期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 13, 页码 4075-4078出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201412051
关键词
aryl esters; C-O cleavage; C-O electrophiles; nickel catalysis
资金
- ICIQ foundation
- European Research Council [ERC-277883]
- MINECO [CTQ2012-34054]
- MINECO (Severo Ochoa Excellence Accreditation) [SEV-2013-0319]
- CELLEX Foundation through the CELLEX-ICIQ high-throughput experimentation platform
- European Union [FP7-PEOPLE-2012-IEF-328381]
- Rackham Graduate School
- ICREA Funding Source: Custom
We report the first enantioselective C-C bond formation through C-O bond cleavage using aryl ester counterparts. This method is characterized by its wide substrate scope and results in the formation of quaternary stereogenic centers with high yields and asymmetric induction.
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