期刊
COORDINATION CHEMISTRY REVIEWS
卷 252, 期 18-20, 页码 2137-2154出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2007.11.023
关键词
group 4 metals; lanthanides; polymerization catalysis; styrene
Styrene-ethylene and styrene-alpha-olefin copolymers are relatively new materials that were developed since the early 1990s thanks to homogeneous single-site catalysts. A wide range of copolymers, differing in their compositions, microstructures and properties have been prepared by using several types of early transition (groups 3 and 4) metal catalysts, which are critically reviewed in this contribution. Structure-activity-control relationships are also discussed. (C) 2008 Elsevier B.V. All rights reserved.
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