期刊
CRYSTENGCOMM
卷 14, 期 5, 页码 1770-1774出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ce06156b
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资金
- Swiss National Science Foundation
- University of Basel
- Novartis Foundation
- Ciba-Geigy Jubilee Foundation
The reaction of NiCl2 center dot 6H(2)O with 4'-tert-butyl-4,2':6',4 ''-terpyridine (1) in MeOH/1,2-Cl2C6H4 leads to the formation of the 2-dimensional coordination polymer 4[Ni2Cl4(1)(4)]center dot 13(1,2-Cl2C6H4)center dot 30H(2)O. Each sheet comprises [4 + 4] macrocycles interconnected by octahedral trans-{NiCl2N4} nodes. In the presence of C-60, NiCl2 center dot 6H(2)O and ligand 1 combine in MeOH/1,2-Cl2C6H4 to give crystalline solvated 3 [NiCl2(1)(2)]center dot C-60 which has a lamellar structure intercalated with C-60 molecules. The fullerene templates the formation of [3 + 3] bowl-shaped macrocycles which are connected through octahedral trans-{NiCl2N4} nodes to [6 + 6] macrocycles generating 2-dimensional sheets.
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