期刊
COLLOID AND POLYMER SCIENCE
卷 291, 期 4, 页码 927-936出版社
SPRINGER
DOI: 10.1007/s00396-012-2811-y
关键词
Dendrimer; Amphiphilic; Langmuir Blodgett; Thin films
资金
- Russian Foundation of Fundamental Researches, COST action [D35-WG0013]
- Center for Advanced Materials, University of Massachusetts Lowell
Amphiphilic carbosilane dendrimers with novel architectural layout have been synthesized. These dendrimers contain peripheral groups consisting of covalently bound promesogenic fragments and hydrophilic (oligoethyleneglycolic) linkages which are connected to a carbosilane core in two distinct ways: as spacer or as tail arrangement. Such molecules have a block structure where the hydrophilic and hydrophobic blocks are distributed within the dendrimer forming layers of different polarity. The hydrophilic layer is either enclosed between two hydrophobic parts of the molecule or is situated on the periphery. The synthetic strategy for achieving these structures is described. The interfacial properties of the dendrimers were studied and the influence of the dendritic structure's organization on the Langmuir film formation process is assessed.
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