4.2 Article

Sensitivity of Mesoporous CoSb2O6 Nanoparticles to Gaseous CO and C3H8 at Low Temperatures

期刊

JOURNAL OF NANOMATERIALS
卷 2015, 期 -, 页码 -

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HINDAWI LTD
DOI: 10.1155/2015/308465

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  1. Consejo Nacional de Ciencia y Tecnologia (CONACyT)
  2. [784-12FRABA]

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Mesoporous CoSb2O6 nanoparticles, synthesized through a nonaqueous method (using cobalt nitrate, antimony trichloride, ethylenediamine, and ethanol as a solvent), were tested to establish their sensitivity to CO and C3H8 atmospheres at relatively low temperatures. The precursor material was dried at 200 degrees C and calcined at 600 degrees C. X-ray diffraction and scanning electron microscopy were employed to verify the existence of crystal phases (Rho 4(2)/mnm) and the morphology of this trirutile-type CoSb2O6 oxide. Pyramidal and cubic shaped crystals (average size: 41.1 nm), embedded in the material's surface, were identified. Mesopores (average size: 6.5 nm) on the nanoparticles' surface were observed by means of transmission electron microscopy. The best sensitivity of the CoSb2O6 in a CO atmosphere was at the relatively low temperatures of 250 and 350 degrees C, whereas, in a C3H8 atmosphere, the sensitivity increased uniformly with temperature. These results encourage using the CoSb2O6 nanoparticles as gas sensors.

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