期刊
CRYSTENGCOMM
卷 13, 期 19, 页码 5951-5955出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1ce05154g
关键词
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资金
- 973 Program [2007CB815301]
- National Science Foundation of China [21073192, 20733003, 20871114, 20801055]
- Science Foundation of CAS [KJCX2-YW-H20]
- Science Foundation of Fujian Province [2009HZ0006-1, 2006L2005]
A novel coordination polymer [NaMn2(dmdn)(3)(H2O)(6)]center dot 4.5H(2)O (dmdn = 6,6'-dimercaptodinicotinate) (1) was prepared and characterized by single-crystal X-ray diffraction along with powder XRD, IR, elemental analyses and magnetic analyses. Compound 1, featuring a rarely reported 2-fold interpenetrated (4(6),6(9))-hxg network based on the wheel-like clusters ligated by the in situ generated dmdn ligands as the six-connected approximately planar nodes, was obtained by slow evaporation of mna (mna = 6-mercaptonicotinic acid) and NaOH with MnCl2 center dot 4H(2)O in distilled water at room temperature. In addition, the magnetic property of 1 has also been investigated in detail.
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