期刊
CRYSTENGCOMM
卷 14, 期 12, 页码 4119-4125出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ce06649a
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资金
- DFG [SPP 1362, STO-643/5-1]
- European Community [228862]
- European Regional Development Fund in the framework of the Polish Innovation Economy Operational Program [POIG.02.01.00-12023/08]
Aluminium trimellitate [Al(OH)(BDC-COOH)]center dot 0.9H(2)O (1), the Al-MIL-53-COOH derivative, was discovered under solvothermal conditions using a high-throughput set-up suitable for microwave (MW)-assisted heating. The compound shows high structural flexibility. The large-pore (lp) form of the framework is obtained under large excess of H2O or after solvothermal treatment with N,N-dimethylformamide upon which [Al(OH)(BDC-COOH)]center dot 0.7DMF (2) is obtained. Exposure of the water rich lp form of 1 to ambient conditions leads to the transformation to the narrow-pore (np) form. Thermal activation of both compounds results in the formation of the empty lp form and the activation of 1 was studied in detail by in situ IR-spectroscopy. Depending on the activation temperature and time two post-synthetic modification (PSM) processes are observed: the partial decarboxylation and the formation of acid anhydride groups. Thus at high temperatures and long activation times [Al(OH)(BDC-OCOCO-BDC)(x/2)(BDC)(y)] (x + y = 1) is formed. Upon cooling in air the anhydride functionality still remains intact, but the np form is obtained in air due to the adsorption of H2O molecules. Sorption measurements of 1 confirm a preference for polar gases like H2O and CO2 in comparison to N-2, H-2, and CH4. The N-2 capacity depends strongly on the degree of decarboxylation.
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