标题
Deconstructing Covalent Organocatalysis
作者
关键词
-
出版物
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 13, Pages 3862-3871
出版商
Wiley
发表日期
2015-02-20
DOI
10.1002/anie.201409004
参考文献
相关参考文献
注意：仅列出部分参考文献，下载原文获取全部文献信息。- On the Mechanism of N-Heterocyclic Carbene-Catalyzed Reactions Involving Acyl Azoliums
- (2014) Jessada Mahatthananchai et al. ACCOUNTS OF CHEMICAL RESEARCH
- The (Not So) Ephemeral Trifluoromethanide Anion
- (2014) Nico Santschi et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Long-Lived Trifluoromethanide Anion: A Key Intermediate in Nucleophilic Trifluoromethylations
- (2014) G. K. Surya Prakash et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Molecular Design Exploiting a FluorinegaucheEffect as a Stereoelectronic Trigger
- (2014) Yannick P. Rey et al. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
- The Houk–List transition states for organocatalytic mechanisms revisited
- (2014) Alan Armstrong et al. Chemical Science
- Structures and Reactivities of Iminium Ions Derived from Substituted Cinnamaldehydes and Various Chiral Imidazolidin-4-ones
- (2014) Feng An et al. Asian Journal of Organic Chemistry
- Mechanism of Diphenylprolinol Silyl Ether Catalyzed Michael Addition Revisited-but Still Controversial
- (2013) Christina Moberg ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Noncovalent Interactions in Organocatalysis: Modulating Conformational Diversity and Reactivity in the MacMillan Catalyst
- (2013) Mareike C. Holland et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Characterization of the Key Intermediates of Carbene-Catalyzed Umpolung by NMR Spectroscopy and X-Ray Diffraction: Breslow Intermediates, Homoenolates, and Azolium Enolates
- (2013) Albrecht Berkessel et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- On the Acidity and Reactivity of Highly Effective Chiral Brønsted Acid Catalysts: Establishment of an Acidity Scale
- (2013) Karl Kaupmees et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Matrix isolation and spectroscopic properties of the methylsulfinyl radical CH3(O)S˙
- (2013) Hans Peter Reisenauer et al. CHEMICAL COMMUNICATIONS
- On the Mechanism of the Organocatalytic Asymmetric Epoxidation of α,β-Unsaturated Aldehydes
- (2013) Rebecca L. Davis et al. CHEMISTRY-A EUROPEAN JOURNAL
- Enantioselective Aziridination of Cyclic Enals Facilitated by the Fluorine-Iminium IonGaucheEffect
- (2013) István Gábor Molnár et al. CHEMISTRY-A EUROPEAN JOURNAL
- Stoichiometric Reactions of Enamines Derived from Diphenylprolinol Silyl Ethers with Nitro Olefins and Lessons for the Corresponding Organocatalytic Conversions - a Survey
- (2013) Dieter Seebach et al. HELVETICA CHIMICA ACTA
- Imidazolidinone-Derived Enamines: Nucleophiles with Low Reactivity
- (2012) Sami Lakhdar et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Dihydrooxazine Oxides as Key Intermediates in Organocatalytic Michael Additions of Aldehydes to Nitroalkenes
- (2012) Gokarneswar Sahoo et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Umpolung by N-Heterocyclic Carbenes: Generation and Reactivity of the Elusive 2,2-Diamino Enols (Breslow Intermediates)
- (2012) Albrecht Berkessel et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Cinchona-based Primary Amine Catalysis in the Asymmetric Functionalization of Carbonyl Compounds
- (2012) Paolo Melchiorre ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- A quantitative approach to nucleophilic organocatalysis
- (2012) Herbert Mayr et al. Beilstein Journal of Organic Chemistry
- Fluorinated Organocatalysts for the Enantioselective Epoxidation of Enals: Molecular Preorganisation by the Fluorine-Iminium Ion Gauche Effect
- (2012) Eva-Maria Tanzer et al. CHEMISTRY-A EUROPEAN JOURNAL
- Designing Fluorinated Cinchona Alkaloids for Enantioselective Catalysis: Controlling Internal Rotation by a Fluorine-Ammonium Ion gauche Effect (φNCCF)
- (2012) Eva-Maria Tanzer et al. CHEMISTRY-A EUROPEAN JOURNAL
- Conformations and Reactions of Bicyclo[3.2.1]oct-6-en-8-ylidene
- (2012) Udo H. Brinker et al. JOURNAL OF ORGANIC CHEMISTRY
- Curtin–Hammett Paradigm for Stereocontrol in Organocatalysis by Diarylprolinol Ether Catalysts
- (2012) Jordi Burés et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Isolable Analogues of the Breslow Intermediate Derived from Chiral Triazolylidene Carbenes
- (2012) Daniel A. DiRocco et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Correction to Curtin–Hammett Paradigm for Stereocontrol in Organocatalysis by Diarylprolinol Ether Catalysts
- (2012) Jordi Burés et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Proton Transfer Reactions of Triazol-3-ylidenes: Kinetic Acidities and Carbon Acid pKa Values for Twenty Triazolium Salts in Aqueous Solution
- (2012) Richard S. Massey et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- (Thio)urea Organocatalyst Equilibrium Acidities in DMSO
- (2012) Gergely Jakab et al. ORGANIC LETTERS
- What is your actual catalyst? TMS cleavage rates of diarylprolinol silyl ethers studied by in situ NMR
- (2012) Michael H. Haindl et al. RSC Advances
- The Diarylprolinol Silyl Ether System: A General Organocatalyst
- (2011) Kim L. Jensen et al. ACCOUNTS OF CHEMICAL RESEARCH
- N-Heterocyclic Carbenes: Organocatalysts with Moderate Nucleophilicity but Extraordinarily High Lewis Basicity
- (2011) Biplab Maji et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Cyclopropyl Iminium Activation: Reactivity Umpolung in Enantioselective Organocatalytic Reaction Design
- (2011) Christof Sparr et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Brønsted Acid Catalysis: Hydrogen Bonding versus Ion Pairing in Imine Activation
- (2011) Matthias Fleischmann et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Fluorine Conformational Effects in Organocatalysis: An Emerging Strategy for Molecular Design
- (2011) Lucie E. Zimmer et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Photoredox Catalysis: A Mild, Operationally Simple Approach to the Synthesis of α-Trifluoromethyl Carbonyl Compounds
- (2011) Phong V. Pham et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Organocatalyzed Michael Addition of Aldehydes to Nitro Alkenes - Generally Accepted Mechanism Revisited and Revised
- (2011) Krystyna Patora-Komisarska et al. HELVETICA CHIMICA ACTA
- Nucleophilicities and Lewis Basicities of Isothiourea Derivatives
- (2011) Biplab Maji et al. JOURNAL OF ORGANIC CHEMISTRY
- Mechanistic Rationalization of Organocatalyzed Conjugate Addition of Linear Aldehydes to Nitro-olefins
- (2011) Jordi Burés et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Distinct conformational preferences of prolinol and prolinol ether enamines in solution revealed by NMR
- (2011) Markus B. Schmid et al. Chemical Science
- Aldehyde Umpolung by N-Heterocyclic Carbenes: NMR Characterization of the Breslow Intermediate in its Keto Form, and a Spiro-Dioxolane as the Resting State of the Catalytic System
- (2010) Albrecht Berkessel et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- The Elusive Enamine Intermediate in Proline-Catalyzed Aldol Reactions: NMR Detection, Formation Pathway, and Stabilization Trends
- (2010) Markus B. Schmid et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Fluoro-Organocatalysts: Conformer Equivalents as a Tool for Mechanistic Studies
- (2010) Christof Sparr et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Enamine versus Oxazolidinone: What Controls Stereoselectivity in Proline-Catalyzed Asymmetric Aldol Reactions?
- (2010) Akhilesh K. Sharma et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Counterion effects in iminium-activated electrophilic aromatic substitutions of pyrroles
- (2010) Sami Lakhdar et al. CHEMICAL COMMUNICATIONS
- Stereochemical Models for Discussing Additions toα,β-Unsaturated Aldehydes Organocatalyzed by Diarylprolinol or Imidazolidinone Derivatives - Is There an‘(E)/(Z)-Dilemma’?
- (2010) Dieter Seebach et al. HELVETICA CHIMICA ACTA
- Oxathiirane
- (2010) Peter R. Schreiner et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Crystal structures of proline-derived enamines
- (2010) D. A. Bock et al. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
- Attractive noncovalent interactions in asymmetric catalysis: Links between enzymes and small molecule catalysts
- (2010) R. R. Knowles et al. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
- A Persistent α-Fluorocarbanion and Its Analogues: Preparation, Characterization, and Computational Study
- (2009) G. K. Surya Prakash et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- A Formal Carbon-Sulfur Triple Bond: HCSOH
- (2009) Peter R. Schreiner et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- The Fluorine-Iminium IonGaucheEffect: Proof of Principle and Application to Asymmetric Organocatalysis
- (2009) Christof Sparr et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Kinetic and mechanistic studies of proline-mediated direct intermolecular aldol reactions
- (2009) Natalia Zotova et al. BIOORGANIC & MEDICINAL CHEMISTRY LETTERS
- Organocatalysis—after the gold rush
- (2009) Søren Bertelsen et al. CHEMICAL SOCIETY REVIEWS
- Structural Analyses ofN-Acetylated 4-(Dimethylamino)pyridine (DMAP) Salts
- (2009) Volker Lutz et al. CHEMISTRY-A EUROPEAN JOURNAL
- Structures of the Reactive Intermediates in Organocatalysis with Diarylprolinol Ethers
- (2009) Uroš Grošelj et al. HELVETICA CHIMICA ACTA
- 5-Benzyl-3-methylimidazolidin-4-one-Derived Reactive Intermediates of Organocatalysis - A Comforting Resemblance of X-Ray, NMR, and DFT Solid-Phase, Liquid-Phase, and Gas-Phase Structures
- (2009) Uroš Grošelj et al. HELVETICA CHIMICA ACTA
- Catalytic Asymmetric oxa-Michael−Michael Cascade for Facile Construction of Chiral Chromans via an Aminal Intermediate
- (2009) Liansuo Zu et al. ORGANIC LETTERS
- Autocatalysis and organocatalysis with synthetic structures
- (2009) S. Kamioka et al. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
- Synergy of NMR, Computation, and X-Ray Crystallography for Structural Biology
- (2009) Blair R. Szymczyna et al. STRUCTURE
- Isolation and X-Ray Structures of Reactive Intermediates of Organocatalysis with Diphenylprolinol Ethers and with Imidazolidinones
- (2008) Dieter Seebach et al. HELVETICA CHIMICA ACTA
- Ab Initio/GIAO-CCSD(T) Study of Structures, Energies, and13C NMR Chemical Shifts of C4H7+and C5H9+Ions: Relative Stability and Dynamic Aspects of the Cyclopropylcarbinyl vs Bicyclobutonium Ions
- (2008) George A. Olah et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- The advent and development of organocatalysis
- (2008) David W. C. MacMillan NATURE
- Solution Phase, Solid State, and Theoretical Investigations on the MacMillan Imidazolidinone
- (2008) John B. Brazier et al. ORGANIC LETTERS
- Organocatalysis Lost: Modern Chemistry, Ancient Chemistry, and an Unseen Biosynthetic Apparatus
- (2007) Carlos F. Barbas ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Publish scientific posters with Peeref
Peeref publishes scientific posters from all research disciplines. Our Diamond Open Access policy means free access to content and no publication fees for authors.
Learn MoreAsk a Question. Answer a Question.
Quickly pose questions to the entire community. Debate answers and get clarity on the most important issues facing researchers.
Get Started