期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 40, 页码 11795-11799出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201505118
关键词
cycloaddition; metal catalysis; reaction mechanisms; structure elucidation; tetrazoles
资金
- National Natural Science Foundation of China [21363001, 21401026, 51268002]
- Major Project for Science and Technology of Jiangxi Province [20152ACB21016]
Using an experimental approach, the role of metal catalysis has been investigated in the in situ cycloaddition reaction of nitrile with azide to form tetrazoles. It has been shown that metal catalysis serves to activate the cyano group in the nitrile reagent by a coordinative interaction.
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