4.7 Article

Mass production of SiC/SiOx nanochain heterojunctions with high purities

期刊

CRYSTENGCOMM
卷 15, 期 15, 页码 2986-2991

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ce27019j

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资金

  1. 973 program [2012CB326407]
  2. National Natural Science Foundation of China (NSFC) [51072084, 51002083, 51075217]
  3. Zhejiang Provincial Science Foundation for Distinguished Young Scholars [R4100242]
  4. Zhejiang Provincial Natural Science Foundation of China (ZJSFC) [Y4110529, Y1100528]

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The purity and yield issues are significant challenges for the practical applications of nanoheterojunctions in functional devices. In the present work, we report the mass production of SiC/SiOx nanochain heterojunctions via pyrolysis of polymeric precursors. The as-synthesized nanochain heterojunctions were characterized by X-ray diffraction (XRD), field-emission scanning electron microscopy (FESEM) and high-resolution transmission electron microscopy (HRTEM). The composition of the raw materials played a critically important role in the formation of SiC/SiOx nanochain heterojunctions. As compared to the reported works, our synthesized SiC/SiOx nanochain heterojunctions exhibit much higher purities with a very uniform size distribution and fascinating microstructures, which make them promising to be utilized as optoelectronic nanodevices.

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