期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 23, 页码 6883-6886出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201501275
关键词
amino acids; asymmetric catalysis; Michael additions; organocatalysis; synthetic methods
资金
- University of the Basque Country UPV/EHU [UFI 11/22]
- Basque Government [IT-628-13]
- Ministerio de Economia y Competitividad (MEC), Spain [CTQ2013-47925-C2-1-P]
- UPV/EHU
1H-Imidazol-4(5H)-ones are introduced as novel nucleophilic -amino acid equivalents in asymmetric synthesis. These compounds not only allow highly efficient construction of tetrasubstituted stereogenic centers, but unlike hitherto known templates, provide direct access to N-substituted (alkyl, allyl, aryl) -amino acid derivatives.
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