期刊
CRYSTENGCOMM
卷 13, 期 22, 页码 6850-6863出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1ce05718a
关键词
-
资金
- National Natural Science Foundation of China [91027003, 21072118, 20871076]
- Shangdong Natural Science Foundation [JQ200803]
Four semirigid symmetric double-armed oxadiazole bridging ligands L1-L4 were designed and synthesized in good yields by reactions of 2,5-bis(2-hydroxyphenyl)-1,3,4-oxadiazole and 2,5-bis(3-hydroxyphenyl)- 1,3,4-oxadiazole with 3-(bromomethyl) benzonitrile and 4-(bromomethyl)benzonitrile, respectively. The coordination chemistry of these four ligands with various Ag(I) salts has been investigated. Eleven discrete, one-and two-dimensional polymeric Ag(I) complexes (1-11) were prepared by solution reactions and characterized by infrared spectroscopy, elemental analysis, and single-crystal X-ray diffraction. Compared to our reported ligands of this type, L1-L4 are more flexible. The ligand conformation and polyatomic anion templating effect play a key role in determining the final supramolecular structures. Compound 6 contains 3D intersecting channels with different interior microenvironments. It can absorb two different types of guest molecules (benzene and THF) independently or take them up simultaneously from a mixture of two kinds of guests. Furthermore, it can completely separate THF/furan and benzene/toluene guest substrates in liquid phase, respectively.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据