☆ 4.7 Article

Crystal water of cadmium acetate-dependent formation of one-dimensional channel structure based on 4,4 '-bis(1-imidazolyl)biphenyl

CRYSTAL GROWTH & DESIGN (2008)

期刊

CRYSTAL GROWTH & DESIGN

卷 8, 期 9, 页码 3134-3136

出版社

AMER CHEMICAL SOC

DOI: 10.1021/cg800038j

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类别

Chemistry, Multidisciplinary Crystallography Materials Science, Multidisciplinary

资金

National Natural Science Foundation of China [20772086, 20602027]
Program for New Century Excellent Talents in University [NCET-04-0881]

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摘要

A novel metal-organic framework with one-dimensional channels {[Cd(3)(CH3COO)(2)(H2O)(2)] (CH3CN)(x)(CH3OH)(y)} (5), based on conformationally restricted linear 4,4'-bis(1-imidazolyl)biphenyl (3) and cadmium acetate dihydrate, has been synthesized. It crystallizes in the triclinic system, space group P (1) over bar with a = 5.6528(11) angstrom, b = 9.887(3) angstrom, c = 12.924(3) angstrom, and Z = 1. The experimental results demonstrate that coordinated crystal water molecules may play a key role in the formation of the metal-organic frameworks.

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