4.7 Article

Triangular prism-shaped p-type 6H-SiC nanowires

期刊

CRYSTENGCOMM
卷 14, 期 2, 页码 488-491

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1ce05873h

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资金

  1. Zhejiang Provincial Science Foundation for Distinguished Young Scholars [R4100242]
  2. National Natural Science Foundation of China (NSFC) [50872058, 51072084, 50572083]
  3. Natural Science Foundation of Ningbo Municipal Government [2011A610182]

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We report, for the first time, the growth of p-type 6H-SiC nanowires with a unique triangular prism shape via the pyrolysis of polymeric precursors. The resultant wires were systematically characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and high-resolution transmission electron microscopy (HRTEM). The triangular prism-shaped SiC nanowires are averagely sized at similar to 700 nm in edge widths with lengths of up to tens of microns. The wires are single-crystalline with 1 at % Al dopants and grown along the direction of [102]. A mechanism based on a typical vapor-liquid-solid (VLS) process was discussed for the growth of the 6H-SiC wires. Intense visible photoluminescence was observed with two respective strong emission peaks centered at 2.4 and 3.1 eV, suggesting that the p-type 6H-SiC wires could be useful in the fabrication of optoelectronic nanodevices.

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