期刊
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
卷 26, 期 6, 页码 3392-3396出版社
SPRINGER
DOI: 10.1007/s10854-015-2845-2
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资金
- National Science Foundation of China [21476066]
- Natural Science Foundation of Hunan Province [13JJ6084]
- construct program of the key discipline in Hunan Province of the 12th Five-Year Plan [080502]
- Excellent Engineering Project of the Department of Education of China [080203]
The 3D micro-nano-structure LiFePO4/C have been synthesized successfully from FePO4 center dot 2H(2)O precursor via a simple, inexpensive and continuously water bath process at 100 A degrees C for 24 h by using Fe3+ as the iron source, followed by a rheological phase method. Both the properties of the FePO4 center dot 2H(2)O and the LiFePO4/C were investigated by XRD and SEM. The results indicated that the 3D micro-nano-structure materials composited of nanoplates which are about 100 nm long and 50 nm thick, and had a hole in the center. Moreover, the FePO4 center dot 2H(2)O had a high yield above 85 %. Furthermore, the 3D micro-nano-structure LiFePO4/C as cathode materials for Li-ion batteries were also evaluated. The materials showed excellent high-rate capability, with discharge capacities reaching 103 and 80 mAh g(-1) at high rates of 10 and 20 C, even could reach 40 mAh g(-1) when the current increased to 30 C. Moreover, the LiFePO4/C had a high tap density about 1.5 g cm(-3). As a result, the 3D micro-nano-structure LiFePO4/C can be the cathode material for large-scale applications and industrialization.
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