期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 32, 页码 9356-9360出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201503412
关键词
alkynes; copper; heterocycles; rearrangements; synthetic methods
资金
- National Basic Research Program of China [973-2015CB856600]
- National Natural Science Foundation of China [21225210, 21202185, 21472219, 21421091]
A novel method for convenient access to CF3-containing azirines has been developed, and involves a copper-catalyzed trifluoromethylazidation of alkynes and a photocatalyzed rearrangement. Both terminal and internal alkynes are compatible with the mild reaction conditions, thus delivering the CF3-containing azirines in moderate to good yields. The azirines can be converted into various CF3-substituted aziridines.
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