期刊
CRYSTENGCOMM
卷 14, 期 2, 页码 366-369出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1ce06273e
关键词
-
资金
- NSF of China [20801040]
New macrocyclic oxamide complexes suitable for being used as metalloligands to link metal ions were designed. Six coordination compounds containing a member of the new metalloligands as the bridging ligand were prepared. X-ray single crystal analysis revealed that the six compounds include a dodecanuclear structure, three 1D helical chainlike coordination polymers and two 2D layered coordination polymers. All of the nickel centres of the metalloligands in the six compounds are exposed on both sides of the corresponding square coordination planes, and all the bonds (Ni-N) formed by the open metal sites are significantly short (ranging from 1.848 to 1.888 angstrom). Thermogravimetric analysis of four of the six compounds showed that their thermal stabilities differ to a considerable extent and that the Na+-containing dodecanuclear structure, which began to decompose at ca. 400 degrees C, has the highest thermal stability.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据