期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 41, 页码 11999-12003出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201505538
关键词
host-guest systems; hydrogen bonds; mesoporous materials; organosilicas; self-assembly
资金
- Japan Society for Promotion of Science (JSPS) [2406]
- Grants-in-Aid for Scientific Research [24107002] Funding Source: KAKEN
Nanoporous materials with functional frameworks have attracted attention because of their potential for various applications. Silica-based mesoporous materials generally consist of amorphous frameworks, whereas a molecular-scale lamellar ordering within the pore wall has been found for periodic mesoporous organosilicas (PMOs) prepared from bridged organosilane precursors. Formation of a crystal-like framework has been expected to significantly change the physical and chemical properties of PMOs. However, until now, there has been no report on other crystal-like arrangements. Here, we report a new molecular-scale ordering induced for a PMO. Our strategy is to form pore walls from precursors exhibiting directional H-bonding interaction. We demonstrate that the H-bonded organosilica columns are hexagonally packed within the pore walls. We also show that the H-bonded pore walls can stably accommodate H-bonding guest molecules, which represents a new method of modifying the PMO framework.
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