4.7 Article

Synthesis and field emission properties of silicon carbide nanobelts with a median ridge

期刊

CRYSTENGCOMM
卷 14, 期 20, 页码 6755-6760

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ce25579k

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资金

  1. National Natural Science Foundation of China [50972063, 51172115]
  2. Natural Science Foundation of Shandong Province [ZR2011EMZ001, ZR2011EMQ011]
  3. Tackling Key Program of Science and Technology in Shandong Province [2012GGX10218]
  4. Innovation Fund of Science and Technology Intensive Small-and-Medium-Sized Enterprises of Ministry of Science and Technology [10C26213712086]
  5. Key Technology Major Research Plan in Qingdao [09-1-4-21-gx]

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beta-Silicon carbide (beta-SiC) nanobelts with a median ridge have been synthesized for the first time via a template/catalyst-free chemical vapor reaction (CVR) method. The characterization results show that the beta-SiC nanobelts with widths of 1.5 mu m and thickness of about 10-20 nm consist of nanowires with rough surfaces in diameters of 100 nm (median ridge) and two symmetrical lateral flakes with uniform width. A reasonable two-step Vapor-Solid (TSVS) growth mechanism is proposed to explain the formation of the nanobelts on the basis of crystal growth theory. Using the beta-SiC nanobelts as the cathode, the result of field-emission measurements shows that the turn-on field and threshold field of the beta-SiC nanobelts are about 3.2 V mu m(-1) and 5.7 V mu m(-1), respectively. These features make the beta-SiC nanobelts a promising candidate for field emission displays. The beta-SiC nanobelts obtained in this work enrich the family of silicon carbides nanostructures; moreover, the method and growth mechanism could be an effective clue and example for the synthesis of belt-like nanostructures of other materials.

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