Article
Chemistry, Physical
Andreas Drexler, Florian Konert, Oded Sobol, Michael Rhode, Josef Domitner, Christof Sommitsch, Thomas Boellinghaus
Summary: This study investigates the detrimental effects of high-pressure hydrogen gas on metals, focusing on understanding the mechanisms and driving forces of hydrogen absorption. A new generalized form of Sievert's law is derived and validated with experimental data, parametrizing the equation for different metals. The role of microstructural trapping sites in parameter identification is discussed, and the parametrized equation is applied to calculate stress-enhanced hydrogen solubility in practical engineering scenarios.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Chemistry, Multidisciplinary
Liubin Luo, Bangfu Huang, Zhe Shi, Zhenjing Wen, Wanjun Li, Gaoyong Zi, Linjing Yang
Summary: The study characterized Mn/AC catalysts and found that a 7% manganese loading resulted in optimal surface properties, enhancing gas contact area and increasing denitration rate. Increasing manganese loading provided more active sites on the catalyst surface, facilitating the conversion of denitration reaction, conforming to different denitration mechanisms at different temperatures.
Article
Chemistry, Physical
Rodolfo M. Antoniassi, Arthur P. Machado, Ana Rita N. Paiva, Carla M. S. Queiroz, Jorge M. Vaz, Estevam Spinace, Julio Cesar M. Silva, Eduardo Carmine, Pedro H. C. Camargo, Roberto M. Torresi
Summary: An efficient Pt20Fe/CeO2 catalyst was synthesized using a simple borohydride reduction process, showing excellent CO conversion and CO2 selectivity at ambient temperature, meeting the requirements for hydrogen supply in fuel cell devices.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Engineering, Environmental
David Cantador-Fernandez, David Suescum-Morales, Dolores Esquivel, Jose Ramon Jimenez, Jose Maria Fernandez-Rodriguez
Summary: This study investigated the maximum CO2 adsorption capacity of a specific mesoporous organosilica (PMO-Ethane) and found that it outperformed other materials in the literature. Furthermore, the material demonstrated potential for use in reversible multicycle CO2 capture processes. Various mathematical models were used to fit the CO2 adsorption curves, and several characterization techniques were employed to analyze the material's properties. These findings contribute to the development and application of new materials in greenhouse gas capture technologies.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Article
Environmental Sciences
Bing Yuan, Hongyun Hu, Yongda Huang, Biao Fu, Huimin Liu, Guangqian Luo, Yongchun Zhao, Hong Yao
Summary: Selenium in gaseous form is difficult to retain in solid phases during coal combustion due to its high saturated vapor pressure. Understanding the migration of SeO2(g) on ash particles in the low-temperature zone is essential for controlling selenium emission. The physically-bound Se in fly ash consists of selenium condensation and physical adsorption, with mullite showing the best performance in selenium capture at temperatures between 90-200 degrees C.
Article
Materials Science, Multidisciplinary
Maria Volokhova, Aleksei Boldin, Joosep Link, Masahiko Tsujimoto, Raivo Stern, Liis Seinberg
Summary: Ni and Co based nanomaterials are widely used for their magnetic, electric, and catalytic properties. In this study, NiO and Co2O3 nanoparticles were synthesized using one-pot pyrolysis and coated with SiO2 to enhance oxygen stability. The crystal structure, morphology, and magnetic behavior of the nanoparticles were analyzed using various techniques.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2022)
Article
Chemistry, Physical
Gihun Kwon, Gunjoo Kim, Hyunjoo Lee
Summary: By controlling oxygen mobility and adding water adsorbents, ethane productivity was enhanced significantly. The Pd/Ce1-xPdxO2-y catalyst showed superior oxygen activation and transfer, resulting in improved ethane yield.
APPLIED CATALYSIS A-GENERAL
(2021)
Article
Nanoscience & Nanotechnology
Eugenio Zapata-Solvas, Bibi Malmal Moshtaghioun, Diego Gomez-Garcia, Arturo Dominguez-Rodriguez, William E. Lee
Summary: This paper examines the mechanical response of hafnium diboride at different temperatures and reveals that it exhibits metal mechanical behavior.
SCRIPTA MATERIALIA
(2021)
Article
Chemistry, Physical
Vyacheslav Kuzmin, Kajum Safiullin, Andrey Stanislavovas, Eduard Baibekov, Murat Tagirov
Summary: This study reports the first observation of diffusion anisotropy of gaseous helium-3 in ordered aerogels at 4.2 K. The origins of the anisotropy in aerogels of different porosity are discussed, and correlations between gas diffusion coefficient and basic aerogel parameters are examined using diffusion simulations. The failure of certain diffusion models in both isotropic and anisotropic aerogels at low temperatures is observed, and the effect of a wall attractive potential on gas dynamics is believed to be crucial in explaining the observed diffusion behavior.
JOURNAL OF PHYSICAL CHEMISTRY B
(2023)
Editorial Material
Chemistry, Physical
Nghi P. Nguyen, Gary F. Moore
Summary: Artificial leaves have the potential to convert sunlight into fuels for a sustainable energy future, but economic viability is a current challenge. Decentralized hydrogen production using thermally integrated architectures operating under sub-freezing temperatures shows promise for addressing this issue.
Article
Chemistry, Physical
Jae Young Kim, Duck Hyun Youn
Summary: This study demonstrates the feasibility of electrochemical reduction of gaseous CO2 at low-intermediate temperatures using a solid acid membrane cell, and introduces a Cu-based catalyst that can produce hydrocarbons and liquid fuels. This system offers a new possibility for addressing the challenges of producing hydrocarbons and liquid fuels from CO2 reduction.
Article
Chemistry, Physical
Shengnan Lu, Houhong Song, Yonghou Xiao, Kamran Qadir, Yanqiang Li, Yushan Li, Gaohong He
Summary: Tuning the fraction of exposed polar and non-polar crystal facets in ZnO is an effective strategy to tailor metal-oxide interfacial active sites. CuO/ZnO catalyst derived from ZnO nanodisks with the most exposed (002) polar plane exhibited more than 2 folds higher catalytic activity than that over CuO/ZnO with commercial ZnO support (CuO/ZnO-C) at 150 degrees C, highlighting the morphology influence of ZnO.
COLLOID AND INTERFACE SCIENCE COMMUNICATIONS
(2023)
Article
Engineering, Manufacturing
Mohammad S. Islam, Larry F. Benninger, Garth Pearce, Chun-Hui Wang
Summary: Adding nanoparticles of nano-silica and nano-cupric oxide in carbon fiber composites at cryogenic temperatures can significantly enhance the mechanical and fracture properties, improving toughness and resistance to matrix cracking.
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING
(2021)
Article
Chemistry, Physical
Shiyu Xu, Jiawei Chen, Zhenguo Li, Zhiming Liu
Summary: MnOx catalysts with 3D structure (Mn-HT) were prepared using KIT-6 as a template by the hard-template method, and their catalytic performance for the selective catalytic reduction of NOx by NH3 was investigated at low temperatures. It was found that the template KIT-6 prepared at different hydrothermal temperatures significantly affected the catalytic performance of Mn-HT catalysts. Among them, Mn-140 catalyst prepared using the template obtained at a hydrothermal temperature of 140 degrees C exhibited the highest catalytic performance. Characterizations showed that Mn-140 catalyst possessed high reducibility with abundant surface oxygen species and Mn4+ species. NH3-TPD and in situ DRIFTS demonstrated that there were more Lewis acid sites and Bronsted acid sites on the surface of Mn-140 catalyst, promoting the adsorption and activation of NH3 and efficiently reducing NOx mainly by the Eley-Rideal (E-R) mechanism, accompanied by the Langmuir-Hinshelwood (L-H) mechanism.
APPLIED CATALYSIS A-GENERAL
(2023)
Article
Engineering, Electrical & Electronic
Fatemeh Bagheri, Hamid Haratizadeh
Summary: This study suggests that UV-excited sensors based on nanoparticles are practical for carbon dioxide gas sensing, overcoming limitations of NDIR and MOS sensors. These sensors provide good sensitivity, stability, and short response/recovery time at low temperatures.
MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING
(2022)
Article
Chemistry, Applied
M. Perez-Gonzalez, M. Morales-Luna, J. Santoyo-Salazar, H. Crotte-Ledesma, P. E. Garcia-Tinoco, S. A. Tomas
Summary: The study investigated the influence of sputtering power, film thickness, and sputtering working pressure on the adsorption capacity and photocatalytic activity of MoO3 thin films. The results indicated that the samples deposited at 60 W and 12.0 mTorr with a thickness of 400 nm exhibited the maximum adsorption and photocatalytic performances. Raman spectroscopy and photoacoustic spectroscopy experiments confirmed strong MB adsorption on the film surface, with a hypsochromic shift indicating MB aggregation on the MoO3 surface.
Article
Environmental Sciences
Leticia Romero-Cedillo, Hector M. Poggi-Varaldo, Jaime Santoyo-Salazar, Carlos Escamilla-Alvarado, Yasuhiro Matsumoto-Kuwabara, M. Teresa Ponce-Noyola, Luz Breton-Deval, Miguel Garcia-Rocha
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2020)
Article
Engineering, Electrical & Electronic
J. Sastre-Hernandez, J. R. Aguilar-Hernandez, J. Santoyo-Salazar, H. M. Alfaro, J. E. Hoyos-Garcia, M. Tufino-Velazquez, G. Contreras-Puente
MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING
(2020)
Article
Reproductive Biology
Ramses Santacruz-Marquez, Aidee Solorio-Rodriguez, Sirenia Gonzalez-Posos, Sihomara Patricia Garcia-Zepeda, Jaime Santoyo-Salazar, Andrea De Vizcaya-Ruiz, Isabel Hernandez-Ochoa
REPRODUCTIVE TOXICOLOGY
(2020)
Article
Physics, Applied
B. E. Zendejas-Leal, Y. L. Casallas-Moreno, C. M. Yee-Rendon, G. Gonzalez-Pedreros, J. Santoyo-Salazar, J. R. Aguilar-Hernandez, C. Vazquez-Lopez, S. Gallardo-Hernandez, J. Huerta-Ruelas, M. Lopez-Lopez
JOURNAL OF APPLIED PHYSICS
(2020)
Article
Materials Science, Multidisciplinary
Patricia Maldonado-Altamirano, Luis Arturo Martinez-Ara, Maria de los Angeles Hernandez-Perez, Jorge R. Aguilar-Hernandez, Maximo Lopez-Lopez, Jaime Santoyo-Salazar
Summary: This study investigates the optical, structural, and chemical properties of semiconducting CdSe nano particles with an organic shell prepared by laser fragmentation of acetone dispersed CdSe powder. Nd-YAG pulsed laser was used at different power intensities, resulting in nanoparticles of different sizes depending on the wavelength used for processing. The characterization of the samples was performed through various techniques such as UV-Vis Absorption, Photoluminescence, Raman, XRD, TEM, and XPS.
Article
Acoustics
J. A. Fuentes-Garcia, J. Santoyo-Salzar, E. Rangel-Cortes, G. F. Goya, V Cardozo-Mata, J. A. Pescador-Rojas
Summary: The optimized synthesis of gold nanoparticles with different shapes and sizes was achieved using ultrasonic irradiation assisted Turkevich-Frens method. The effects of different ultrasound powers and continuous irradiation time were studied to control the size and shape of the GNPs colloidal solutions. The resulting quasi-spherical GNPs showed sizes ranging from 12 to 16 nm, with different shapes such as pentakis dodecahedron, triakis icosahedron, and tetrakis hexahedron.
ULTRASONICS SONOCHEMISTRY
(2021)
Article
Engineering, Electrical & Electronic
Jose Trinidad Guillen Bonilla, Hector Guillen Bonilla, Veronica-M. Rodriguez-Betancourtt, Alex Guillen Bonilla, Antonio Casillas Zamora, Oscar Blanco Alonso, Jorge Alberto Ramirez Ortega
Summary: The propane gas detector was built using the semiconductor nickel antimonate oxide (NiSb2O6) and an analog electronic circuit to monitor atmospheres where propane gas leakage may occur. The construction process involved 5 stages, including material synthesis, sensor fabrication, and testing, demonstrating excellent functionality at low cost.
JOURNAL OF SENSORS
(2021)
Article
Materials Science, Multidisciplinary
Erwin Said Guillen-Lopez, Florentino Lopez-Urias, Emilio Munoz-Sandoval, Maykel Courel-Piedrahita, Marciano Sanchez-Tizapa, Hector Guillen-Bonilla, Veronica Maria Rodriguez-Betancourtt, Oscar Blanco-Alonso, Alex Guillen-Bonilla, Juan Pablo Moran-Lazaro
Summary: Spinel-type ZnMn2O4 nanoparticles were successfully synthesized using dodecylamine as a surfactant agent, showing good gas sensing performance to isopropanol vapor at 250 degrees C. The sensor exhibited a gas response ranging from 22% to 99%, with a theoretical detection limit estimated to be 666 ppb and a stable electrical signal. These results suggest that ZnMn2O4 can be a promising sensing material for isopropanol vapor.
MATERIALS TODAY COMMUNICATIONS
(2021)
Article
Chemistry, Physical
Ch-Th Thomas, Ravichandran Manisekaran, Jaime Santoyo-Salazar, B. Schoefs, S. Velumani, H. Castaneda, A. Jantrania
Summary: The study developed nanocomposites like GOT and GOB to enhance the inactivation efficiency of E.coli, with OH and O-2(-) radicals responsible for ROS production in photocatalytic disinfection. Results showed that a smaller quantity of GOT achieved highly efficient disinfection.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2021)
Article
Nanoscience & Nanotechnology
Juan Carlos Camacho-Fernandez, Genesis Karendash Gonzalez-Quijano, Childerick Severac, Etienne Dague, Veronique Gigoux, Jaime Santoyo-Salazar, Adrian Martinez-Rivas
Summary: The study investigated the impact of magnetic nanoparticles interacting with HeLa cells under high frequency alternating magnetic field. It was found that these interactions modified the biomechanical behavior of the cell interfaces, particularly with Fe3O4@SiO2-NH2 MNPs incubated HeLa cells exposed to AMF showing the most significant difference in elasticity and stiffness.
Article
Cell Biology
Manuel A. Fernandez-Parrilla, David Reyes-Corona, Yazmin M. Flores-Martinez, Rasajna Nadella, Michael J. Bannon, Lourdes Escobedo, Minerva Maldonado-Berny, Jaime Santoyo-Salazar, Luis O. Soto-Rojas, Claudia Luna-Herrera, Jose Ayala-Davila, Juan A. Gonzalez-Barrios, Gonzalo Flores, Maria E. Gutierrez-Castillo, Armando J. Espadas-Alvarez, Irma A. Martinez-Davila, Porfirio Nava, Daniel Martinez-Fong
Summary: In Parkinson's disease, expressing human cerebral dopamine neurotrophic factor (hCDNF) in dopamine neurons using a neurotensin-polyplex nanoparticle system can reverse pathological features, restore behavior, and improve disease symptoms.
NEURAL REGENERATION RESEARCH
(2022)
Article
Physics, Multidisciplinary
Lucero Alejandra Esquivel-Mendez, Maria De Lourdes Albor-Aguilera, Roberto Carlos Ruiz-Ortega, Miguel Angel Gonzalez-Trujillo, Cesar Hernandez-Vasquez, Jaime Santoyo-Salazar, Miguel Tufino-Velazquez, Gabriela Rueda-Morales, Osvaldo Vigil-Galan, Gerardo Silverio Contreras-Puente
Summary: Deposition of polycrystalline CdTe thin films in large areas faces challenges of non-uniformity and pin holes. This study reports CdTe and CdS thin films with optimal physical properties for potential application in solar cells, and fabricates CdTe mini-modules for outdoor characterization.
REVISTA MEXICANA DE FISICA
(2022)
Article
Engineering, Multidisciplinary
J. I. Alvarez-Vazquez, J. Sastre-Hernandez, G. Ortega-Cervantez, R. Mendoza-Perez, J. Aguilar-Hernandez, J. Santoyo-Salazar, J. A. Del Oso
Summary: This study discusses the potential application of transparent thin films of Zinc Oxide doped with Aluminum (AZO) as a substrate for single-wall carbon nanotubes processing. The AZO thin films were deposited using radiofrequency magnetron sputtering technique at room temperature. Characterization of the AZO thin films and processed bilayers of Zinc Oxide: Aluminum/Single wall carbon nanotubes was done using various techniques. The feasibility of AZO thin films as a substrate for single wall carbon nanotubes in photovoltaics devices was analyzed based on their electrical, morphological, and optical properties.
ENGINEERING RESEARCH EXPRESS
(2023)
Article
Nanoscience & Nanotechnology
Sandra Eguia-Eguia, Lorenzo Gildo-Ortiz, Mario Perez-Gonzalez, Sergio A. Tomas, Jesus A. Arenas-Alatorre, Jaime Santoyo-Salazar
Summary: This study evaluated the orientation of magnetic domains (MDs) in magnetite/maghemite nanoparticles coated with Gadolinium chelated with diethylenetriamine pentaacetate acid (Gd-DTPA). The results showed that the structure, particle size, composition, thickness, and interface defects play important roles in MDs orientation. Addressable and rotational features could potentially be utilized for inducing hydrogen proton alignment in water for various applications.