期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 29, 页码 8533-8537出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201503373
关键词
copper; cyclizations; fluorine; heterocycles; homogeneous catalysis
资金
- Swedish Research Council
- Knut and Alice Wallenbergs Foundation
Application of a fluoroiodine analogue of the Togni reagent was studied in fluorocyclization reactions. In the presence of a transition-metal catalyst the applied fluoroiodine reagent can be used for aminofluorination, oxyfluorination, and carbofluorination reactions. The described procedure has a very broad synthetic scope for preparation of functionalized hetero- and isocyclic compounds having a tertiary fluorine substituent.
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