期刊
CRYSTAL GROWTH & DESIGN
卷 13, 期 1, 页码 74-90出版社
AMER CHEMICAL SOC
DOI: 10.1021/cg3011629
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资金
- Department of Science and Technology (DST), New Delhi
- CSIR
The present work shows the syntheses, structures, and hydrogen-bonding-based self-assembly of Co3+ coordination complexes containing appended arylcarboxylic acid groups. The carboxylic acid groups are present at either the para or the meta position of the appended arene ring. Every Co3+ coordination complex offers both hydrogen-bond donors (in O-H groups of atylcarboxylic acid) and acceptors (in C=O-amide groups as well as C=O-acid of arylcarboxylic acid) in a single molecule. As a consequence, all molecules self-assemble in a highly complementary and unique structural fashion via an array of inter- and intramolecular hydrogen bonding. The position of carboxylic acid, presence of cation, type of cation, and solvent of crystallization has significantly affected/altered the self-assembly process of complementary functional groups.
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