期刊
CRYSTAL GROWTH & DESIGN
卷 11, 期 6, 页码 2398-2403出版社
AMER CHEMICAL SOC
DOI: 10.1021/cg200490v
关键词
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资金
- NSFC [20821001, 50872157, 90922009]
- 973 Project [2007CB815305]
- NSF of Guangdong Province [9151027501000048]
The axially chiral conformations of 2,2'-bipyridine are, for the first time, captured and isolated in individual crystals of a new family of three-dimensional coordination polymers [Mn(II)(2,2'-bpy)(HCO2)(2-x)(N-3)(x)] (x = 0.3-0.7) upon an unusual spontaneous resolution. Furthermore, the Mn(II)center dot center dot center dot Mn(II) magnetic exchange can be tuned by control of the ratio of N-3(-)/HCO2-.
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