4.7 Article

Bulk Re2C Crystal Structure, Hardness, and Ultra-incompressibility

期刊

CRYSTAL GROWTH & DESIGN
卷 10, 期 12, 页码 5024-5026

出版社

AMER CHEMICAL SOC
DOI: 10.1021/cg100659g

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资金

  1. NSFC [50872118, 50821001, 91022029]
  2. PCSIRT [IRT0650]
  3. NBRPC [2005CB724400, 2011CB808205]
  4. Natural Science Foundation of Heibei Province of China [E2009000453]

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A hard ultra-incompressible bulk Re2C material is first synthesized under moderate pressure (2-6 GPa) and high temperature (873 -1873 K) The phase composition of Re2C was determined by a chemical analysis method and its structure is finally determined to be a ReB2 type structure by means of X-ray diffraction, Raman technology, and ab initio calculations The hardness measurements show that it is a hard material which can rival ReB2 More impressively its volume incompressibility is comparable with that of diamond and its c axis incompressibility even exceeds that of diamond In the end the P-T phase diagram of the Re-C system has also been determined in the regions of P = 1-6 GPa and T=873-1873 K The moderate synthesis conditions show that this hard ultra incompressible bulk material will obtain the further applications

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