期刊
COORDINATION CHEMISTRY REVIEWS
卷 252, 期 8-9, 页码 940-963出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2007.10.013
关键词
polypyridyls; metallo-supramolecular chemistry; self-assembly; X-ray structures
Polypyridyl ligand derivatives have been widely employed for the construction of metallo-supramolecular entities from the beginning of this contemporary area of research. Representative recent developments in the use of such 'classical' polypyridyl ligands combined with selected d-block metal ions to obtain supramolecular assemblies incorporating both the polypyridyl and the metal ion as structural elements are described. In particular, helicates, metal-chain oligo-pyridylamido systems, grids as well as a range of other metallo-supramolecular structures are discussed. (c) 2007 Published by Elsevier B.V.
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