHEMISTRY
(2018)
Article
Chemistry, Physical
Lumei Peng, Houxun Hong, Yanli Shi, Xiaowen Zhou, Yuan Lin, Jianguang Jia
JOURNAL OF ALLOYS AND COMPOUNDS
(2018)
Article
Chemistry, Physical
Zongwei Mei, Yehuan Li, Xiaoyang Yang, Wenju Ren, Shengfu Tong, Ning Zhang, Wenguang Zhao, Yuan Lin, Feng Pan
CATALYSIS SCIENCE & TECHNOLOGY
(2018)
Article
Chemistry, Multidisciplinary
Pin Ma, Wenli Lu, Xiaoying Yan, Weidan Li, Li Li, Yanyan Fang, Xiong Yin, Zhengang Liu, Yuan Lin
Article
Chemistry, Multidisciplinary
Jiaxin Zheng, Guoyu Tan, Peng Shan, Tongchao Liu, Jiangtao Hu, Yancong Feng, Luyi Yang, Mingjian Zhang, Zonghai Chen, Yuan Lin, Jun Lu, Joerg C. Neuefeind, Yang Ren, Khalil Amine, Lin-Wang Wang, Kang Xu, Feng Pan
Article
Chemistry, Physical
Yongsheng Li, Ziwei Chen, Rui Zhou, Wenguang Zhao, Mu Li, Jun Chen, Zhongyuan Huang, Jian Liu, Yuhang Li, Maolin Yang, Minghan Yu, Dong Zhou, Yuan Lin, Feng Pan
Summary: A simple method was developed to synthesize microcrystalline spherical silver particles with internal pores, and their excellent sintering activity and ability to improve silver-silicon contact were found. These particles showed a low series resistance and high photoelectric conversion efficiency in solar cells.
Article
Chemistry, Physical
Jiaduo Wang, Zhuo Dong, Jiajun Wang, Junwei Zhang, Zeyu Zhai, Fazheng Qiu, Jinpeng Wu, Yuan Lin, Jingbo Zhang
Summary: The performance of perovskite solar cells is affected by the conductivity and energy alignment of the electron transport layer. In this study, high-quality amorphous TiO2 thin films were produced using vacuum ultraviolet light and combined with SnO2 to improve electron mobility and conductivity. The composite electron transport layer enhanced electron extraction and achieved high power conversion efficiency and excellent light stability.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Chemistry, Physical
Dongmei Xie, Yuan Lin, Nianqing Fu, Pin Ma, Xiaowen Zhou
JOURNAL OF MATERIALS CHEMISTRY A
(2018)
Article
Materials Science, Multidisciplinary
Honggyun Kim, Jamal Aziz, Vijay D. Chavan, Deok-kee Kim
Summary: Silicon nitride films were prepared using plasma enhanced chemical vapor deposition with different trap densities induced by adjusting the RF power ratio. It was found that the film's trap density was lowest under compressive stress and increased under tensile stress. This study has significant implications for the formation of durable nitride films in various electronic and optoelectronic applications.
CURRENT APPLIED PHYSICS
(2024)
Article
Materials Science, Multidisciplinary
Qiang Yu, Huwei Zhao, Yue Zhao
Summary: Zinc oxide thin films and Al-doped zinc oxide films were prepared and characterized in this study. The addition of Al ions was found to change the growth orientation, increase the grain size, and enhance the absorption intensity in the visible light region. Furthermore, the addition of Al ions also increased the forward current in the heterojunction.
CURRENT APPLIED PHYSICS
(2024)
Article
Materials Science, Multidisciplinary
Sang Woo Lee, Min Sun Park, Sangwon Wi, So Yeon Lim, Yeseul Lee, Jin-Seok Chung, Sang Mo Yang
Summary: In this study, we investigated the dynamics of domain switching in pristine and fatigued BiFeO3 capacitors through experimental observations and measurements. The results showed that the switching in the pristine capacitors was dominantly driven by domain growth, while the fatigued capacitors exhibited two different switching dynamics, in which nucleation played a critical role.
CURRENT APPLIED PHYSICS
(2024)
Article
Materials Science, Multidisciplinary
Boshi Wang, Tianyi Wang, Yufang Liu, Kun Yu
Summary: In this paper, a tunable and anisotropic perfect absorber composed of anisotropic black phosphorus (BP) and isotropic graphene is proposed. The structure exhibits high absorption and strong anisotropic plasma response. The resonance characteristics can be effectively controlled by adjusting geometric parameters and doping levels, offering potential applications.
CURRENT APPLIED PHYSICS
(2024)
Article
Materials Science, Multidisciplinary
Xiaolan Liu, Chunyang Li, Tonghui Yang, Naiqiang Yin, Gangling Zhao
Summary: Water drop triboelectric nanogenerators (WD-TENGs) can harvest energy from raindrops and improve the output performance of TENGs.
CURRENT APPLIED PHYSICS
(2024)