期刊
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING
卷 53, 期 -, 页码 24-33出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.compositesa.2013.06.007
关键词
Polymer matrix composites (PMCs); Electrical properties; Thermal properties; Compression moulding
资金
- National Natural Science Foundation of China (NSFC) [21034005, 51121001]
In situ thermal reduction of GO is a simple and green approach in the preparation of polymer/graphene nanocomposites, and has received increasingly attention. However, its efficiency is usually low due to the limitation of thermal reduction temperature used. In this paper, well dispersion of graphene oxide (GO) in polycarbonate (PC) matrix was firstly prepared via solvent-exchange and coagulation. Then the GO was in situ thermal reduced efficiently within a few minutes in PC solid matrix, taking the advantage of PC processing at high temperature (280 degrees C). The presence of well-dispersed isolated reduced graphene oxide (RGO) single sheets in the PC matrix had been demonstrated. The reduction of graphene oxide was well confirmed. As a result, the nanocomposites exhibit a low percolation threshold of similar to 0.21 vol% and a conductivity of 0.041 S m(-1) at a RGO content of 1.09 vol%. Meanwhile, the mechanical properties and thermal stability of PC are also significantly enhanced by adding RGO. (C) 2013 Elsevier Ltd. All rights reserved.
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