Article
Materials Science, Ceramics
Ilker Cetin Keskin
Summary: Dy3+, Nd3+, Sm3+ doped Y2O3 nanophosphors were synthesized using the sol-gel method. The structural and optical changes of the doped nanophosphors were compared using XRD and SEM techniques. Radioluminescence and thermoluminescence behaviors were also studied. The study provides insights into the properties and potential applications of these nanophosphors.
CERAMICS INTERNATIONAL
(2022)
Article
Chemistry, Physical
Kaiming Zhu, Zhanglin Chen, Hui Liu, Xin Yi, Yihuan Wang, Junjie Chen, Xuanyi Yuan, Guanghua Liu
Summary: A series of CaAlSiN3:Ln (Ln=Eu, Ce, Dy, Pr, Tb, Gd, Sm, Tm, Nd) phosphors were successfully prepared by combustion synthesis, and their polychromatic visible afterglow emissions were observed. CaAlSiN3:Eu2+ and CaAlSiN3:Ce3+ showed the best red and yellow long persistent luminescence with persistent times of 4980 s and 4860 s, respectively. Eu2+, Ce3+ co-doped CaAlSiN3 exhibited enhanced red long persistent luminescence with a persistent time of 6300 s, attributed to a more appropriate trap depth distribution.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Physical
Ilya E. Kolesnikov, Daria V. Mamonova, Mikhail A. Kurochkin, Vassily A. Medvedev, Gongxun Bai, Evgenii Yu. Kolesnikov
Summary: The structural and luminescence properties of Dy3+- and Sm3+-doped LaVO4 concentration series were studied for their potential application as temperature sensors. Nanocrystalline phosphors were synthesized and demonstrated multimode thermal sensing based on the temperature-induced red shift of the charge transfer band. The best thermometric performance was observed for LaVO4:Sm3+ 2 at% sample, with a sensitivity of Sr = 2.07 % K 1 and a resolution of ΔT = 0.2 K at room temperature.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Optics
Yuxuan Luo, Danyu Zhang, Shujun Xu, Lianjie Li, Liping Chen, Hai Guo
Summary: YNbO4 (YNO):Bi3+,Ln3+ (Ln = Dy, Eu) phosphors were synthesized by high-temperature solid-phase reaction and their structural properties, optical characteristics, and energy transfer mechanisms were analyzed. The phosphors showed broad emission from Bi3+ ions and sharp peaks from Ln3+ ions, making them suitable for optical thermometry. The YNO:Bi3+,Ln3+ phosphors exhibited high sensitivity and superior thermochromic properties in temperature sensing, with maximum absolute sensitivities and relative sensitivities reaching significant values.
JOURNAL OF LUMINESCENCE
(2023)
Article
Materials Science, Ceramics
N. L. Jayalekshmy, Annamma John, Jijimon K. Thomas, Sam Solomon
Summary: In this study, Ln(2)(MO4)(3) (Ln = La and Sm; M = W and Mo) nanomaterials were synthesized using the auto ignited combustion method. The synthesized materials were characterized using various techniques and it was found that they had a monoclinic structure and spherical shape with narrow size distribution. The conductivity studies revealed oxide ion and mixed electron-proton conduction in the prepared materials.
JOURNAL OF THE AUSTRALIAN CERAMIC SOCIETY
(2023)
Article
Materials Science, Multidisciplinary
Marikumar Rajendran, Kasturi Singh, Sivakumar Vaidyanathan
Summary: The study synthesized Sm3+-activated deep red phosphors for plant growth and LED fabrication, showing good emission performance and thermal stability through PXRD, SEM, and FT-IR analyses to verify their phosphor structure, morphology, and chemical composition.
JOURNAL OF INFORMATION DISPLAY
(2021)
Article
Chemistry, Physical
Xiaoqing Guo, Shuangju Song, Xue Jiang, Jingru Cui, Yunshuai Li, Wenqing Lv, Haiyan Liu, Yuanyuan Han, Liyong Wang
Summary: A room temperature coprecipitation method for synthesizing phosphors was reported, with SiO2 modification increasing emission intensity. Multicolor phosphors were designed by changing lattice activators. The study also demonstrated the development of transparent photoluminescent film and assembly of red emission LED devices with the prepared phosphors.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Engineering, Environmental
Junpeng Xue, Zhongkai Yu, Hyeon Mi Noh, Bo Ram Lee, Byung Chun Choi, Sung Heum Park, Jung Hyun Jeong, Peng Du, Mingjun Song
Summary: The article discusses the preparation of LaNbO4:1.0%Bi3+/x%Ln(3+) (Ln = Eu, Tb, Dy, Sm) phosphors by solid-state reaction technology, which can emit both Bi3+ and Ln(3+) ions emissions, resulting in multi-color emissions. By taking advantage of the different thermal quenching properties between Bi3+ and Ln(3+) ions, the optical thermometric characteristics of the compounds were evaluated.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Chemistry, Inorganic & Nuclear
Juan H. Mecchia Ortiz, Daiana Cabrosi, Carlos Cruz, Veronica Paredes-Garcia, Pablo Albores
Summary: The synthesis and structural characterization of triangle-in-triangle {Cr(3)Ln(3)} complexes with Gd and Dy has been successfully achieved, showing strong antiferromagnetic interaction and slow relaxation of magnetization in magnetic measurements. The suppression of quantum tunnelling pathways was observed, with possible Raman and Orbach relaxation mechanisms established.
DALTON TRANSACTIONS
(2022)
Article
Materials Science, Multidisciplinary
Li Ye Cao, Meng Yang, Le Wang, Yong Li, Bi Xia Gao, Lei Wang, Jia Lun Liu, Ai Fang Fang, You Guo Shi, Rong Yan Chen
Summary: The interaction among nontrivial topology, symmetry breaking orders, and strong electron correlation in LnSbTe compounds leads to a variety of exotic physical phenomena, such as charge-density wave (CDW) orders and the Kondo effect. Optical spectroscopic measurements reveal metallic responses in all four compounds, with varying CDW gaps.
Article
Chemistry, Inorganic & Nuclear
Gopabandhu Panigrahi, Subhendu Jana, Mohd Ishtiyak, S. Narayanswamy, Pinaki P. Bhattacharjee, K. V. Ramanujachary, Manish K. Niranjan, Jai Prakash
Summary: Three new isostructural quaternary tellurides, Ba(2)Ln(1-x)Mn(2)Te(5) (Ln = Pr, Gd, and Yb), were synthesized by the molten-flux method at 1273 K, and they crystallize in the monoclinic crystal system with partially filled Ln sites. These structures do not contain any homoatomic or metallic bonding.
DALTON TRANSACTIONS
(2021)
Article
Chemistry, Physical
Nikolai Kuzmin, Victor Maltsev, Elizaveta Mikliaeva, Elena Volkova, Kirill Boldyrev, Elizaveta Koporulina
Summary: Isothermal sections of the Ln(2)O(3)-Cr2O3-B2O3 (Ln = Gd-Lu) ternary oxide systems at different temperatures were determined using powder X-ray diffraction, and were divided into subsidiary subsystems. Two types of double borates, LnCr(3)(BO3)(4) (Ln = Gd-Er) and LnCr(BO3)(2) (Ln = Ho-Lu), were observed. The stability regions and structural properties of these compounds were characterized using powder X-ray diffraction and thermal analysis.
Article
Chemistry, Multidisciplinary
Ekaterina Orlova, Timofei Sorokin, Alexander Pustovit, Egor Baldin, Elena Zakharova, Elena Kharitonova, Nikolay Lyskov, Valentina Utochnikova, Olga Alekseeva, Valentina Voronkova
Summary: Fluorine-containing rare earth compounds of the LiLn(4)Mo(3)O(15)F composition were synthesized using solid-phase synthesis. Luminescence, hygroscopic, and electrophysical characteristics of the LiEu4Mo3O15F phase were studied for the first time. The replacement of europium with lithium and oxygen with fluorine led to a reversible phase transition and a significant increase in conductivity. The size of the Ln cation was found to affect the hygroscopic and conductive properties of LiLn(4)Mo(3)O(15)F compounds.
NEW JOURNAL OF CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Girbide Amitkumar Ramakant, Naushad Ahmed, Ibtesham Tarannum, Sakshi Mehta, Muneshwar Nandeshwar, Abhishake Mondal, Saurabh Kumar Singh, Ganesan Prabusankar
Summary: LnIII {Ln = Dy (1_Dy), Gd (2_Gd), and La (3_La)} benzimidazolium tricarboxylate coordination polymers have been synthesized and studied for their magnetic properties. These coordination polymers exhibit one-dimensional structure with spiral arrangement in the solid state. One of the compounds showed characteristics of single-molecule magnets at low temperatures.
CRYSTAL GROWTH & DESIGN
(2022)
Article
Materials Science, Multidisciplinary
Bing Zhao, Feng Chen, Jingjing Ru, Feiyun Guo, Jianzhong Chen
Summary: A series of color-tunable Li2Y4(MoO4)(7): Ln(3+) (Ln = Dy, Eu) phosphors were prepared through solid-state reaction, with emission color ranging from pale yellow to nearly white by adjusting concentrations or excitation wavelength. The results suggest that Li2Y4(MoO4)(7): Ln(3+) (Ln = Dy, Eu) may be used as color-tunable phosphors.
ECS JOURNAL OF SOLID STATE SCIENCE AND TECHNOLOGY
(2021)
Article
Chemistry, Analytical
Yang-Bao Miao, Hong-Xia Ren, Ning Gan, You Zhou, Yuting Cao, Tianhua Li, Yinji Chen
ANALYTICA CHIMICA ACTA
(2016)
Article
Chemistry, Analytical
You Zhou, Qian Yang, Jing Cuan, Yanan Wang, Ning Gan, Yuting Cao, Tianhua Li
Article
Chemistry, Analytical
Qian Yang, Lingying Zhou, Yong-Xiang Wu, Kai Zhang, Yuting Cao, You Zhou, Dazhen Wu, Futao Hu, Ning Gan
ANALYTICA CHIMICA ACTA
(2018)
Article
Chemistry, Analytical
You Zhou, Qian Yang, Denan Zhang, Ning Gan, Qiuping Li, Jing Cuan
SENSORS AND ACTUATORS B-CHEMICAL
(2018)
Article
Chemistry, Analytical
You Zhou, Denan Zhang, Jin Zeng, Ning Gan, Jing Cuan
Article
Chemistry, Multidisciplinary
Jing Cuan, You Zhou, Tengfei Zhou, Shigang Ling, Kun Rui, Zaiping Guo, Huakun Liu, Xuebin Yu
ADVANCED MATERIALS
(2019)
Article
Chemistry, Analytical
You Zhou, Denan Zhang, Wenzhe Xing, Jing Cuan, Yuhua Hu, Yuting Cao, Ning Gan
ANALYTICAL CHEMISTRY
(2019)
Article
Chemistry, Multidisciplinary
Jing Cuan, You Zhou, Jian Zhang, Tengfei Zhou, Gemeng Liang, Sean Li, Xuebin Yu, Wei Kong Pang, Zaiping Guo
Article
Engineering, Environmental
Jing Cuan, Denan Zhang, Wenzhe Xing, Jingjing Han, Hui Zhou, You Zhou
Summary: Confining metal-halide perovskites within hierarchically porous MOF hosts enables high loading capacities, uniform distribution, and enhanced stability. The obtained CsPbX3@MOF nano-composites show bright luminescence and good resistance to ambient moisture, UV light irradiation, and anion-exchange. Integration with InGaN LED chips leads to a primary WLED with high color quality values, highlighting its potential in backlight display applications.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Chemistry, Physical
Wenzhe Xing, Hui Zhou, Jingjing Han, You Zhou, Ning Gan, Jing Cuan
Summary: By utilizing dye encapsulation engineering within a dual-emitting MOF hybrid, researchers have developed a high-quality white-light emitter that can emit light from blue to white to orange. This hybrid demonstrates excellent stability and optoelectronic performance, making it a promising material for applications in displays and solid-state lighting.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2021)
Article
Engineering, Environmental
Hui Zhou, Jingjing Han, Jing Cuan, You Zhou
Summary: Smart stimuli-responsive luminescent metal-organic frameworks (MOFs) have gained significant development in recent years due to their unique advantages and exciting application prospects. These materials have the ability to respond to external chemical or physical stimuli in various ways, making them highly attractive in anti-counterfeiting technologies. This review summarizes the recent progress in stimuli-responsive luminescent MOF materials for advanced anti-counterfeiting technologies, including the different types of stimuli and the mechanisms of their responsive luminescence. The implementation strategies and future perspectives for advanced anti-counterfeiting using these materials are also discussed.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Analytical
Jingjing Han, Yangbao Miao, Jing Cuan, Hui Zhou, Shihao Zhu, Zixian Wu, You Zhou
Summary: The study proposes a novel strategy to achieve solid-state luminescence turn-on sensing by assembling reporter-spacer-receptor (RSR) architectures within MOF frameworks. Unlike regular RSR systems, the framework-confined fluorophore and receptor are well arranged and separated even in the solid state. This study demonstrates a sensitive solid-state luminescence turn-on probe for phosphate by utilizing a multicomponent MOF (Fc@NU-1000) with a quencher displacement-based RSR system, offering new opportunities for MOF materials in developing luminescence turn-on sensors.
ANALYTICAL CHEMISTRY
(2023)
Article
Nanoscience & Nanotechnology
Xinhang Cong, Jingjing Han, Jing Cuan, Zixian Wu, Shihao Zhu, Qiuping Li, You Zhou
Summary: This study presents a strategy for designing luminescence turn-on sensors for residual antibiotic tetracycline (TC) detection using metal-organic frameworks (MOFs). The competitive interactions and verification by high-resolution mass spectrometry, photo-luminescence, and UV-vis spectroscopy enable sensitive and quantitative determination of TC, which can be visually detected by the naked eye and smartphone color-scanning app.
ACS APPLIED NANO MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Jing Cuan, Hui Zhou, Xuefang Huang, Xinhang Cong, You Zhou
Summary: This study presents a material capable of solid-state multicolor luminescence switching in response to hydro-photo-thermo stimuli. The material is constructed by immobilizing Eu3+ and methyl viologen cations within a MOF framework. The hybrid exhibits rapid and reversible PL color-switching in response to water simulation and photo-thermo stimuli. The potential of this material in advanced anticounterfeiting applications is demonstrated.
Article
Biophysics
Ye Wang, Ning Gan, You Zhou, Tianhua Li, Yuting Cao, Yinji Chen
BIOSENSORS & BIOELECTRONICS
(2017)
Article
Chemistry, Multidisciplinary
Abu Talha Aqueel Ahmed, Sankar Sekar, Shubhangi S. Khadtare, Nurul Taufiqu Rochman, Bathula Chinna, Abu Saad Ansari
Summary: In this study, MnCo2S4 nanosheet catalyst was successfully synthesized and found to exhibit superior performance in hydrogen evolution. Compared to MnCo2S4, MnCo2S4 showed low overpotentials, moderate Tafel slope, and excellent sustainability. The outstanding performance can be attributed to the increased number of electrochemically active sites and enhanced electronic conductivity on the catalyst surface.
Article
Chemistry, Multidisciplinary
Victor V. Maltsev, Elena A. Volkova, Elizaveta V. Koporulina, Diana D. Mitina, Vladimir L. Kosorukov, Anna I. Jiliaeva, Daniil A. Naprasnikov, Konstantin N. Gorbachenya, Viktor E. Kisel
Summary: The phase relationships, crystal properties and luminescence kinetics of two complex systems were studied, including unit cell parameters, segregation coefficients of impurities, and lifetimes of energy levels.
Article
Chemistry, Multidisciplinary
Xiaoman Zhang, Wangwang Xu, W. J. Meng, Andrew C. Meng
Summary: This study successfully grew high-quality single crystal AlScN nanowires through ultra-high vacuum reactive sputtering technique and characterized their structure and properties. The nanowires exhibit significantly reduced mosaic spread and predominantly single ferroelectric domains, as well as a high piezoelectric constant.
Article
Chemistry, Multidisciplinary
Tom E. de Vries, Elias Vlieg, Rene de Gelder
Summary: Networks are important for describing relationships between people, roads between cities, reactions between chemicals, and other interactions. Bipartiteness, dividing the network into two groups, can facilitate the study of the network's structure. We have developed an algorithm that can find a near-optimal bipartisation within a reasonable time frame and used it to uncover the hidden structure of the CSD cocrystal network.
Article
Chemistry, Multidisciplinary
Chuchu Han, Jing Yang, Xin Zhang, Aisen Li, Jiang Peng
Summary: An elastic crystal based on a photo-reactive acylhydrazone derivative is reported, which exhibits reversible bending behavior under UV irradiation and heating. The crystal undergoes reversible E<->Z isomerization under light and heating conditions. The crystal demonstrates excellent elastic properties and the bending can be controlled to control the output direction of red light.
Article
Chemistry, Multidisciplinary
Lingfeng Zhang, Yu Wang, Yefeng Wang, Shuai Liu, Na Zhang, Mingmin Yang, Haixia Ma, Zhaoqi Guo
Summary: This study designs and synthesizes a series of high-energy salts compounds without heavy metal ions and azide groups. The molecular structures and stability of the compounds are confirmed through single-crystal X-ray diffraction and intermolecular interaction analysis. Furthermore, the thermal stability, energetic properties, and electrical initiation properties of the compounds are investigated, suggesting their potential as primary explosives.