Article
Materials Science, Multidisciplinary
H. Nasrinpour, S. M. Masoudpanah, M. Soltanieh
Summary: Submicron octahedral LiMn1.5Ni0.5O4 particles were easily prepared by solvothermal synthesis method, and their characteristics varied with different synthesis conditions, including particle size, morphology, and structure. Higher precursor concentration and longer calcination time resulted in larger particle size and wider distribution, as well as the appearance of chamfered corners and edges.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2021)
Article
Chemistry, Physical
Ehsan Ghasemiestahbanati, Young Hee Yoon, Ryan P. Lively, Mahdokht Shaibani, Mainak Majumder, Matthew R. Hill
Summary: Graphene interlayer can address the issues of cycling stability and storage capacity in lithium-sulfur batteries.
Article
Chemistry, Physical
K. P. Lakshmi, R. Deivanayagam, M. M. Shaijumon
Summary: A composite of antimony oxide microstructures encapsulated in graphene aerogel, interconnected by a network of carbon nanotubes, shows excellent electrochemical performance as an anode for sodium and lithium ion batteries. The unique star-shaped Sb2O3 microstructures are synthesized through a facile hydrothermal method, exhibiting stable specific capacity over 100 cycles. The study investigates the reaction kinetics upon sodiation and attempts to probe the underlying electrochemical charge storage mechanism using ex-situ techniques.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Multidisciplinary
Yuki Nomura, Kazuo Yamamoto, Yuji Yamagishi, Emiko Igaki
Summary: This study reveals the correlations between grain architecture, Li transport pathways, and phase transitions in Ni-rich layered cathodes using in situ transmission electron microscopy. The results show that Li ions are extracted through tortuous paths connecting the Li-containing a-b planes in the crystals, and the grain boundary resistance depends not only on the misorientations of the neighboring grains.
Article
Chemistry, Physical
Seung-Yong Lee, Junyi Shangguan, Sophia Betzler, Stephen J. Harris, Marca M. Doeff, Haimei Zheng
Summary: Understanding lithium stripping is crucial for using lithium metal anodes in high-energy rechargeable batteries. Through in-situ electrochemical liquid cell transmission electron microscopy, the mechanisms of lithium stripping were revealed, and different modes of stripping behavior were observed. The study also highlighted the importance of solid-electrolyte interphase (SEI) protection in subsequent cycles.
Review
Chemistry, Multidisciplinary
Wei Zhong, Ziqi Zeng, Shijie Cheng, Jia Xie
Summary: Prelithiation technology is one of the most effective methods to compensate for the loss of active lithium. This review analyzes the factors inducing lithium loss and investigates the mechanisms and effects of prelithiation. The emerging advanced prelithiation technologies and key issues are systematically summarized. Hybrid replenishment and lithium storage technologies are proposed to provide a reference for developing prelithiation technology.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Yu Zhang, Shuting Zhang, Junguo Ma, Xin Chen, Caiyun Nan, Chen Chen
Summary: In this study, a series of high-efficiency cathode catalysts were demonstrated by loading single-atomic metals (M=Ru, Pd, Pt, Au, Ir) onto Co3O4. The single-atomic metals substituted the central Co atom in the octahedral coordination structure, maintaining its stability. The presence of the single atoms promoted the exposure of highly active Co3+ and provided nucleation sites for Li2O2 deposition. Additionally, the loaded M atoms regulated the dispersion of Li2O2, resulting in a sheet-like morphology that facilitated its decomposition in subsequent charge cycles. This research highlights the effective modulation of active metal oxide by single atoms, collectively enhancing catalytic performance.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Review
Chemistry, Multidisciplinary
Ruichun Luo, Meng Gao, Chunwen Wang, Juntong Zhu, Roger Guzman, Wu Zhou
Summary: This review provides an overview of the static and in situ investigation of functional structures, defects, and interfaces in 2D transition metal dichalcogenides (TMDs), primarily utilizing scanning transmission electron microscopy and electron energy loss spectroscopy. Recent advancements in in situ visualization and manipulation of 2D TMDs using electron beams are also highlighted.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Green & Sustainable Science & Technology
Hsing- Hsiang, Wei-Yu Chen
Summary: The cathode material of spent LiFePO4 batteries can be directly reused via electrochemical technology for environmental sustainability.
Review
Chemistry, Multidisciplinary
Zu-Wei Yin, Wenguang Zhao, Jianyuan Li, Xin-Xing Peng, Cong Lin, Mingjian Zhang, Zhiyuan Zeng, Hong-Gang Liao, Haibiao Chen, Hai Lin, Feng Pan
Summary: This article introduces the importance of EELS as a powerful tool for chemical compositional analyses in battery studies, as well as its role in revealing abundant information in materials. It also looks ahead at the future development of EELS techniques and their potential applications in battery research.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Materials Science, Multidisciplinary
Weiyi Chen, Shaopeng Li, Chenhui Wang, Hui Dou, Xiaogang Zhang
Summary: In this study, a precise and efficient strategy for stabilizing lithium-metal batteries was proposed by using a lithiophilic Ag-modified Cu current host. The lithiophilic silver layer anchored on the Cu mesh through magnetron sputtering method effectively guided uniform Li deposition and realized spatial control over Li nucleation. The use of this current host resulted in the successful preparation of a dendrite-free lithium anode and demonstrated a low overpotential and long cycle life.
ENERGY & ENVIRONMENTAL MATERIALS
(2023)
Article
Chemistry, Physical
Mikhail N. Palatnikov, Vladimir A. Sandler, Nikolay V. Sidorov, Olga V. Makarova, Diana V. Manukovskaya
Summary: This article presents a detailed study on the dielectric properties and conductivity of SrTiO3 crystal in an oxygen-free environment. It is found that at a certain ionic conductivity value, conductivity is carried out by associated carriers, leading to an increase in conductivity activation enthalpy. The study also confirms the presence of defects association in structures with high ionic conductivity. This effect is independent of crystal structure and charge carrier type, and there is a temperature region where ionic associates and single carriers determine ion transport characteristics.
SOLID STATE IONICS
(2022)
Article
Materials Science, Multidisciplinary
Zhihong Luo, Fujie Li, Chengliang Hu, Liankun Yin, Degui Li, Chenhao Ji, Xiangqun Zhuge, Kui Zhang, Kun Luo
Summary: The introduction of silver nanoparticles in aprotic lithium-oxygen batteries leads to the formation of film-like lithium peroxide through surface pathway, accelerating the decomposition of discharge product and significantly extending the battery lifespan while improving performance.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2021)
Article
Agricultural Engineering
Caiwei Wang, Dongjie Yang, Yunpeng Zhu, Yuebin Xi, Wenli Zhang, Mengzhen Yan, Yanlin Qin, Xueqing Qiu
Summary: A delicate strategy of pyrolytic gas exfoliation and template mediation was developed to engineer the microstructure of Enzymatic hydrolysis lignin-derived carbonaceous material (ECM) for robust lithium storage. The developed mesoporous ECM with interconnected grape-like network and nanostructured grape-like network exhibited excellent lithium storage performance.
INDUSTRIAL CROPS AND PRODUCTS
(2022)
Article
Engineering, Chemical
Minxia Liu, Dang Wu, Dongling Qin, Gang Yang
Summary: This study reports a spray-drying assisted solid-state method for preparing spherical layer-structured H2TiO3 ion sieve particles, and investigates the effects of synthesis parameters on the adsorption-desorption performance. The as-prepared LSTIS exhibits excellent adsorption capacity and selectivity for Li+ enrichment from saline solutions.
CHINESE JOURNAL OF CHEMICAL ENGINEERING
(2022)
Article
Multidisciplinary Sciences
Jing Li, Qingping Meng, Yiman Zhang, Lele Peng, Guihua Yu, Amy C. Marschilok, Lijun Wu, Dong Su, Kenneth J. Takeuchi, Esther S. Takeuchi, Yimei Zhu, Eric A. Stach
NATURE COMMUNICATIONS
(2019)
Article
Chemistry, Physical
Jingxu Zheng, Qing Zhao, Xiaotun Liu, Tian Tang, David C. Bock, Andrea M. Bruck, Killian R. Tallman, Lisa M. Housel, Andrew M. Kiss, Amy C. Marschilok, Esther S. Takeuchi, Kenneth J. Takeuchi, Lynden A. Archer
ACS ENERGY LETTERS
(2019)
Article
Nanoscience & Nanotechnology
Matthew M. Huie, David C. Bock, Andrea M. Bruck, Killian R. Tallman, Lisa M. Housel, Lei Wang, Juergen Thieme, Kenneth J. Takeuchi, Esther S. Takeuchi, Amy C. Marschilok
ACS APPLIED MATERIALS & INTERFACES
(2019)
Article
Materials Science, Multidisciplinary
Alyson Abraham, Mikaela R. Dunkin, Jianping Huang, Bingjie Zhang, Kenneth J. Takeuchi, Esther S. Takeuchi, Amy C. Marschilok
MRS COMMUNICATIONS
(2019)
Article
Chemistry, Multidisciplinary
Zhengyan Lun, Bin Ouyang, Zijian Cai, Raphaele Clement, Deok-Hwang Kwon, Jianping Huang, Joseph K. Papp, Mahalingam Balasubramanian, Yaosen Tian, Bryan D. McCloskey, Huiwen Ji, Haegyeom Kim, Daniil A. Kitchaev, Gerbrand Ceder
Article
Chemistry, Multidisciplinary
Weiwei Sun, Hsiu-Wen Wang, Lukas Vlcek, Jing Peng, Alexander B. Brady, Naresh C. Osti, Eugene Mamontov, Madhusudan Tyagi, Jagjit Nanda, Steven G. Greenbaum, Paul R. C. Kent, Michael Naguib
ADVANCED MATERIALS INTERFACES
(2020)
Article
Chemistry, Physical
Shilun Gao, Feiyuan Sun, Alexander Brady, Yiyang Pan, Andrew Erwin, Dandan Yang, Vladimir Tsukruk, Andrew G. Stack, Tomonori Saito, Huabin Yang, Peng-Fei Cao
Article
Chemistry, Physical
Zhengyan Lun, Bin Ouyang, Deok-Hwang Kwon, Yang Ha, Emily E. Foley, Tzu-Yang Huang, Zijian Cai, Hyunchul Kim, Mahalingam Balasubramanian, Yingzhi Sun, Jianping Huang, Yaosen Tian, Haegyeom Kim, Bryan D. McCloskey, Wanli Yang, Raphaele J. Clement, Huiwen Ji, Gerbrand Ceder
Summary: High-entropy ceramics are solid solutions with compositional flexibility and wide applicability, showing substantial performance improvement in lithium-ion battery cathodes. The high-entropy concept leads to enhancements in energy density and rate capability, especially in cation-disordered rocksalt-type cathodes. High-entropy materials have the potential for various applications and the design of high-entropy solid solutions in the DRX space can further enhance performance in battery electrodes.
Article
Chemistry, Multidisciplinary
Alexander Brady, Kun Liang, Van Quan Vuong, Robert Sacci, Kaitlyn Prenger, Matt Thompson, Ray Matsumoto, Peter Cummings, Stephan Irle, Hsiu-Wen Wang, Michael Naguib
Summary: Through the study of sodium preintercalated MXene, we identified the formation of a two-dimensional sodium domain structure at interfaces/surfaces and found that the location of sodium ions determines the layer charges and redox process. Electrochemical testing of pre-sodiated MXene as an electrode material in a sodium-ion capacitor showed excellent reversibility and performance, demonstrating the feasibility of chemical preintercalation as an approach to prepare MXene electrodes.
Article
Energy & Fuels
Jianping Huang, Peichen Zhong, Yang Ha, Deok-Hwang Kwon, Matthew J. Crafton, Yaosen Tian, Mahalingam Balasubramanian, Bryan D. McCloskey, Wanli Yang, Gerbrand Ceder
Summary: This study demonstrates that the rate capability in a Li-rich cation-disordered rocksalt cathode can be significantly improved when the topotactic reaction is replaced by a non-topotactic reaction. Fast non-topotactic lithiation reaction is enabled by facile and reversible transition metal octahedral-to-tetrahedral migration, which improves rather than impedes Li transport. High-rate performance can be achieved by reversible switching between octahedral and tetrahedral sites in transition metal content.
Article
Electrochemistry
Jianping Huang, Shan Yan, Daren Wu, Lisa Housel, Xiaobing Hu, Sooyeon Hwang, Lei Wang, Xiao Tong, Lijun Wu, Yimei Zhu, Amy C. Marschilok, Esther S. Takeuchi, Kenneth J. Takeuchi
Summary: This study synthesized K+-containing alpha-MnO2 hollow nanotubes with variations in dimensions of the hollow regions and levels of surface defects. The nanotubes with larger hollow regions and higher surface defect levels exhibited better electrochemical performance, showing higher lithium ion diffusion coefficients and lower polarization. The research highlights the positive impact of tuning particle architecture and surface defects on the functional behavior of electrochemical storage materials.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2021)
Article
Chemistry, Physical
Jianping Huang, Bin Ouyang, Yaqian Zhang, Liang Yin, Deok-Hwang Kwon, Zijian Cai, Zhengyan Lun, Guobo Zeng, Mahalingam Balasubramanian, Gerbrand Ceder
Summary: Lithium-rich cathodes have high energy densities, but voltage hysteresis limits their practical implementation. This study shows that voltage hysteresis is related to collective migration of metal ions, and introducing partial disorder can create high-capacity reversible cathodes.
Review
Chemistry, Multidisciplinary
Kenna L. Salvatore, Justin Fang, Christopher R. Tang, Esther S. Takeuchi, Amy C. Marschilok, Kenneth J. Takeuchi, Stanislaus S. Wong
Summary: Nanomaterials, especially nanoscale motifs of binary metal sulfides, have been used in relevant energy applications as conversion materials with high theoretical capacity and low cost. This review focuses on the structure-composition-property relationships for battery applications, involving the variation of nanoscale architectures or the introduction of conductive carbon-based entities. The microwave-mediated synthetic approach is explored extensively to generate metal sulfide nanostructures and tailor them for energy storage applications by controlling both chemical composition and physical morphology.
Article
Chemistry, Physical
Jianping Huang, Peichen Zhong, Yang Ha, Zhengyan Lun, Yaosen Tian, Mahalingam Balasubramanian, Wanli Yang, Gerbrand Ceder
Summary: Substituting the labile oxygen with a vacancy in cation-disordered Li-rich rocksalt materials is an effective strategy to inhibit oxygen oxidation, leading to improved capacity and voltage retention in lithium-ion batteries.
Article
Chemistry, Physical
Jianping Huang, Lisa M. Housel, Lei Wang, Andrea M. Bruck, Calvin D. Quilty, Alyson Abraham, Diana M. Lutz, Christopher R. Tang, Andrew Kiss, Juergen Thieme, Kenneth J. Takeuchi, Esther S. Takeuchi, Amy C. Marschilok
SUSTAINABLE ENERGY & FUELS
(2019)