4.6 Article

Visible-to-UVC upconversion efficiency and mechanisms of Lu7O6F9:Pr3+ and Y2SiO5:Pr3+ ceramics

期刊

JOURNAL OF LUMINESCENCE
卷 160, 期 -, 页码 202-209

出版社

ELSEVIER SCIENCE BV
DOI: 10.1016/j.jlumin.2014.11.049

关键词

Upconversion; UVC; Praseodymium; Oxyfluoride

类别

资金

  1. National Science Foundation (CBET) [1033866]
  2. Korea Institute for Advancement of Technology [2011-GU-400115-001]
  3. Ministry of Knowledge Economy (MKE), Republic of Korea [2011-GU-400115-001] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
  4. Directorate For Engineering
  5. Div Of Chem, Bioeng, Env, & Transp Sys [1033866] Funding Source: National Science Foundation

向作者/读者索取更多资源

Visible-to-UVC upconversion (UC) by Pr3+-doped materials is a promising candidate for application to sustainable disinfection technologies, including light-activated antimicrobial surfaces and solar water treatment. In this work, we studied Pr3+ upconversion in an oxyfluoride host system for the first time, employing Lu7O6F9:Pr3+ ceramics. Compared to the previously studied Y2SiO5:Pr3+ reference material, the oxyfluoride host resulted in a 5-fold increase in intermediate state lifetime, likely due to a lower maximum phonon energy; however, only a 60% gain in UC intensity was observed. To explain this discrepancy, luminescence spectral distribution and decay kinetics were studied in both phosphor systems. The Pr3+ 4f5d band energy distribution in each phosphor was found to play a key role by allowing or disallowing the occurrence of a previously unexplored UC mechanism, which had a significant impact on overall efficiency. (C) 2014 Elsevier B.V. All rights reserved.

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