期刊
CRYSTAL GROWTH & DESIGN
卷 12, 期 7, 页码 3786-3791出版社
AMER CHEMICAL SOC
DOI: 10.1021/cg3006162
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资金
- National Natural Science Foundation of China [21075064, 21027013, 21021062, 90813020]
- National Basic Research Program of China [2007CB925102]
Spheres-like coordination polymer architectures in submicro regimes have been synthesized from the hydrothermal reaction of transition metal ions and 3,5-bis(pyridin-3-ylmethylamino)benzoic acid (L1). The size of the final coordination polymer was dependent on the concentrations of reactants. Scanning electron microscopy studies monitored at numerous stages of growth reveal that coordination-induced morphology changes from uncoordinated flowerlike ligands to sphere-like coordination polymer particles. Moreover, variations of luminescent and antibacterial profiles are associated with coordination environments or the size of as-obtained coordination polymer samples. In addition, the newly synthesized Cu-based polymer particles may act as novel metal-based anticancer drugs in the future because of their potent in vitro anticancer activities against three chosen cancer lines MCF-7, HeLa, and NCI-H446.
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