期刊
COMPTES RENDUS CHIMIE
卷 15, 期 9, 页码 815-836出版社
ELSEVIER FRANCE-EDITIONS SCIENTIFIQUES MEDICALES ELSEVIER
DOI: 10.1016/j.crci.2012.07.004
关键词
Octahedral cluster; Molybdenum; Rhenium; Chalcohalide; Dimensionality; Solid state chemistry; Crystal structure
资金
- Fondation Langlois
The octahedral Mo-6 and Re-6 chalcohalides prepared by solid state routes at high temperature are reviewed from their origin to the recent period. Their crystal structures built from the face-capped M6L14 building blocks are presented according to the interunit connectivities, starting from the three-dimensional Chevrel phases and decreasing the dimensionality down to 2D, 1D and finally OD compounds in which the cluster units are discrete. In a second step, it is shown that the solid cluster compounds are relevant precursors for more recently expanded reactions in solution or by soft chemistry, giving access to a large variety of hybrid organic/inorganic cluster materials. (C) 2012 Academie des sciences. Published by Elsevier Masson SAS. All rights reserved.
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