4.7 Article

Hierarchical composites of conductivity controllable polyaniline layers on the exfoliated graphite for dielectric application

期刊

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.compositesa.2012.06.001

关键词

Composite films; Polyaniline/exfoliated graphite; Poly(vinylidene fluoride); Dielectric properties

资金

  1. Key Project of Chinese Ministry of Education [107023]
  2. Fundamental Research Funds for the Central Universities [2011PY0180, 2011PY0181]
  3. National laboratory of minerals of China University of Geosciences (Beijing) [098003]
  4. City University of Hong Kong Strategic Research Grant (SRG) [7008009]

向作者/读者索取更多资源

Hierarchical composites of polyaniline fibers on the surface of exfoliated graphite were synthesized by chemical oxidation method. The conductivity of polyaniline fibers was controlled by doping and dedoping procedures. The morphology, structure and chemical character of doped and dedoped hierarchical composites were systemically investigated by SEM, TEM, XRD, FT-IR. XPS and conductivity measurement. After dedoping procedure, polyaniline/exfoliated graphite composites were used to improve dielectric property of the electroactive polymer poly(vinylidene fluoride). The dielectric constant and loss tangent of composites were 17 and 0.06 (10(3) Hz) when the polyaniline/exfoliated graphite loading was 3 wt%. Of great interest was that the dielectric loss tangent of composites showed inherent low loss of poly(vinylidene fluoride) because insulating polyaniline fibers on the surface of exfoliated graphite effectively prevented direct contact of exfoliated graphite flakes in poly(vinylidene fluoride) matrix. (c) 2012 Elsevier Ltd. All rights reserved.

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