4.7 Article

Effect of a grain-refined microalloyed steel substrate on the formation mechanism of a tight oxide scale

期刊

CORROSION SCIENCE
卷 85, 期 -, 页码 115-125

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PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2014.04.006

关键词

steel; Oxidation; SEM; Electron backscattered diffraction (EBSD)

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The formation mechanism of tight oxide scale on the microalloyed steel was investigated at temperatures of 550-850 degrees C in dry air. Microstructural characterisations reveal that the spallation of oxide scale dominates at the centre of coarse grains on the oxidation initiation. The fine-grained steel improves the adhesive properties of oxide scale by enhanced grain-boundary diffusion. The lower activation energy and higher oxidation rate accelerate cation/anion migration along grain boundaries, leading to high magnetite content in the oxide scale. The approach by grain refinement at initial oxidation has been proposed to generate the pickle-free tight oxide scale. (C) 2014 Elsevier Ltd. All rights reserved.

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