Article
Chemistry, Applied
Zhao-Hao Li, Li-Ping Xue, Shuo Li, Ping-Fang Zang
Summary: Two new photochromic coordination polymers have been synthesized through the regulation of metal-ligand ratios.
Article
Chemistry, Applied
Mei-Li Zhang, Xue-Ying Lu, Ye Bai, Yi-Xia Ren, Ji-Jiang Wang, Xiao-Gang Yang
Summary: Three new Cd(II) coordination polymers with different structures and adsorption capacities have been synthesized as sensitive luminescent sensors for tetracycline. These materials have the potential to remove pollutants from industrial wastewaters, reducing risks to human health and natural ecosystems.
Article
Chemistry, Inorganic & Nuclear
Nannan Yuan, Jinhuan Yu, Yuanyuan Li, Ying Gao, Minghui Zuo, Shuxin Cui
Summary: This article reports a novel coordination polymer based on a new flexible viologen ligand, and investigates its photosensitivity and photocontrolled luminescence properties.
INORGANIC CHEMISTRY COMMUNICATIONS
(2022)
Article
Chemistry, Inorganic & Nuclear
Vasile Lozovan, Victor Ch. Kravtsov, Natalia Costriucova, Anatolii Siminel, Olga Kulikova, Marina S. Fonari
Summary: Cd(II) and Zn(II) coordination polymers based on a dicarboxylic azine chromophore were successfully synthesized and studied using spectroscopic and X-ray diffraction methods. The organic chromophore showed dual emission in the high and low energy regions of the spectrum. The emission properties of the coordination polymers could be tuned and showed excellent sensing of solvated dmso.
JOURNAL OF SOLID STATE CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Zhi-Ming Yuan, Ze-Xu Lin, Shui-Lian Chen, Xin Lin
Summary: Two coordination polymers involving Cd(II) were studied for their preventive effect and mechanism on scar formation after cosmetic surgery. The complexes were found to inhibit the viability of human immortal keratinocytes and affect the VEGF signal pathway in cells.
JOURNAL OF CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Tomoyuki Mochida, Syou Maekawa, Ryo Sumitani
Summary: A study was conducted to explore ionic liquids with stimuli-responsiveness based on linkage isomerization, resulting in the synthesis of an ionic liquid containing a cationic half-sandwich thiocyanate complex. The N- and S-coordinated isomers showed small solvatochromic absorption shifts in organic solvents, with different solvent dependencies observed for each isomer.
INORGANIC CHEMISTRY
(2021)
Article
Chemistry, Physical
Xia Wang, Xiang Fang, Xianxian Yuan, Fei Zhang, Jing Yang, Ning Ling, Huaixia Yang
Summary: In this study, two new coordination polymers were synthesized and characterized by X-ray single crystal diffraction analysis, elemental analysis, 1H-NMR spectra, and IR spectra. The results showed that both polymers exhibited outstanding photocatalytic activities in the degradation of MB and RhB, with remarkable efficiencies.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Chemistry, Multidisciplinary
Jia-Hao Gao, Pei-Pei Huang, Jie Liu, Nan Zheng, Dong Wang, Si-Yu Yue, Er-Nu Liu, Quan Liu, Bo Liu, Jiu-Fu Lu
Summary: Three metal coordination polymers with different spatial structures were synthesized by changing the central ion under solvothermal and hydrothermal conditions. They were characterized by various analysis methods. SNUT-12 exhibited excellent electrocatalytic activity, while SNUT-13 and SNUT-14 showed strong fluorescence at room temperature.
ARABIAN JOURNAL OF CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Sujitra Tunsrichon, Sujittra Youngme, Jaursup Boonmak
Summary: Iodo-cadmium(i) complexes with various crystalline architectures were synthesized using a Cd(s) precursor and different iodine solutions. One of the complexes was assembled via a dissolution-recrystallization structural transformation process at room temperature. The complexes also showed structural transformation in different solvents.
Article
Biochemistry & Molecular Biology
Giuseppina D. G. Santonoceta, Carmelo Sgarlata
Summary: The development of novel drug delivery systems with strong antibacterial properties is crucial in response to the increasing resistance to antimicrobial agents. In this study, a pH-responsive cobalt(II)-coordinated assembly containing quercetin and polyacrylic acid is proposed as a drug delivery system. This system releases the model drug in a pH-dependent mode by exploiting the localized acidic environment at the bacterial infection sites under anaerobic conditions. The binding affinities and thermodynamic parameters of the cobalt(II) complexes with quercetin in the presence of polyacrylic acid were investigated, providing essential information for the development of an improved drug delivery system.
Article
Chemistry, Multidisciplinary
Ming-Yue Wen, Li Ren, Guang-Hua Cui
Summary: Two new Co(II) coordination compounds were synthesized and characterized, one displaying a 2D layered network while the other exhibited a dinuclear structure. Both complexes showed high pH stabilities in the range from 3 to 12, and could serve as fluorescence probes for detecting various substances with high quenching constants and low detection limits. The fluorescence sensing mechanisms of the two compounds were discussed in detail.
Article
Chemistry, Multidisciplinary
Yothin Chimupala, Nippich Kaeosamut, Saranphong Yimklan
Summary: A new cationic rectangular zinc(II) metal-organic framework with flexible chainlike and rigid rodlike ligands was successfully synthesized and studied using X-ray diffraction to understand its crystal structure and chemical properties.
CRYSTAL GROWTH & DESIGN
(2021)
Article
Chemistry, Applied
Guang-Li Wang, Jun Wang, Luyi Zhou, Mi Zhou, Xiaoxiong Wang, Shan-He Zhou, Lu Lu, Manoj Trivedi, Abhinav Kumar
Summary: In this study, four new Zn(II)/Cd(II) coordination polymers were synthesized and showed efficient photocatalytic performances in selectively degrading methylene blue among other dyes under UV irradiation. The photocatalytic properties of these materials were investigated using LC-MS studies, band gap calculations, and Hirshfeld surface analysis.
Article
Chemistry, Physical
Halina Gluchowska, Renata Lyszczek, Liliana Mazur, Alexander M. Kirillov
Summary: Two coordination polymers were synthesized using flexible dicarboxylate linkers, resulting in structures with different topologies, including a 3D metal-organic network and a linear chain. The mu(4-) and mu-L2- linkers in the synthesized compounds exhibited different coordination modes, leading to the formation of Co3O4/CoO and NiO as final thermal decomposition products.
Article
Chemistry, Physical
Anirban Karmakar, Anup Paul, Pedro M. R. Santos, Ines R. M. Santos, M. . Fatima C. Guedes da Silva, Armando J. L. Pombeiro
Summary: In this study, two new Cd(II) coordination polymers were synthesized and characterized. These polymers showed good adsorption efficiency for cationic dyes. The adsorption kinetics and isotherms were determined, and in silico studies provided insights into the dye removal mechanism. Additionally, the stability and recyclability of the polymers were tested.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2023)
