Article
Chemistry, Applied
Javier Isaac Contreras-Ramirez, Esperanza Acosta-Gurrola, Walfred Rosas-Flores, Jose Alberto Gallegos-Infante, Jorge Fernando Toro-Vazquez
Summary: This research presents a comparison between differential scanning calorimetry (DSC) and spectrophotometric methods for the study of microstructure in oleogels. The results show that spectrophotometry can be a good alternative to DSC in oleogel crystallization studies when high sensitivity or specific thermal parameters are not required. Differences in the microstructuring process were found between the two methods due to temperature ramp and formulation variables.
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY
(2023)
Article
Thermodynamics
Pixiang Wang, Yifen Wang, Xueqi Wang, Yucheng Peng, Shaoyang Liu
Summary: The crystallization kinetics of isotactic homopolymer polypropylene (HPP), impact copolymer polypropylene (ICPP), and their composites were investigated. The Avrami-Jeziorny and Mo models accurately described the crystallization process. The nucleation activity and crystallization rate were influenced by the content of ICPP, with the highest rate observed at 60% ICPP. The changes in chain mobility and crystal-crystal interactions accounted for the fluctuations in crystallization rate and activation energy.
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
(2023)
Article
Polymer Science
How Wei Benjamin Teo, Kaijuan Chen, Van Thai Tran, Hejun Du, Jun Zeng, Kun Zhou
Summary: This study investigates the shrinkage phenomenon of PA12 during crystallization process, with different cooling rates affecting its crystallization behavior and crystal shrinkage. The crystallization shrinkage of PA12 is found to be closely related to the exothermic reaction during the crystallization process, and XRD suggests that shrinkage are related to crystal growth.
Article
Thermodynamics
J. M. Mata-Padilla, C. A. Avila-Orta, A. Almendarez-Camarillo, J. G. Martinez-Colunga, E. Hernandez-Hernandez, V. J. Cruz-Delgado, P. Gonzalez-Morones, S. G. Solis-Rosales, J. A. Gonzalez-Calderon
Summary: The non-isothermal crystallization behavior of isotactic polypropylene (iPP)/copper nanocomposites with different mass percentages of copper nanoparticles was studied using differential scanning calorimeter (DSC). The results showed that while the incorporation of nanoparticles affected the lamellas size and X-ray diffraction intensity, it did not influence the spherulite size. Additionally, the presence of copper nanoparticles in the iPP matrix significantly increased the thermal conductivity of the nanocomposites, accelerating the crystallization process.
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
(2021)
Article
Polymer Science
Xiaodong Yang, Bin Yu, Hui Sun, Nan Wang, Peng Liu, Jiangli Feng, Xiaogang Cui
Summary: The study investigated the crystallization kinetics, morphology, and structure of ECTFE using DSC, POM, and XRD, revealing various patterns of crystallization processes and changes in crystalline degree.
Article
Engineering, Chemical
Olga Mysiukiewicz, Kamila Salasinska, Mateusz Barczewski, Maciej Celinski, Katarzyna Skorczewska
Summary: This study investigates the influence of adding intumescent flame retardants (IFRs) on the non-isothermal crystallization process of high-density polyethylene (HDPE). The findings show that the degree of crystallinity remains comparable to unmodified HDPE, despite the increase in activation energy. Microscopic analysis reveals an increase in spherulite density for HDPE/IFRs. Moreover, there are no polymorphic changes in the polyethylene according to WAXS analysis.
POLYMER ENGINEERING AND SCIENCE
(2022)
Article
Biochemistry & Molecular Biology
Hongwei Yang, Jianghua Du
Summary: This study investigates the crystallization kinetics of GF/PLA composites by melt blending GFs and PLA. The results show that the presence of GFs significantly promotes PLA crystallization, accelerates the crystallization rate, and shortens the crystallization time. Additionally, the calculation of crystallization activation energy indicates that GFs enhance the crystallization capacity and decrease the effective potential barrier of the composite.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2023)
Article
Food Science & Technology
Yi-Hsiou Tsai, Donyau Chiang, Yu-Ting Li, Tsong-Pyng Perng, Sanboh Lee
Summary: In this study, the properties of sunflower, soybean, olive, and canola oils were examined periodically at different elevated temperatures. It was found that the unsaturated triglyceride in oils reacts significantly with environmental oxygen or water vapor, leading to changes in optical absorbance, viscosity, electrical impedance, and acid value. Olive oil has the lowest rate of color center and dynamic viscosity among the four oils, with the smallest pre-exponential factor and the largest activation energy. The rate constants of the acid reaction in olive oil are the highest among the four oils, with the lowest pre-exponential factor.
Article
Materials Science, Multidisciplinary
Shan Zhang, Chao Wei, Jingwang Lv, Haoran Zhang, Zhilin Shi, Xinyu Zhang, Mingzhen Ma
Summary: The crystallization kinetics of Zr50Cu34Al8Ag8 bulk metallic glass under non-isothermal conditions was studied using differential scanning calorimetry. The activation energies were calculated and the crystallization mechanism was explored, revealing that the crystallization is mainly governed by diffusion-controlled three-dimensional growth.
Article
Materials Science, Multidisciplinary
S. V. Vasiliev, K. A. Svyrydova, N. V. Vasylyeva, V. I. Tkatch
Summary: The non-isothermal crystallization kinetics of Fe48Co32P14B6 glass were experimentally studied using differential scanning calorimetry (DSC) with heating rates ranging from 5 to 40 K/min. A kinetic model combining the Kolmogorov's model and the Kashchiev's transient nucleation approach was derived to describe the interface-controlled mode of crystallization. The experimental DSC scans were accurately approximated using thermodynamic and kinetic parameters derived from analysis of the isothermal crystallization, and the effect of non-stationarity on the thermal stability of metallic glasses was discussed.
Article
Thermodynamics
Akihiko Toda
Summary: A reinterpreted analysis method of the Ozawa model is presented for the non-isothermal kinetics of the nucleation and growth processes of polymer spherulites, allowing for a more reliable determination of the Ozawa index n. The reinterpretation involves expressing crystallinity phi as a term dependent on temperature and scan rates, leading to a continuous curve of phi as a function of T-dependent beta(half)(T) in the reinterpreted Ozawa plot. Experimental examination and numerical calculations confirm the applicability of the reinterpreted Ozawa model for the spherulitic crystallization of poly(vinylidene fluoride).
THERMOCHIMICA ACTA
(2022)
Article
Agricultural Engineering
Aakriti Sood, Rahul Upadhyay, Sushil K. Maurya
Summary: The sustainable and eco-compatible synthesis of important chemicals using renewable feedstocks is a significant area of research. This study demonstrates the synthesis of azelaic acid using non-edible Triadica sebifera seed oil and other vegetable oils, with yields of 48-72%. The use of a recyclable catalytic system and a greener oxidant reduces the harmful impact on the environment. The method can also be applied to the synthesis of other important chemicals.
INDUSTRIAL CROPS AND PRODUCTS
(2022)
Article
Materials Science, Characterization & Testing
Fei Yu, Linghan Xiao
Summary: The addition of poly(ether sulfone) modified graphene reduced the crystallinity of PEEK composites and shortened the total crystallization time. With increasing the mass ratio of PES to GE, the peak temperature and nucleation activity of f-GE(i) increased before declining.
Review
Polymer Science
Leire Sangroniz, Bao Wang, Yunlan Su, Guoming Liu, Dario Cavallo, Dujin Wang, Alejandro J. Muller
Summary: This study investigates fractionated crystallization, where multiple separated crystallization events are observed in semicrystalline polymers when the number of microdomains is significantly higher than the available number of heterogeneities. The origins of fractionated crystallization effects and their impact on nucleation and crystallization kinetics are discussed.
PROGRESS IN POLYMER SCIENCE
(2021)
Article
Biochemistry & Molecular Biology
Maëva Almeida, Daniel Dudzinski, Catherine Amiel, Jean-Michel Guigner, Sylvain Prevost, Clemence Le Coeur, Fabrice Cousin
Summary: The behavior of mixtures of stearic acid (SA) and its hydroxylated counterpart 12-hydroxystearic acid (12-HSA) in aqueous mixtures was studied. The partitioning between the two types of fatty acids was observed. The self-assembled structures exhibited both lamellar and tubular morphologies depending on the mole ratio R.