Article
Chemistry, Applied
K. Waszkowska, Y. Cheret, A. Zawadzka, A. Korcala, J. Strzelecki, A. El-Ghayoury, A. Migalska-Zalas, B. Sahraoui
Summary: This study focuses on investigating the optical properties of metallohelicates in both solid state and solution, using self-assembly process to obtain metallohelicates involving transition metal cations and ligands. The properties of thin films were examined using various optical techniques, and theoretical models were used to determine the nonlinear optical susceptibilities. Factors such as metal ions, film morphology, and interligand charge transfer were discussed in relation to the optical properties.
Article
Chemistry, Multidisciplinary
Dibya Jyoti Mondal, Arindam Gupta, Sanjit Konar
Summary: In this study, three dinuclear iron(II) helicates with imidazole and pyridine-imine-based ligands were synthesized. The spin-transition behavior of these complexes in the solid state was changed from incomplete, multi-step to complete transition around room temperature by modulating the ligand field strength. The spin transition behavior was also observed in solution phase and correlated using spectroscopy.
CHEMISTRY-A EUROPEAN JOURNAL
(2023)
Article
Chemistry, Multidisciplinary
Toshikazu Ono, Kohei Ishihama, Ai Taema, Takunori Harada, Kiyonao Furusho, Masashi Hasegawa, Yuki Nojima, Masaaki Abe, Yoshio Hisaeda
Summary: A new type of chiroptical chromophores composed of tetradentate ligands with aluminum(III) ions exhibit multi-color photoluminescence with quantum yields up to 54%. The right-handed and left-handed helicates are stable and do not racemize in some solvents, showing mirror images in circular dichroism and circularly polarized luminescence. Mixing different helicates can produce white light emission with CPL characteristics, providing potential applications for chromophores with diverse photophysical properties.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Multidisciplinary
Thanh Nhan Nguyen, Anh Ngoc Nguyen, Ngoc Minh Tran, In-Hyeok Park, Hyojong Yoo
Summary: Three novel hierarchical Ni-based metallosupramolecular cages were constructed using nickel ions, pyridine dicarboxylates, and isophthalate derivative ligands. These cages consist of interlinked multinuclear nickel clusters and isophthalate-derivative ligands, forming a nickel-based triple-stranded helicate and serving as supramolecular building blocks for the metallocages. The crystal packing of the racemic cages was characterized by single-crystal X-ray diffraction. Additionally, a cobalt-based molecular cage with 5-methylisophthalate bridging ligands was synthesized for host-guest interaction studies.
Review
Chemistry, Multidisciplinary
Ana B. Caballero, Patrick Gamez
Summary: The generation of highly organized amyloid fibrils is associated with a wide range of conformational pathologies, primarily neurodegenerative diseases. Recent findings suggest that impairment in proteostasis network may lead to accumulation and spread of amyloids, contributing to a new focus in anti-amyloid drug design. Chaperones, as known regulators of proteostasis, represent interesting targets for the development of novel therapeutics, with the concept of nanochaperone potentially leading towards the development of cost-effective, disease-modifying drugs.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Inorganic & Nuclear
Laia Rafols, Sara Torrente, David Aguila, Vanessa Soto-Cerrato, Ricardo Perez-Tomas, Patrick Gamez, Arnald Grabulosa
Article
Chemistry, Multidisciplinary
Marina Uzelac, Pasquale Mastropierro, Marco de Tullio, Ivana Borilovic, Marius Tarres, Alan R. Kennedy, Guillem Aromi, Eva Hevia
Summary: Pairing lithium and manganese(II) to form lithium manganate enables efficient direct Mn-I exchange of aryliodides, with mixed Li/Mn constitution of organometallic intermediates revealed by EPR and X-ray crystallographic studies. These intermediates synergistically facilitate both the Mn-I exchange and C-C bond-forming steps.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Biochemistry & Molecular Biology
Joanna Kowalczyk, Ettore Grapsi, Alba Espargaro, Ana B. Caballero, Jordi Juarez-Jimenez, Maria A. Busquets, Patrick Gamez, Raimon Sabate, Joan Estelrich
Summary: Alzheimer's disease, affecting nearly 50 million individuals globally, is currently the leading cause of dementia. Despite limited available drugs, new therapeutic strategies like direct inhibition of amyloid formation or metal homeostasis regulation are gaining prominence. Prussian blue, a drug listed in the World Health Organization Model List of Essential Medicines, shows potential in Alzheimer's disease treatment by reducing amyloid formation and restoring fibrillation pathways.
Article
Chemistry, Multidisciplinary
Laura Abad Galan, David Aguila, Yannick Guyot, Veronica Velasco, Olivier Roubeau, Simon J. Teat, Massimiliano Massi, Guillem Aromi
Summary: The ligand H3L has been used to study energy transfer in dinuclear lanthanide analogues, showing that ET between Eu-III and Yb-III does not occur significantly, and that Yb-III emission originates from sensitization by the ligand. Energy migration seems to occur between the two Nd-III centers, with Yb-III luminescence being partially sensitized by ET from Nd.
CHEMISTRY-A EUROPEAN JOURNAL
(2021)
Article
Biochemistry & Molecular Biology
Marcos Palmeira-Mello, Ana B. Caballero, Aida Lopez-Espinar, Guilherme P. Guedes, Amparo Caubet, Alessandra M. Teles de Souza, Mauricio Lanznaster, Patrick Gamez
Summary: The two square-planar coordination compounds interact differently with DNA, with the palladium(II) complex showing stronger binding leading to double strand cleavage, while the copper complex has weaker and concentration dependent binding.
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY
(2021)
Article
Chemistry, Physical
Alejandro Salvatori, David Aguila, Guillem Aromi, Lluis Manosa, Antoni Planes, Pol Lloveras, Luis Carlos Pardo, Markus Appel, Guillaume F. Nataf, Fabien Giovannelli, Maria Barrio, Josep Lluis Tamarit, Michela Romanini
Summary: Materials undergoing pressure-driven solid-solid phase transformations can be a valuable alternative for eco-friendly refrigeration, heat pumping and waste heat recovery based on the barocaloric effect. Ferroelectric compounds and plastic crystals have shown their potential in these fields due to their ability to undergo large changes in volume and entropy at the transition, resulting in a significant pressure-induced caloric response.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Biochemistry & Molecular Biology
Piedad Herrera-Ramirez, Sarah Alina Berger, Dana Josa, David Aguila, Ana B. Caballero, Pere Fontova, Vanessa Soto-Cerrato, Manuel Martinez, Patrick Gamez
Summary: Two ruthenium(II) polypyridyl complexes, [Ru(phen)(2)(dpa)](PF6)(2) and [Ru(phen)2(Bndpa)](PF6)2, were synthesized with the {Ru(phen)(2)}(2+) moiety and different bidentate ligands. The photochemical behavior of these complexes in acetonitrile and water was investigated, showing that they undergo two-step photoejection of the ligands upon irradiation. Furthermore, these complexes exhibit different effects on DNA and cytotoxicity when irradiated.
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Leoni A. Barrios, Simon. J. Teat, Olivier Roubeau, Guillem Aromi
Summary: A biphenyl-spaced bis-pyrazolylpyridine ligand forms a dimetallic helical coordination cage when interacting with ferrous ions, which encapsulates an Fe3+ tris-anilate complex. The host-guest interaction breaks the symmetry of the Fe2+ centers, resulting in a differential spin crossover behavior that can be studied in detail using crystallographic methods.
CHEMICAL COMMUNICATIONS
(2023)
Article
Chemistry, Inorganic & Nuclear
Dana Josa, David Aguila, Pere Fontova, Vanessa Soto-Cerrato, Piedad Herrera-Ramirez, Laia Rafols, Arnald Grabulosa, Patrick Gamez
Summary: Five metal-arene complexes and nine cyclometalated half-sandwich complexes were synthesized, characterized, and evaluated for cytotoxicity against human cancer cells. The complexes showed notable cytotoxic properties, particularly against lung adenocarcinoma cells. One of the complexes also exhibited significant toxic effects on other cell lines. Furthermore, the study identified a complex that impacted the cell cycle of lung adenocarcinoma cells.
DALTON TRANSACTIONS
(2023)
Article
Chemistry, Multidisciplinary
Nuria Capo, Leoni A. Barrios, Joan Cardona, Jordi Ribas-Arino, Simon J. Teat, Olivier Roubeau, Guillem Aromi
Summary: The anion SiF62- plays a significant role in guiding the assembly of two different bispyridylpyrazolyl ligands, resulting in the formation of a novel triple stranded Fe(ii) dinuclear heteroleptic helicate.
CHEMICAL COMMUNICATIONS
(2022)
Article
Chemistry, Multidisciplinary
Ivana Borilovic, Olivier Roubeau, Boris Le Guennic, Joris van Slageren, Samuel Lenz, Simon J. Teat, Guillem Aromi
Summary: An asymmetric bis-phenol-beta-diketone (H4L) has been designed as a ligand that promotes the assembly of three magnetically exchanged [NiCu] pairs, each exhibiting an S = 1/2 spin. EPR and magnetometry measurements show that these pairs are good qubit realizations and non-equivalent within the molecule in the solid state, meeting the requirements for conditional quantum gates.
CHEMICAL COMMUNICATIONS
(2022)
Article
Chemistry, Multidisciplinary
Diamantoula Maniaki, Diego Garay-Ruiz, Leoni A. Barrios, Daniel O. T. A. Martins, David Aguila, Floriana Tuna, Daniel Reta, Olivier Roubeau, Carles Bo, Guillem Aromi
Summary: This study successfully synthesized high-purity [LnLn'Ln] type molecules using a coordination chemistry scaffold and revealed their exceptional chemical selectivity through density functional theory calculations. The magnetic analysis and ab initio calculations suggest that these composite quantum gates have the potential to act as addressable, conditional multiqubit spin-based quantum gates. Furthermore, EPR analysis and pulsed experiments confirm the coherence and feasibility of these molecular systems.
Article
Chemistry, Multidisciplinary
Leoni A. Barrios, Rosa Diego, Mohanad Darawsheh, Jesus Martinez, Oliver Roubeau, Guillem Aromi
Summary: This article presents a designed dimetallic Fe(ii) helicate made with biphenylene-bridged bispyrazolylpyridine ligands, which exhibits spin crossover at temperatures higher than ambient. It is also demonstrated that this helicate has the ability to encapsulate an S = 5/2 tris-oxalato Fe(iii) ion, leading to a significant reduction in the spin relaxation dynamics of the encapsulated guest.
CHEMICAL COMMUNICATIONS
(2022)
Review
Chemistry, Inorganic & Nuclear
David Aguila, Olivier Roubeau, Guillem Aromi
Summary: This study explores the synthesis of lanthanide-based coordination compounds using dissymmetric organic ligands, enabling the access to well-defined heterolanthanide compositions and versatile quantum gate design. The weak interaction between the Ln ions allows for multi-qubit quantum logical operations and the implementation of quantum-error correction protocols. The research shows the vast potential of these systems in spin-based quantum information processing.
DALTON TRANSACTIONS
(2021)
Review
Chemistry, Inorganic & Nuclear
Pegah Hajivand, Johannes Carolus Jansen, Emilio Pardo, Donatella Armentano, Teresa F. Mastropietro, Amirreza Azadmehr
Summary: VOCs in human breath can be used as biomarkers for diseases, and MOFs have been extensively studied as gas sensors for VOCs. This review provides a comprehensive summary of the latest MOF-derived composites used as VOCs biomarkers' sensors, and discusses the structural and functional characteristics of MOFs, sensing properties, and the potential of bio-MOFs in VOCs sensing.
COORDINATION CHEMISTRY REVIEWS
(2024)
Review
Chemistry, Inorganic & Nuclear
Seoyoon Song, Deborah Lee, Lucia C. Dalle Ore, Sungjun Kwak, Lifeng Kang, Hyung Kyo Kim, Noah Malmstadt, Sun Min Kim, Tae-Joon Jeon
Summary: This paper introduces the latest advancements in photoactivable liposomes in drug delivery, highlighting their advantages in precise control over drug release and targeted delivery, as well as the fine control over release kinetics achieved through the manipulation of light-responsive components. Additionally, the paper emphasizes the design considerations of physicochemical properties and light-related constituents.
COORDINATION CHEMISTRY REVIEWS
(2024)
Review
Chemistry, Inorganic & Nuclear
Shudi Liu, Liangwei Zhang, Heejeong Kim, Jinyu Sun, Juyoung Yoon
Summary: Chromium is a strategic and critical transition metal element with extensive applications. Efficient detection methods, such as fluorescence and colorimetry, have been developed for monitoring its concentrations. However, existing reviews on fluorescent probes for chromium lack comprehensive coverage. This review aims to consolidate information and promote the development of novel fluorescent probes for chromium detection.
COORDINATION CHEMISTRY REVIEWS
(2024)
Review
Chemistry, Inorganic & Nuclear
Rehab H. Elattar, Samah F. El-Malla, Amira H. Kamal, Fotouh R. Mansour
Summary: Metal complexes have strong analysis potential and can be used to measure analytes lacking essential chemical properties. Their analytical methods based on different mechanisms offer superior performance.
COORDINATION CHEMISTRY REVIEWS
(2024)
Review
Chemistry, Inorganic & Nuclear
Nem Singh, Miae Won, Yunjie Xu, Changyu Yoon, Jiyoung Yoo, Mingle Li, Heemin Kang, Jong Seung Kim
Summary: Hypoxia is a common occurrence in the tumor microenvironment and poses challenges for cancer treatment. The introduction of covalent organic frameworks (COFs) offers promising prospects for addressing hypoxia-related issues. This article explores the role of COFs in enhancing oxygen delivery, generating reactive oxygen species, optimizing drug delivery, and enabling hypoxia-specific imaging, as well as outlining their applications in various hypoxia-targeting therapeutic modalities.
COORDINATION CHEMISTRY REVIEWS
(2024)
Review
Chemistry, Inorganic & Nuclear
Priyadarshi Roy Chowdhury, Himani Medhi, Krishna G. Bhattacharyya, Chaudhery Mustansar Hussain
Summary: This review critically analyzes the production of waste-derived layered double hydroxides (LDH) and their utility in electrochemical water splitting for the generation of green hydrogen as sustainable energy. It highlights the importance of waste-derived LDH and discusses the challenges and future directions in this field.
COORDINATION CHEMISTRY REVIEWS
(2024)
Review
Chemistry, Inorganic & Nuclear
Rajamanickam Sivakumar, Nae Yoon Lee
Summary: This article reviews the progress in imaging reactive oxygen, nitrogen, and sulfur species (RONSS) using luminescent metal complex-based probes. This technology is selective and sensitive, which is of great significance for studying the impact of RONSS in cells and tissues and preventing diseases.
COORDINATION CHEMISTRY REVIEWS
(2024)
Review
Chemistry, Inorganic & Nuclear
Xinyang Li, Binbin Ding, Pan Zheng, Ping'an Ma, Jun Lin
Summary: The main goal of immunotherapy is to enhance the response and cytotoxicity of tumor-specific T cells by turning cold tumors into hot tumors. However, metabolic reprogramming in the tumor microenvironment can depress the cytotoxicity of T cells and hinder the effectiveness of immunotherapy. This review discusses the role of metabolic reprogramming in the interplay between cancer cells and immune cells in the tumor microenvironment and explores the use of nanomaterials to modulate metabolic pathways and improve immunotherapy outcomes.
COORDINATION CHEMISTRY REVIEWS
(2024)
Review
Chemistry, Inorganic & Nuclear
Kingsley Poon, Abhishek Gupta, William S. Price, Hala Zreiqat, Gurvinder Singh
Summary: Progress in the development of manganese oxide nanoparticles (MONPs) has provided an alternative for early-stage diagnosis of life-threatening diseases and therapeutic delivery of drugs and genes. The synthesis and characterization of MONPs have enabled the production of multi-functional targeted nanoparticles in various sizes and shapes. The integration of diagnosis and therapeutic capabilities within a single entity, known as nanotheranostics, is promising for real-time monitoring of disease progression and evaluating therapeutic treatment efficacy.
COORDINATION CHEMISTRY REVIEWS
(2024)
Review
Chemistry, Inorganic & Nuclear
Reza Abedi-Firoozjah, Hadiseh Ebdali, Mahya Soltani, Parastoo Abdolahi-Fard, Mahshid Heydari, Elham Assadpour, Maryam Azizi-Lalabadi, Fuyuan Zhang, Seid Mahdi Jafari
Summary: With the increasing awareness of food safety, there is a growing demand for efficient and affordable sensing methods for the detection of pathogens and toxins in food products. Nanosensors offer promising solutions with their quick and reliable detection capabilities, although challenges remain in their fabrication and practical application.
COORDINATION CHEMISTRY REVIEWS
(2024)
Review
Chemistry, Inorganic & Nuclear
Demei Sun, Xuesong Feng, Xinyuan Zhu, Youfu Wang, Jinghui Yang
Summary: Metal organic cages (MOCs) with precise and tunable nano structures show great potential in cancer therapy. Their diverse functions and ultrasmall size make them excellent nanoagents for different anticancer strategies, demonstrating outstanding anticancer performances.
COORDINATION CHEMISTRY REVIEWS
(2024)
Review
Chemistry, Inorganic & Nuclear
Li Li, Yang-Tao Yu, Ning-Ning Zhang, Shu-Hao Li, Jian-Ge Zeng, Yang Hua, Hong Zhang
Summary: This article summarizes recent advances in POM-based hybrid photochromic materials (PCHPMs), including structure types, new photochromic mechanisms, and applications. It can provide valuable guidance for researchers investigating POM-based hybrid photochromic materials.
COORDINATION CHEMISTRY REVIEWS
(2024)
Review
Chemistry, Inorganic & Nuclear
Chien Ing Yeo, Clariss Hui Peng Goh, Edward R. T. Tiekink, Jactty Chew
Summary: This review article provides an overview of the antibacterial activity of gold complexes, with a focus on gold(I) and gold(III) complexes. It also summarizes the repurposing of Auranofin for antibacterial purposes and the associated mechanism(s) of action.
COORDINATION CHEMISTRY REVIEWS
(2024)
Review
Chemistry, Inorganic & Nuclear
Sangharaj Diyali, Nilankar Diyali, Bhaskar Biswas
Summary: This study discusses the recent progress in the design and development of catalysts, focusing on the factors influencing overpotential, catalytic rate, and stability, as well as the mechanisms of the hydrogen evolution reaction in acidic and alkaline media. Moreover, it outlines the challenges in future design of robust and active electrocatalysts.
COORDINATION CHEMISTRY REVIEWS
(2024)
Review
Chemistry, Inorganic & Nuclear
Shaik Gouse Peera, Rahul S. Menon, Sumanta Kumar Das, Akram Alfantazi, K. Karuppasamy, Chao Liu, Akhila Kumar Sahu
Summary: Doped carbon materials, especially F-doped carbon catalysts, have gained significant attention as metal-free catalysts for oxygen reduction reactions and as corrosion-resistant supports for Pt and non-Pt nanoparticles. F-doped carbon materials possess unique properties and greatly improve the activity and durability of the ORR compared to N-doped carbon materials. The high electronegativity of F-doping can efficiently modify the electronic band structure of carbon materials, favoring the ORR. This review systematically discusses the effect of F-doping/F co-doping on the electrocatalytic reduction of O2 in acidic and alkaline conditions, the stability and durability of fuel cell catalysts, and provides guidelines for working with F-doped carbons. Future research directions on F-doped carbons are also proposed to bridge the gap between laboratory-scale assessments and commercial applications.
COORDINATION CHEMISTRY REVIEWS
(2024)