Synthesis and applications of oxophosphonates in organic chemistry

Synthesis and affliations of oxophosphonates in organic chemistry. This work devoted to oxophosphonates deals with three different series of compounds: the alpha-ketophosphonates, the beta-ketophosphonates and finally the gamma- and delta-ketophosphonates which were considered as one series of compounds. For each type of products, the various synthetic methods as well as their reactivity were presented. In the last part, we have developed different methods of reduction, nucleophilic addition and substitution reactions. Particular attention was focused on sulfur and nitrogen containing derivatives as well as fluorinated and chlorinated compounds. To cite this article: A. Almani et al., C R. Chimie 12 (2009). (C) 2008 Published by Elsevier Masson SAS on behalf of Academie des sciences.