期刊
CRYSTAL GROWTH & DESIGN
卷 13, 期 5, 页码 1807-1811出版社
AMER CHEMICAL SOC
DOI: 10.1021/cg4000318
关键词
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资金
- National Natural Science Foundation of China [21071087, 91122012, 21171102]
- Special Project of 973 Program [2011CB612306]
- Swedish Research Council (VR)
- Goran-Gustafsson Foundation for Nature Science and Medical Research
- Scientific Research Foundation for the Returned Overseas Chinese Scholars
- Outstanding Dissertation Growth Fundation of Ningbo University [PY2012017]
- Discipline Fund in Ningbo University [XKL11051]
- K. C. Wong MagnaFund at Ningbo University
Two novel Mg-based metal-organic framework isomers with the formula [Mg-2(HCO2)(2)(NH2-BDC)-(DMF)(2)](n) (NH2-BDC = 2-amino-1,4-benzenedicarboxylate) have been synthesized based on a 6-connected [24-MC-6] metallacrown secondary building unit (SBU), which display a two-dimensional (2D) 3(6) net (1) and three-dimensional primitive rhombohedral net (2) derived from a different extended orientation of SBU, respectively. The 2D framework of 1 exhibits relevant thermal stability, solvents stability, high CO2 adsorption, and strong luminescent properties.
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